• 제목/요약/키워드: Chloride Diffusion Coefficient

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고르슬래그미분말을 다량 혼입한 콘크리트의 염분침투저항성 (Chloride Penetration Resistance of Concrete Mixed with High Volume Blast Furnace Slag)

  • 박기철;김동훈;박신;임남기
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2014년도 추계 학술논문 발표대회
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    • pp.40-41
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    • 2014
  • As a result of strength test on BFS concrete, those mixed with 30% and 50% of BFS8000, respectively, showed higher or equivalent strength compare to OPC. As a result of test of chloride penetration on BFS, diffusion coefficients of concrete mixed with 30% FA4000 and FA5000, respectively, showed to restrain average 6.5% of diffusion coefficient compared to OPC. And in case of BFS concrete, those mixed with BFS6000 and BFS8000, restrained diffusion of chloride ions 253% and 336%, respectively, compared to OPC. Therefore, Mixing 50% of BFS was most efficient in order to maximize restraint of chloride penetration according to metathesis of large amount. In this study, when mixing BFS to concrete for long-run durability and restraint against chloride penetration, for BFS, as fineness was higher and mixing it to concrete with less or equivalent 50% of replacement rate, there were results of higher strength compared to OPC and more efficient restraint of chloride ions.

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혼화재 종류 및 치환율이 염수에 침지한 콘크리트의 내염성능 향상에 미치는 영향에 관한 연구 (A Study on the Effect of the Kinds and Replacement Ratios of Mineral Admixtures on the Development of Chloride Invasion Resistance Property of Concrete Immersed in Salt Water)

  • 유재강;김동석;박상준;원철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2004년도 학술대회지
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    • pp.71-76
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    • 2004
  • This paper investigate that the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for $3\sim4$ replacement ratios under W/B ratios ranged from 0.40 to 0.55. Specimens were immersed in $3.6\%$ NaCl solution for 330 days, and penetration depth, water soluble chloride contents and acid soluble chloride contents were measured in 28, 91, 182 and 330 days. Then, diffusion coefficient were calculated using total chloride contents. As a results. the kinds of mineral admixture and replacement ratios had a great effect on the resistance property of the concrete to chloride ion invasion compared with the plain concrete. And the optimal replacement ratios of mineral admixture had a limitation for each admixtures. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures and the penetration depth from the concrete skin. Chloride diffusion coefficient of each concretes decreased with the time elapsed. and the diffusion coefficients of the concrete immersed salt water for 330 days had a establishment with the compressive strength measured before immersing.

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혼화재 종류 및 치환율이 콘크리트의 내염성능 향상에 미치는 영향에 관한 연구 (Effect of the Kinds and Replacement Ratios of Mineral Admixtures on the Development of Concrete Resistance against the Penetration of Chloride Ions)

  • 김영진;이상수;김동석;유재강
    • 콘크리트학회논문집
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    • 제16권3호
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    • pp.319-326
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    • 2004
  • 본 연구는 콘크리트의 시공성 및 역학적 특성을 향상시키기 위하여 사용되는 혼화재료(플라이애쉬, 고로슬래그미분말, 실리카퓸 및 메타카올린)를 해양환경에 노출되는 콘크리트에 적용할 경우, 혼화재료가 콘크리트의 내염성능 향상에 미치는 영향을 검토하기 위하여 비교적 단기간에 평가할 수 있는 전기적 촉진시험방법을 사용하여 혼화재 종류 및 치환율, 물-결합재비, 재령에 따른 염화물 확산계수를 비교$\cdot$평가하였다. 혼화재 종류 및 치환율에 따른 염화물 확산계수 평가결과 물-결합재비 수준에 따라 성능의 차이는 있지만 각 혼화재별로 염화물 침투저항성이 우수한 치환율 수준이 있는 것을 알 수 있었다. 또한, 염화물확산계수는 물-결합재비 수준에 따른 영향과 더불어 적정의 치환율을 적용한 혼화재의 사용에 의해서도 현저하게 저감시킬 수 있는 것으로 나타났으며, 시간의 경과와 함께 염화물 확산계수도 감소되는 시간의존적인 특성은 혼화재 종류 및 치환율에 의해 영향을 받는 것으로 사료된다. 압축강도와 염화물 확산계수는 반비례의 관계를 보이고 있으며, 본 연구의 범위에서 보면 50MPa 이하영역에서는 염화물 확산계수는 압축강도 발현특성과 더불어 혼화재 사용 및 치환율에 따른 영향도 크게 나타나고 있어, 향후 염해 환경하에서 내구성을 고려한 구조물 설계시 보다 정확한 내구성능 평가를 위해서는 압축강도 발현특성 검토와 더불어 염화물 확산계수의 평가가 이루어져야 할 것으로 사료된다.

