• Title/Summary/Keyword: Chemical wastewater treatment

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Feasibility of Phosphorus Recovery from Biological Livestock Wastewater Treatment Plant (생물학적 축산분뇨처리시설에서 인 회수의 가능성 평가)

  • Ahn, Johwan;Kim, Jangho;Min, Sungjae
    • Journal of Korean Society on Water Environment
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    • v.32 no.4
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    • pp.343-348
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    • 2016
  • A chemical sequencing batch reactor was operated to test the feasibility of nutrient recovery from a biological livestock wastewater treatment plant. Both phosphate and ammonia could be successfully recovered as magnesium ammonium phosphate (MAP) crystals. The contents of TP and TN in the recovered MAP crystals were 26.2% and 4.0%, respectively. Zn, Cr and Ti were identified in the crystals, but the contents remained below the Korean standard for an organic fertilizer. Chemical analyses confirmed that the MAP crystals could be useful phosphate fertilizers. On the other hand, the results of physical analyses using an X-ray diffractometer and an energy dispersive X-ray spectrometer strongly suggested that crystalline materials like magnesium potassium phosphate (KMP) and hydroxyapatite (HAP) were also formed during the MAP crystallization, depending on the availability of K+ and Ca2+.

Quantitative and Qualitative Assessment of Blow Down Wastewater from Yeosu Industrial Complex (여수석유화학산단 산업폐수 재이용을 위한 블로우 다운 (Blow Down)수 발생현황 조사)

  • Kwon, Tae-Ouk;Moon, Il-Shik
    • Journal of Korean Society on Water Environment
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    • v.21 no.3
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    • pp.289-296
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    • 2005
  • Purpose of this research is to quantitatively and qualitatively investigate the blow down wastewater produced from Yeosu Industrial Complex. Approximately, 38,325,000 tons/year of wastewater is produced, processed and finally discharged. Six representative companies, namely, A, B, C, D, E, F were chosen for this study. Each company produce over 5,000 tons/day of wastewater. In total, 6,844 tons/day of blow down water is produced from these six companies, put together. However, companies A and C produce about 24% and 37% of blow down water, respectively. It was found that the blow down water had favorable qualities, except for its high conductivity, ranging from 230 to $1,700{\mu}s/cm$. It was evident that, this water can be suitable for reuse, for industrial purposes, if a suitable treatment, for example, RO membrane process is adopted to remove high conductivity.

Study of Factors Influenced on denitrification in wastewater treatment (폐수처리 탈질 공정에 미치는 인자 연구)

  • Jeong, Gwi-Taek;Park, Seok-Hwan;Park, Jae-Hee;Bhang, Sung-Hun;Lim, Eun-Tae;Park, Don-Hee
    • KSBB Journal
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    • v.23 no.6
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    • pp.535-540
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    • 2008
  • In this study, the effects of several factors such as initial nitrate concentration, C/N ratio, biomass amount and external carbon source on denitrification process were investigated using synthetic wastewater and sludge obtained from wastewater treatment facility. As a result, the condition of lower initial nitrate concentration was increased to the removal rate of nitrate than that of high concentration. The increases of C/N ratio and initial biomass amount were linearly enhanced the removal rate. The use of ethanol as external carbon source was shown the highest removal yield than that of others.

A Study on Cost-effective Treatment of Wastewater and Odor Reduction for Southeast Asian Market Entry

  • Jung, Min-Jae;Kim, Yong-Do;Kwon, Lee-Seung;Lee, Woo-Sic;Kwon, Woo-Taeg
    • The Journal of Industrial Distribution & Business
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    • v.9 no.12
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    • pp.23-29
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    • 2018
  • Purpose - The purpose of this study is to apply a cost effective ultrasonic odor reduction method that generated micro-bubbles using ejector to the Southeast Asian wastewater market. Research design, data, and methodology - A leather maker located in Ansan-city, Gyunggi-do, South Korea was sampled from the collection tank to select experimental materials. Experimental setup consisted of circulating water tank-air ejector-ultrasonic device, and circulating wastewater. Sample analysis was performed by CODcr, T-N, T-P, and turbidity by the National Environmental Science Institute. Results - Experimental results show that it is most effective in removing odors when the frequency range of ultrasonic wave is 60~80 Khz and the output is 200 W. It showed that the concentration of complex odor dropped from a maximum of 14,422 times to a minimum of 120 times. Also, analysis of ammonia and hydrogen sulfide in specific odor substances has shown that they were reduced from 1.5 ppm to 0.4 ppm and from 0.6 ppm to 0.1 ppm, respectively. Conclusions - It is possible to shorten more than 12 hours in the treatment of micro-organisms. It can be seen that the processing time of odor after ultrasonic treatment in the pre-treatment facility is reduced by 25% when compared to the resultant micro-organisms after the chemical treatment, that is, the time of the bio-treatment of micro-organisms. Based on the results, it was confirmed that the pre-treatment method using the ultrasonic and the air ejector device of the experiment shows the effect of reducing the water pollutants and odor more effectively in a relatively short time than the conventional advanced oxidation method.

