• 제목/요약/키워드: Chloride salt

검색결과 598건 처리시간 0.024초

플라이애시를 혼입한 콘크리트의 전위차 적정법과 XRF를 이용한 염화물 침투 분석 (Chloride Penetration Analysis of Fly Ash Concrete using Potentiometric Titration and XRF )

  • 서은아;김지현;이호재
    • 한국구조물진단유지관리공학회 논문집
    • /
    • 제27권5호
    • /
    • pp.16-22
    • /
    • 2023
  • 이 연구는 원전 콘크리트 배합설계를 모사한 콘크리트 시험체에 대하여 염수침지 실험을 수행하였으며, 시험체 깊이에 따른 염화물량과 XRF 성분의 상관관계를 분석하였다. 원전 콘크리트의 표면부의 염화물량은 염수 침지기간이 증가함에 따라 소폭 증가하였으나, 깊이 5.5 mm 이상의 콘크리트 시험체 내부 염화물량은 염수 침지기간이 증가함에 증가하는 경향이 뚜렷하게 나타났다. 콘크리트의 염화물량과 XRF 성분의 상관관계 분석결과, OPC 배합과 비교하여 FA가 20% 치환된 배합은 XRF 성분분석을 통한 Cl 이온의 구성비율과 염해저항성 평가결과의 상관관계가 매우 높게 나타났다. 이에 따라 FA가 20% 치환된 원전 콘크리트 배합에서는 반복적인 데이터 누적을 통해 XRF 성분분석을 통하여 염소이온분석 및 염해저항성능 평가가 가능함을 확인하였다.

아연염으로 표면처리한 활성탄에 의한 수중 유기화합물의 흡착 (Adsorption of Organic Chemical by Coconut Activated Carbon treated with Zinc Salt)

  • 김영규;한진수
    • 환경위생공학
    • /
    • 제10권1호
    • /
    • pp.132-141
    • /
    • 1995
  • The objectives of this study was to find the effect of zinc salt treated with coconut activated carbon and the effect of humic substance. The bottle- Point technique was used in determining the Freundlich isotherm equation. The adsorptive capacity of granular activated carbon was reduced when humic substance are present. Coconut activated carbon was coated with 0.0001 N zinc chloride decreased the BET surface area but increased the adsorptive capacity more than coconut activated carbon not coated with zinc chloride. The adsorptive capacity of TCE in coconut activated carbon coated with higher concentration of zinc chloride was reduced but increased in the solution containing humic substance when the coconut activated carbon was coated with 0.01 N- zinc chloride. The zinc salt coated with coconut activated carbon did not Increase the adsorptive velocity of coconut activated carbon.

  • PDF

마그네슘 용융염전해(溶融鹽電解)를 위한 무수(無水)염화마그네슘 제조(製造) (Preparation of Anhydrous Magnesium Chloride for a Fused Salt Electrolysis of Magnesium)

  • 엄형춘;박형규;윤호성
    • 자원리싸이클링
    • /
    • 제16권1호
    • /
    • pp.37-43
    • /
    • 2007
  • 본 연구에서는 함수염화마그네슘 탈수를 통하여 마그네슘 용융염전해의 원료 물질인 무수염화마그네슘을 제조하였으며, 탈수는 관상로를 이용하여 $350{\sim}580^{\circ}C$ 범위에서 수행하였다. 함수염화마그네슘을 대기중에서 탈수할 경우 모두 산화마그네슘으로 산화되는 것을 알 수 있었으며, 염화수소가스 분위기에서 탈수시켜 무수염화마그네슘을 제조할 수 있음을 확인하였다. 그리고 탈수 온도와 시간이 증가함에 따라 탈수된 무수염화마그네슘의 결정성이 증가하였다. 염화수소가스 분위기에서 탈수가 일어나는 동안 발생되는 미반응 염화수소가스는 모두 염산으로 회수할 수 있었으며, 회수한 염산은 산화마그네슘으로부터 함수염화마그네슘을 제조하는 데에 재사용 가능할 것으로 판단된다.