제설제로부터 기인한 염화물의 콘크리트 확산특성 (Chloride Diffusion of Concrete in Presence of De-icing Salt)

  • 정해문;안태송
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.507-510
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    • 2005
  • In winter, a large amount of de-icing salts such as $CaCl_2$, NaCl have been used on highways for road safety. They make concrete structures deteriorated. In this study, the chloride diffusion of concrete in presence of de-icing salt was investigated. The diffusion coefficient of chloride in presence of $CaCl_2$ solution was larger than in presence of NaCl solution. Therefore, it is necessary to assess chloride profile in presence of $CaCl_2$ by different way from the case in presence of NaCl solution or seawater.

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An adaptive approach for the chloride diffusivity of cement-based materials

  • Tran, Bao-Viet;Pham, Duc-Chinh;Loc, Mai-Dinh;Le, Minh-Cuong
    • Computers and Concrete
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    • 제23권2호
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    • pp.145-153
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    • 2019
  • Adaptive schemes are constructed in this paper for modeling the effective chloride diffusion coefficient of cement-based materials (paste and concrete). Based on the polarization approximations for the effective conductivity of isotropic multicomponent materials, we develop some fitting procedures to include more information about the materials, to improve the accuracy of the scheme. The variable reference parameter of the approximation involves a few free scalars, which are determined through the available numerical or experimental values of the macroscopic chloride diffusion coefficient of cement paste or concrete at some volume proportions of the component materials. The various factors that affect the chloride diffusivity of cement-based material (porous material structure, uncertainty of value of the chloride diffusion coefficient in water-saturated pore spaces, etc.) may be accounted to make the predictions more accurate. Illustrations of applications are provided in a number of examples to show the usefulness of the approach.

인장 및 압축영역에서 콜드조인트 콘크리트의 염화물 확산계수 평가 (Evaluation of Chloride Diffusion Coefficients in Cold Joint Concrete Considering Tensile and Compressive Regions)

  • 문진만;권성준
    • 콘크리트학회논문집
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    • 제28권4호
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    • pp.481-488
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    • 2016
  • 콘크리트는 공용기간동안 구조물 자체의 자중 및 이동 하중에 따른 응력을 받게 되며, 이러한 응력은 구조적인 거동뿐 아니라 내구적인 거동에도 영향을 준다. 대단위 콘크리트 부재의 시공은 시공이음을 요구하는데, 면처리 불량 또는 이어치기의 지연에 의해 콜드조인트가 발생하게 된다. 이러한 콜드조인트는 전단력에 취약할 뿐 아니라 염화물 확산성에도 영향을 미친다. 본 연구에서는 응력조건과 콜드조인트가 콘크리트의 염화물 확산에 미치는 영향을 정량적으로 평가하였다. 콜드조인트를 가진 콘크리트는 인장하중 수준이 30%에서 60%로 커질 때, 확산계수는 꾸준하게 증가하여 건전부와 큰 차이를 보이지 않았다. 그러나 압축부에서는 하중재하 30% 수준부터 콜드조인트 콘크리트에서 염화물 확산계수가 크게 증가하여 확산계수가 170% 이상 증가하였다. 이러한 특성은 압축하중을 받는 건전부 콘크리트와 큰 차이가 있으므로 이음부를 가지는 콘크리트의 내구성 설계에 주의가 필요하다.

