• 제목/요약/키워드: Chemical shrinkage

검색결과 266건 처리시간 0.028초

Injection Molding of Vertebral Fixed Cage Implant

  • Yoo, Kyun Min;Lee, Seok Won;Youn, Jae Ryoun;Yoon, Do Heum;Cho, Yon Eun;Yu, Jae-Pil;Park, Hyung Sang
    • Fibers and Polymers
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    • 제4권2호
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    • pp.89-96
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    • 2003
  • A vertebral cage is a hollow medical device which is used in spine forgery. By implanting the cage into the spine column, it is possible to restore disc and relieve pressure on the nerve roots. Most cages have been made of titanium alloys but they detract the biocompatibility. Currently PEEK (polyether ether ketone) if applied to various implants because it has good properties like heat resistance, chemical resistance, strength, and especially biocompatibility. A new shape of vertebral cage is designed and injection molding of PEEK is considered for production. Before injection molding of the cage, it is needed to evaluate process conditions and properties of the final product. Variables affecting the shrinkage of the cage are considered, e.g., injection time, packing pressure, mold temperature, and melt temperature. By using the numerical simula-tion program, MOLDFLOW, several cases are studied. Data files obtained by MOLDFLOW analysis are used for stress anal-ysis with ABAQUS, and shrinkage and residual stress fields are predicted. With these results, optimum process conditions are determined.

Improvement of precision of three-dimensional ceramic microstructures employing silica nanoparticle-mixed precursor (나노 실리카분말의 충진효과를 이용한 극미세 3차원 세라믹 구조물 정밀화)

  • Lim T.W.;Park S.H.;Yang D.Y.;Pham Tuan Anh;Kim D.P.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.157-158
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    • 2006
  • A novel nanofabrication process has been developed using two-photon crosslinking (TPC) for the fabrication of three-dimensional (3D) SiCN ceramic microstructures applicable to high functional 3D devices, which can be used in harsh working environments requiring a high temperature, a resistance to chemical corrosion, as well as tribological properties. After sequential processes: TPC and pyrolysis, 3D ceramic microstructures are obtained. However, large shrinkage due to low-ceramic yield during the pyrolysis is a serious problem to be solved in the precise fabrication of 3D ceramic microstructures. In this work, silica nanoparticles were employed as a filler to reduce the amount of shrinkage. In particular, the ceramic microstructures containing 40 wt% silica nanoparticles exhibited relatively isotropic shrinkage owing to its sliding free from the substrate during pyrolysis.

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Effects of Alkaline Treatment on the Characteristics of Chemical Pulps for Papermaking (알칼리 처리가 제지용 화학펄프의 특성에 미치는 영향)

  • Won, Jong-Myoung;Kim, Min-Hyun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • 제43권3호
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    • pp.106-112
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    • 2011
  • The effects of alkaline treatment on the WRV, crystalline structure and sheet structure of softwood and hardwood bleached kraft pulp were investigated. Sodium hydroxide and sodium carbonate were used as chemicals for alkaline treatment and two levels of alkali dosage (5%, 10%) were applied respectively. Alkali treated and untreated pulp were refined to three levels (550, 450 and 350 mL CSF). WRV of the alkali treated pulps depended on the alkaline type and concentration. It was found that the crystalline structures of softwood and hardwood pulp were not changed by refining. Sodium carbonate and lower concentration of sodium hydroxide treatment did not caused any modification of cellulose crystalline structure, while higher concentration of sodium hydroxide treatment caused the partial modification of cellulose crystalline structure. Alkaline treatment of hardwood bleached kraft pulp led to the shrinkage of fiber diameter and bulky structure of sheet. Alkaline treatment of softwood bleached kraft pulp did not cause the significant change in fiber shrinkage and bulk of sheet.

A Study on Reducing Deterioration in Long-span Slab Concrete (장스팬 슬라브 콘크리트의 열화저감에 대한 연구)

  • Kim, Dae-Geon;Cha, Hun;Choi, Sang-Hwan;Moon, Kyeong-Sik
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 한국건축시공학회 2014년도 추계 학술논문 발표대회
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    • pp.11-12
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    • 2014
  • In this study, fundamental properties of concrete mixed with fiber has been analysed. Compressive strength, tensile strength and plastic shrinkage has been tested to conduct the optimum addition ratio of fiber. Effect to control press concrete's cracking has been tested. The following results could be made as the conclusion. For the flowability, slump decreased about 41-79% when all types of fiber used in the concrete. When the addition ratio of fiber is 1.2%, the slump of concrete decreased about 45%. For the strength properties. all the specimens with different addition ratio of fiber shown higher compressive strength comparing with Plain. Comparing with Plain, cracking decreased when the fiber added. Especially, when NY fiber used in the concrete, the plastic shrinkage did not occurred. In addition, Latex modified concrete(LMC) has improved superior physical and chemical properties. The properties of latex, combined with the low water-cement ratio, produce a concrete that has improved flexural, tensile, and bond strength, lower modulus of elasticity, increased freeze-thaw resistance, and reduced permeability compared to conventional concrete of similar mix design.