염화칼슘을 함유하는 소금용액에서의 절임이 김치숙성에 미치는 영향 (Effect of Salting in Salt Solution Added calcium Chloride on the Fermentation of Baechu Kimchi)

  • 오영애;김순동
    • 동아시아식생활학회지
    • /
    • 제5권3호
    • /
    • pp.287-298
    • /
    • 1995
  • This study was undertaken to examine the effect of salting in 10% salt solution added 2% calcium chloride on the kimchi fermentation. The addition of calcium chloride extended edible periods of the Kimchi to 4~5 days and increased relatively the hardness of Chinese Cabbage. In the addition of calcium chloride, the activities of amylase and $\beta$ -galactosidase were not high during all periods fermentation. Polygalacturonase and protease activities were low 2~21%, 2~26% all periods fermentation, respectively. There were significant correlations between the delay of ripeness and decreasing enzyme activation. The amount of free amino acid by the treatment with calcium chloride was decreased of 10~16% at the late of fermentation than that of control. the treatment with calcium chloride of the Kimchi was increased hardness, but decreased cohesiveness and gumminess was during all periods fermentation. the adhesiveness was increased at the early of fermentation but decreased at the late of fermentation.

  • PDF

담수환경하에 노출된 일반 벤토나이트 매트재의 팽윤성능 평가 (A Study on the Swelling Property of Bentonite Mat under Salt Water Condition)

  • 양승도;김영삼;유재강;오상근
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2002년도 학술논문발표회
    • /
    • pp.81-84
    • /
    • 2002
  • Recently Bentonite mat is applied various structure : External waterproofing for underground structure, A reclaimed land, Artificial lake, Large-scaled civil structure, etc. With these various structure environment, water quality for application of Bentonite Mat affects watertightness. Specially spot with a large quantity of Chloride ion like salt water, degree of watertightness revelation is evaluated and applied. In this study, it is a main goal to investigate watertightness of Bentonite Mat with distilled water and salt water dissolved chloride ion Contents 0.88%. The result of this paper is as follows. 1) Water permeability coefficient of Bentonite Mat : distilled water(1.21$\times$10$^{-9}$cm/sec), salt water(3.12$\times$10$^{-7}$cm/sec). 2) Variation of thickness : distilled water(187%), salt water(108%). 3) Swelling ratio : distilled water(1500%), salt water(350%).

  • PDF

Surprisingly, traditional purple bamboo salt, unlike other salts does not induce hypertension in rats

  • Kim, Young-Sick;Lee, Eun-Hee;Kim, Hyung-Min
    • 셀메드
    • /
    • 제3권2호
    • /
    • pp.16.1-16.5
    • /
    • 2013
  • Hypertension induces many of the social costs related by cardiovascular diseases. Sodium is known as a crucial factor in inducing type I hypertension. In traditional Korean medicine, bamboo salt (BS) has been used in the attenuation of salts toxic coldness and nowadays it has shown various therapeutic effects. It contains mostly sodium chloride (about 91.7% of BS); however, the effect of BS on hypertension is still not completely understood. Thus, we investigated the effect of BS on blood pressure for the first time. Two group of BS, sun-dried salt (SDS), NaCl, or distilled water (DW, vehicle control) was administrated orally for 8 weeks. Although BS had no effect on body weight and food intake, it increased water intake (p < 0.05). The BS groups, in terms of blood pressure, was similar to the DW group; whereas the SDS and NaCl groups showed significantly increased blood pressure levels (p < 0.05). BS also decreased sodium-chloride cotransporter (NCC) mRNA expression, unlike SDS or NaCl. These observations indicate that BS may be a promising strategy for the prevention of various diseases including salt-related diseases.

침적시험에 의한 콘크리트의 염소이온 확산계수 평가 (A Study on the Chloride Ion Diffusion Coefficient of Concrete by Submergence in Salt Water)

  • 김동석;양승규;정연식;유재상;이종열;본간건일
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
    • /
    • pp.297-300
    • /
    • 2003
  • A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon. In this study, It is evaluated the diffusion coefficient of chloride ion in non-steady state by Fick's second law. Submergence method in salt water carried out in this experiment. Two types of cement which is different in mineral composition were used. In addition, the effect of mineral admixtures of blast-furnace slag and meta-kaolin was studied. In conclusion, the diffusion coefficient of chloride ion is much affected according to cement type and mineral admixtures, also, it is proved that meta-kaolin as well as blast-furnace slag is effective in preventing penetration of chloride ion.

