• YAKHAK HOEJI
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• v.52 no.4
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• pp.311-315
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• 2008

The synthesis of 7-arylidene cephalosporanates for ${\beta}-lactamase$ inhibitor was described. The reactions of substituted benzyl halides $[1]{\sim}[3]$ with triphenylphosphine gave triphenylphcsphonium chlorides $[4]{\sim}[6]$. These phosphonium salts were treated with n-butyllithium to give ylides, which were reated with 7-oxocephalosporanate [7] by Wittig reaction to afford the 7-exomethylene cephalosporanates $[8]{\sim}[10]$. These cephalosporanates were oxidized to cephalosporanate sulfones $[11]{\sim}[13]$ with mCPBA. The deprotection of benzhydryl cephalosporanate $[8]{\sim}[13]$ with $AlCl_3$ and $NaHCO_{3}$ gave sodium salts of 7-arylidene cephalosporanates $[14]{\sim}[19]$.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.104-105
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• 2006

We succeeded the synthesis of new functional polymers by novel ring-opening addition reactions of bis(oxetane)s with diacyl chlorides, di(active ester)s, and di(carboxylic acid)s using quaternary onium salts as catalysts at appropriate conditions. Hyperbranched polyesters with many pendant hydroxy groups were also synthesized by the polyaddition of bis(oxetane)s with tricarboxylic acid, or by the self-polyadditions of $AB_2\;or\;A_2B$ type monomers containing oxetane group. The anionic ring-opening polymerization of (3-ethyl-3-hydroxymethyl)oxetane was examined using sodium tert-buthoxide to give hyperbranched poly(ether)s containing one oxetanyl group and many hydroxyl groups in the end of polymer chain.

• Journal of the Korean Chemical Society
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• v.9 no.1
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• pp.8-15
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• 1965

Justifications for the use of ${\sigma}$ and Y as independent potential energy variables in the general equation have been reviewed and some mechanistic significances of the relationship discussed. Analysis of the activation parameters for the solvolysis of benzyl chlorides in ethanol-water mixture showed that there are two distinct series of substrate constants ${\alpha}'$, which can be correlated linearly within a series with the substituent constants ${\sigma}$ conforming to the generally accepted concept of change in mechanism from $S_N1$ to $S_N2$.

• Bulletin of the Korean Chemical Society
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• v.34 no.3
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• pp.820-822
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• 2013

N,N,N',N'-Tetrabromobenzene-1,3-disulfonamide (TBBDA)/$PPh_3$ and N,N,N',N'-tetrachlorobenzene-1,3-disulfonamide (TCBDA)/$PPh_3$ are two highly reactive reagent systems for the conversion of alcohols corresponding into alkyl chlorides and bromides in moderate to excellent yields in dichloromethane at room temperature under mild and neutral conditions.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.597-600
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• 2006

In Marine Land underground reinforced concrete structures, such as electric box power structure, water and chloride ion penetrated into concrete through the cracks of concrete and its permeable property, cause the corrosion of reinforcing steel bar, which accelerates the expansive cracks and deterioration of concrete. The purpose of this paper is to evaluate on deterioration of durability concrete through instrumental analysis such as schmidt hammer and carbonation, chloride content. Under the reclaimed marine land, the main cause of deterioration of concrete structures is the steel corrosion due to the penetration of chlorides and the deterioration of outer concrete itself by chemical attack.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.177-180
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• 2006

Reinforced concrete has been widely used as a semi-permanent construction materials. However, sea sand, deicing salt, and marine condition might induce the corrosion of embedded reinforcement due to the penetration of chlorides in concrete structures. This reinforcement corrosion causes serious problems on safety and serviceability of structures during lifetime. Also, reinforcement corrosion may cause the collapse of structures in worst case, so that the corrosion problem is more and more intensely growing. The purpose of this paper is to provide the fundamental data for the mechanical effect of corrosion through evaluation on bond characteristics of reinforced concrete using corroded bars.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.493-496
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• 2006

Steel corrosion in concrete is aggravated with the increase of chloride content in concrete. So, there are regulations in the total amount of chloride ions in concrete in Korea and Japan. The purpose of this paper is to propose a resonable method to regulate the amount of chlorides in concrete. In this study, the experimental results showed that it is rather reasonable to regulate the amount of chloride ions in cement than the total amount of the chloride ions in concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.417-418
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• 2009

As iron corrosion by means of penetration of chlorides resulted in a serious deterioration of seaside and landfill concrete construction, it is urgently necessary for seaside construction to acquire watertightness and resistance for chloride-attack. Hence in this study, Si/Al liquor type hybrid-inorganic salt which was very effective compound for improving resistance for chloride-attack applied to mortar and then evaluated resistance for chloride-attack with curing(7, 14, 28, 56 days).

• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.281-284
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• 2003

When concrete structures are exposed under marine condition for a long time, the steel in concrete is corroded due to the ingression of chlorides in the sea water. Because the damages of corrosion resulting from the chloride ion are very serious, many research have been performed. In this study, it was experimentally investigated that the mechanical and diffusion characteristics of concrete substituted with ordinary portland cement, silica fume and blast furnace slag to investigate the chloride ingress characteristics with concrete quality. Chloride diffusion coefficients in concrete shows increasing tendency as w/c ratio increase. Also test results indicate that blend of admixture become lower chloride diffusion coefficients in concrete as compared with normal concrete.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.11a
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• pp.657-664
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• 2000

Weak and soft compressible clay deposits are commonly found in natural subgrade soils. These Soils need to be stabilized for using the subbase materials of highway constructions. This paper presents that a chemical treatment using chemical additives comprised of sulfate(SO$_4$) and chloride(Cl) is evaluated for stabilizing soft clay deposits and lime. The physical and mechanical characteristics of soil-lime and additives are described by means of a laboratory study. The study results indicate that the presence of chlorides encouraged the efficiency of lime stabilization, and the use of calcium chloride with quicklime is the best additive for improving soil behavior. The treated soil with lime-calcium chloride can have the adaptability to the subbase materials of highway constructions.