Polyvinyl Alcohol 분해 공생 균주에 의한 염색 폐수 중의 PVA 제거

  • Kim, Chul Ki;Choi, Yong-Jin;Lee, Chul-Woo;Rim, Yeon-Taek;Ryu, Jae-Keun
    • Microbiology and Biotechnology Letters
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    • v.25 no.1
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    • pp.89-95
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    • 1997
  • The current processer of the textile wastewater treatment are mostly consisted of a combination of a physico-chemical and a biological treatment. The overall efficiency of these processes is, however, assessed to be fairly low. It is even worse during the summer season when temperature of the wastewater rises above 40$\circ $C. Therefore, a feasible process of the textile wastewater treatment which can work efficiently at higher temperatures was investigated in this work. We used a bench scale reactor consisted of one 4 liter anaerobic and one 8 liter aerobic tank, and the thermophilic symbiotic PVA degraders, Pasteruella hemolytica KMG1 and Pseudomonas sp. KMG6 that had been isolated in our laboratory. In the preliminary flask experiments, we observed that the thermophilic symbiotic PVA degraders could not grow in the wastewater substrate. Then, we isolated the mutant strains by acclimating the KMG1and KMG6 strains to the wastewater medium. The mutant symbionts (KMG1-1 and KMG6-1) were isolated through 6 times successive transfers into the fresh wastewater medium after 5 days culture for each. The mutant strains obtained grew well in the mixed medium composed of 75% wastewater and 25% synthetic medium, and supplemented with 0.5% PVA as a sole carbon source. During the culture for 14 days at pH 7.0 and 40$\CIRC $C, the bacteria assimilated about 89% of the added PVA. The symbionts degraded equally well all the PVA substrates of different molecular weight (nd=500~30000). In contrast to the flask experiments, in the reactor system the mutant strains showed very low levels of the PVA and COD removal rates. However, the new reactor system with an additional aerobic tank attained 82% removal rate of COD, 94% of PVA degradation and 71% of color index under the conditions of 5% inoculm on the tank 2, incubation temperature of 40$\circ $C, dissolved oxygen level of 2~3 mg/l and retention time of 30 hours. This result ensures that the process described above could be an efficient and feasible treatment for the PVA contained textile wastewater at higher temperatures.

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Treatment and Reuse of Acrylic Wastewater using Membrane Separation System

  • Lee, Kwanghyun
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.117-120
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    • 2004
  • The separation characteristics were investigated with the variations of pressure and temperature using ultrafiltration and reverse osmosis membrane module sets composed of different membrane types and materials. TDS, T-N and COD removal efficiencies were not affected and low with the change of temperature and pressure in case of using UF modules contained in module set 1, 2, 3. TDS, T-N and COD removal efficiencies were very high in RO modules. The final water quality of acrylic wastewater was satisfied within the discharge limit value of plant wastewater. It was known that membrane module sets could be used for the reuse of wastewater.

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A Study of Improvement on Collaboration Treatment Method of Electroplating Wastewater (도금폐수의 공동처리를 위한 공정개선에 관한 연구)

  • 이내우;최재욱;안병환
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.93-101
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    • 1997
  • A modified procedure for electroplating wastewater treatment using formaldehyde and hydrogen peroxide can destroy free cyanide. The representative diagram which is quite sensitive on reaction temperature is showed for this kinds of treatment. Principally free cyanide and some kinds of cyanide complex should be treated first, and then toxic heavy metals can be removed because cyanide component will be inhibited to remove other pollutants, if it is not destroyed perfectly. Formaldehyde and hydrogen peroxide are added in controlled amounts to cyanide treatment tank. Reasonable amounts of these chemicals are (HCHO/CN)=0.9 and ($H_2O_2/CN$)=1.1 in molar ratios, it is also variable on reaction temperature. Of course, actual treatment processes depending on plating material and chemical are good applicable, also to systematize operation manual for treating electroplating wastewater process, further works are desirable.