해상교량 주탑용 고성능 콘크리트의 기준재령 염소이온 확산계수 (Chloride Diffusion Coefficient at Reference Time for High Performance Concrete for Bridge Pylons in Marine Environment)

  • 윤철수;김기현;양우용;차수원
    • 콘크리트학회논문집
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    • 제24권4호
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    • pp.435-444
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    • 2012
  • 기준재령 염소이온 확산계수를 측정하기 위하여 고성능 콘크리트 배합을 선정하고 공시체를 제작하였다. 배합은 해양환경에 건설되는 교량에 적합하도록 선정되었으며 배합설계 변수는 결합재 종류, 물-결합재비, 광물질 혼화재 치환율, 잔골재 종류, 고강도 및 고유동성을 얻기 위한 화학 혼화제 종류, 목표 슬럼프 또는 슬럼프 플로우이다. 시험 결과로부터 기준재령 염소이온 확산계수는 결합재 종류와 그 치환율에 따라 크게 다름을 확인하고, 결합재 종류와 치환율을 고려한 기준재령 확산계수 모델을 개발하였다. 개발된 모델의 확산계수를 기존 모델의 확산계수 및 추가 확산 계수 측정시험 결과 비교하여 개발된 모델의 타당성을 확인하였다.

Chloride diffusion study in different types of concrete using finite element method (FEM)

  • Paul, Sajal K.;Chaudhuri, Subrata;Barai, Sudhirkumar V.
    • Advances in concrete construction
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    • 제2권1호
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    • pp.39-56
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    • 2014
  • Corrosion in RCC structures is one of the most important factors that affects the structure's durability and subsequently causes reduction of serviceability. The most severe cause of this corrosion is chloride attack. Hence, to prevent this to happen proper understanding of the chloride penetration into concrete structures is necessary. In this study, first the mechanism of this chloride attack is understood and various parameters affecting the process are identified. Then an FEM modelling is carried out for the chloride diffusion process. The effects of fly ash and slag on the diffusion coefficient and chloride penetration depth in various mixes of concretes are also analyzed through integrating Virtual RCPT Lab and FEM.

Research on chloride ion diffusivity of concrete subjected to CO2 environment

  • Zhang, Shiping;Zhao, Binghua
    • Computers and Concrete
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    • 제10권3호
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    • pp.219-229
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    • 2012
  • Carbonation is a widespread degradation of concrete and may be coupled with more severe degradations. An experimental investigation was carried out to study the effect of carbonation on chloride ion diffusion of concrete. The characteristic of concrete after carbonation was measured, such as carbonation depth, strength and pore structure. Results indicated that carbonation depth has a good linear relation with square root of carbonate time, and carbonation can improve compressive strength, but lower flexural strength. Results about pore structure of concrete before and after carbonation have shown that carbonation could cause a redistribution of the pore sizes and increase the proportion of small pores. It also can decrease porosities, most probable pore size and average pore diameters. Chloride ion diffusion of concrete after carbonation was studied through natural diffusion method and steady state migration testing method respectively. It is supposed that the chloride ion concentration of carbonation region is higher than that of the sound region because of the separation of fixed salts, and chloride ion diffusion coefficient was increased due to carbonation action evidently.

부산지역 레미콘사의 콘크리트의 압축강도와 염소이온 확산계수 (Chloride Ion Diffusion Coefficient and Compressive Strength of the Concrete Produced by Ready Mixed Concrete Company in Busan)

  • 박동천;방중석;김용로;이태규
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
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    • pp.11-12
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    • 2017
  • The properties of concrete produced by ready mixed concrete company in Busan were tested. Because the concrete was mixed with blast furnace slag and fly ash, the compressive strength and chloride ion diffusion coefficient were lower than OPC concrete even though the specified concrete strength was same. If the durability about salt attack were satisfied, the concrete of lower specified concrete strength would be adopted to concrete mixing design.

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