  • PDF

해양 환경하 콘크리트 교량의 염해환경 성능평가 연구 (A Study on the Evaluation of the Environmental Performance of Salt Damage in Concrete Bridges under Marine Environment)

  • 채원규;이명구;손영현;홍성욱
    • 한국안전학회지
    • /
    • 제33권5호
    • /
    • pp.60-69
    • /
    • 2018
  • This study aims to investigate in the assessment of salt damage conditions in concrete structures under marine environment conditions. It aims also to improve the durability of new concrete bridge through applying the life prediction method of salt damaged bridges. As measuring chloride contents of these bridges on the southwest coastal area, it is shown that the average amount of chloride on these surfaces close to shore is $10.5kg/m^3$. This figure is much higher than that of the Standard Specification for Concrete($1.5kg/m^3{\sim}2.5kg/m^3$). In contrast, it is shown the average amount of chloride on these surfaces in tide zone is $13.1kg/m^3$. Its figure is much lower than that of the Standard Specification for Concrete($20kg/m^3$). And the life of bridges is estimated about 17 years. To improve the durability for salt damage, these bridges are applied to surface treatment method which the replacement rate of furnace slag is 60%. Under this condition, it is expected to be 110 years. Consequently, it is clear that the use of slag replacement rate, surface treatment agent, and anti-corrosion agent to control chloride penetration effects of a submerge-based concrete bridge will be required.

Modified Carrageenan. 6. Crosslinked Graft Copolymer of Methacrylic Acid and kappa-Carrageenan as a Novel Superabsorbent Hydrogel with Low Salt- and High pH-Sensitivity

  • Pourjavadi A.;Harzandi A. M.;Hosseinzadeh H.
    • Macromolecular Research
    • /
    • 제13권6호
    • /
    • pp.483-490
    • /
    • 2005
  • A novel, polysaccharide-based, superabsorbent hydrogel was synthesized through crosslinking graft copolymerization of methacrylic acid (MAA) onto kappa-carrageenan ($_{k}C$), using ammonium persulfate (APS) as a free radical initiator in the presence of methylenebisacrylamide (MBA) as a crosslinker. A proposed mechanism for $_{k}C$­g-polymethacrylic acid ($_{k}C$-g-PMAA) formation was suggested and the hydrogel structure was confirmed using FTIR spectroscopy. The effect of grafting variables, including MBA, MAA, and APS concentration, was systematically optimized to achieve a hydrogel with the maximum possible swelling capacity. The swelling kinetics in distilled water and various salt solutions were preliminarily investigated. Absorbency in aqueous salt solutions of lithium chloride, sodium chloride, potassium chloride, calcium chloride, and aluminum chloride indicated that the swelling capacity decreased with increased ionic strength of the swelling medium. This behavior can be attributed to the charge screening effect for monovalent cations, as well as ionic crosslinking for multivalent cations. The swelling of super absorbing hydrogels was measured in solutions with pH ranging from 1 to 13. In addition, the pH reversibility and on-off switching behavior, at pH levels of 3.0 and 8.0, give the synthesized hydrogels great potential as an excellent candidate for the controlled delivery of bioactive agents.

우레탄계와 아크릴계 도막 방수재가 도포된 바탕 모르타르의 염해 저항성 평가 (Salt damage resistance of mortar substrate coated by the urethane and acrylic waterproofing membranes)

  • 이준;미야우치 히로유키;구경모;최경철;미야우치 카오리;김규용
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2013년도 춘계 학술논문 발표대회
    • /
    • pp.329-331
    • /
    • 2013
  • The salt damage resistance of waterproofing membrane was evaluated on the cracked mortar substrate. The types of specimens are urethane, acrylic waterproofing membrane, and no coating mortar substrate. After these specimens were cured by water curing for 4 weeks, they were cured by atmospheric curing at 20±2Co for 8 weeks. The salt water immersion test was carried out by following KS F 2737, and the penetration depth of chloride ion into substrate was measured in 1, 4, 8, and 13 weeks. As a result, in the case of non coating specimen, the chloride ion penetrated within one week. In the coated specimens, a regardless of the membrane type, the chloride ion did not penetrate during 13 weeks-tests on condition that the cracked width of substrate is less than 0.3mm. Also, the penetration speeds of the coated specimens were lower than that of non coating specimen. Therefore, our results reached a conclusion that waterproofing membrane has high salt damage resistance.

  • PDF