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Mitigation of Membrane Biofouling in MBR Using a Cellulolytic Bacterium, Undibacterium sp. DM-1, Isolated from Activated Sludge

  • Nahm, Chang Hyun;Lee, Seonki;Lee, Sang Hyun;Lee, Kibaek;Lee, Jaewoo;Kwon, Hyeokpil;Choo, Kwang-Ho;Lee, Jung-Kee;Jang, Jae Young;Lee, Chung-Hak;Park, Pyung-Kyu
    • Journal of Microbiology and Biotechnology
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    • v.27 no.3
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    • pp.573-583
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    • 2017
  • Biofilm formation on the membrane surface results in the loss of permeability in membrane bioreactors (MBRs) for wastewater treatment. Studies have revealed that cellulose is not only produced by a number of bacterial species but also plays a key role during formation of their biofilm. Hence, in this study, cellulase was introduced to a MBR as a cellulose-induced biofilm control strategy. For practical application of cellulase to MBR, a cellulolytic (i.e., cellulase-producing) bacterium, Undibacterium sp. DM-1, was isolated from a lab-scale MBR for wastewater treatment. Prior to its application to MBR, it was confirmed that the cell-free supernatant of DM-1 was capable of inhibiting biofilm formation and of detaching the mature biofilm of activated sludge and cellulose-producing bacteria. This suggested that cellulase could be an effective anti-biofouling agent for MBRs used in wastewater treatment. Undibacterium sp. DM-1-entrapping beads (i.e., cellulolytic-beads) were applied to a continuous MBR to mitigate membrane biofouling 2.2-fold, compared with an MBR with vacant-beads as a control. Subsequent analysis of the cellulose content in the biofilm formed on the membrane surface revealed that this mitigation was associated with an approximately 30% reduction in cellulose by cellulolytic-beads in MBR.

The Investigation of Treatment of Pistachio Processing Industrial Wastewater by Electrochemical Methods in Terms of Chemical Oxygen Demand and Total Phenol Removal

  • Alper Erdem Yilmaz;Baybars Ali Fil;Murat Tolga Yilmaz;Serkan Bayar;Zuhal Koksal
    • Journal of Electrochemical Science and Technology
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    • v.15 no.1
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    • pp.178-189
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    • 2024
  • This work aims to investigate the efficiency of electrocoagulation (EC) of pistachio processing industrial wastewater (PPIW) using the continuous EC process. The tubular reactor made of stainless steel with an internal diameter of 60 mm was used as a cathode electrode. The effect of some parameters was examined on the removal of chemical oxygen demand (COD) and total phenols (TP) removal efficiency. The influences of the initial pH of wastewater (from 4 to 8), flow rate (from 25 to 125 mL/min), current density (from 7 to 21 mA/cm2), and supporting electrolyte type (NaCl, NaNO3, and Na2SO4), supporting electrolyte concentration (from 10 to 100 mg/L NaCl) on removal efficiency were investigated to determine the best experimental conditions. The examination of the physico-chemical parameters during the EC treatment showed that the best removal efficiency was obtained under conditions where the flow rate was 25 mL/min (20 min reaction time), the pH value was 5.2, and the current density was 21 mA/cm2 has set. Under these experimental conditions, COD and TP removal efficiency were found to be 75% and 97%, respectively, while energy consumption was 18.5 kW h/m3. The study results show that the EC can be applied to PPIW pre-treatment.

Integrated Wet Oxidation and Aerobic Biological Treatment of the Wastewater Containing High Concentration of Phenol (고농도 페놀 폐수의 습식산화와 호기성 생물학적 통합처리)

  • Choi, Ho-Jun;Lee, Seung-Ho;Yu, Yong-Ho;Yoon, Wang-Lai;Suh, II-Soon
    • KSBB Journal
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    • v.22 no.4
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    • pp.244-248
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    • 2007
  • The treatment of a model wastewater containing high concentration, 10 $g/{\ell}$, of phenol in an integrated wet oxidation-aerobic biological treatment was investigated. Partial wet oxidation under mild operating conditions was capable of converting the original phenol to biodegradable organic acids such as maleic acid, formic acid and acetic acid, the solution of which was subjected to the subsequent aerobic biological treatment. The wet oxidation was carried out at 150$^{\circ}C$ and 200$^{\circ}C$ and the initial pH of 1 to 12. The high temperature of 200$^{\circ}C$ and the acidic initial condition in the wet oxidation led to effluents of which biodegradability was higher in the subsequent biological oxidation process, as assessed by chemical oxygen demand (COD) removal. Homogeneous catalyst of $CuSO_4$ was also used for increasing the oxidation rate in the wet oxidation at 150$^{\circ}C$ and initial pH of 3.0. However, the pretreatment with the catalytic wet oxidation resulted in effluents which were less biodegradable in the aerobic biological process compared to those out of the non-catalytic wet oxidation at the same operating conditions.