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Prediction of Spring-in of Curved Laminated Composite Structure (굴곡 형상 복합재 구조물의 스프링-인 예측)

  • Oh, Jae-Min;Kim, Wie-Dae
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • 제43권1호
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    • pp.1-7
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    • 2015
  • This paper predicts the spring-in effect of curved laminated composite structure for various stacking sequence using finite element analysis(ABAQUS). In composite manufacturing process, large temperature difference, different coefficient of thermal expansion and chemical shrinkage effect cause distortion of composite parts such as spring-in and warpage. Distortion of composite structure is important issue on quality of product, and it should be considered in manufacturing process. In finite element analysis, a CHILE(Cure Hardening Instantaneously Linear Elastic) model and chemical shrinkage effects are considered developing user subroutine in ABAQUS and some cases are simulated.

Initial Behavior and Shrinkage Properties of Lime Mortars for Restoration of Cultural Heritage According to the Mixing Ratio (석회 종류와 배합비 별 문화재 보수용 석회 모르타르의 초기거동특성과 수축특성 연구)

  • Nam, Byeong Jik;Noh, Sang Kyun;Kim, Eun Kyung;Ahn, Sun Ah;Kang, So Yeong
    • Journal of Conservation Science
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    • 제36권6호
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    • pp.456-474
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    • 2020
  • This study investigated the initial behavior (flowability and setting properties) and shrinkage characteristics of lime mortar, based on the mixing ratio of hydrated lime (lump, powder) and commercial lime, which is primarily used for repairing and restoring cultural assets. The flowability showed that the optimum mixing water contents of the masonry lime mortar were 8-10% for the lump hydrated lime, 10-18% for the powdered hydrated lime, and 17-40% for the commercial hydrated lime. The results of the setting and shrinkage analysis showed that the average final setting time ratio compared to the standard of cultural asset repair was in the increasing order of commercial hydrated lime(0.4) < powder hydrated lime(5.6) < lump hydrated lime(5.7). Moreover, the average shrinkage ratio was ordered as lump hydrated lime(1.1) < powder hydrated lime(1.2) < commercial hydrated lime(3.0). The analysis of the physical and chemical characteristics of hydrated lime showed that the optimum mixing water content was reduced as the particle size of the lime increased, thus delaying the setting time and decreasing the length change rate (shrinkage). These results are expected to contribute to the prediction of the initial behavior and shrinkage characteristics of mortars using handmade and commercial lime during repair and restoration work on cultural, heritage buildings.

Effect of carbonization temperature and chemical pre-treatment on the thermal change and fiber morphology of kenaf-based carbon fibers

  • Kim, Jin-Myung;Song, In-Seong;Cho, Dong-Hwan;Hong, Ik-Pyo
    • Carbon letters
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    • 제12권3호
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    • pp.131-137
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    • 2011
  • Kenaf fibers, cellulose-based natural fibers, were used as precursor for preparing kenafbased carbon fibers. The effects of carbonization temperature ($700^{\circ}C$ to $1100^{\circ}C$) and chemical pre-treatment (NaOH and $NH_4Cl$) at various concentrations on the thermal change, chemical composition and fiber morphology of kenaf-based carbon fibers were investigated. Remarkable weight loss and longitudinal shrinkage were found to occur during the thermal conversion from kenaf precursor to kenaf-based carbon fiber, depending on the carbonization temperature. It was noted that the alkali pre-treatment of kenaf with NaOH played a role in reducing the weight loss and the longitudinal shrinkage and also in increasing the carbon content of kenaf-based carbon fibers. The number and size of the cells and the fiber diameter were reduced with increasing carbonization temperature. Morphological observations implied that the micrometer-sized cells were combined or fused and then re-organized with the neighboring cells during the carbonization process. By the pre-treatment of kenaf with 10 and 15 wt% NaOH solutions and the subsequent carbonization process, the inner cells completely disappeared through the transverse direction of the kenaf fiber, resulting in the fiber densification. It was noticeable that the alkali pre-treatment of the kenaf fibers prior to carbonization contributed to the forming of kenaf-based carbon fibers.

A Study on Monte Carlo Simulation in Resin of New Austria Tunnel Method by admixture for Shrinkage Compensating Concrete (무수축 콘크리트 혼화제를 활용한 New Austria Tunnel Method 수지에서 Monte Carlo 시뮬레이션에 관한 연구)

  • Kim, Ki-Jun;Sung, Wan-Mo;Kim, Joo-Han;Jung, Hyung-Hak
    • Journal of the Korean Applied Science and Technology
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    • 제34권1호
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    • pp.125-131
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    • 2017
  • The influences of scatterer and absorber in turbid material by light scattering in concrete admixture were interpreted for the scattered intensity and wavelength. The molecular properties have been studied by Monte Carlo simulation in resin of New Austria Tunnel Method. It has been found that the effects of optical properties in scattering media could be investigated by the optical parameters(${\mu}_s$, ${\mu}_a$,${\mu}_t$). Monte Carlo Simulation method for modelling of light transport in the civil engineering and construction field was applied. The results using a phantom were discussed that the admixture for shrinkage compensating concrete in NATM-rasin from source to detector is measured, and scattering intensity is stronger with those obtained through Monte Carlo Simulation. It may also aid in designing the best model for coatings and corrosion for the durability of metal constructions.

Preparation and Performance of Aluminosilicate Fibrous Porous Ceramics Via Vacuum Suction Filtration

  • Qingqing Wang;Shaofeng Zhu;Zhenfan Chen;Tong Zhang
    • Korean Journal of Materials Research
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    • 제34권1호
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    • pp.12-20
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    • 2024
  • This study successfully prepared high-porosity aluminosilicate fibrous porous ceramics through vacuum suction filtration using aluminosilicate fiber as the primary raw material and glass powder as binder, with the appropriate incorporation of glass fiber. The effects of the composition of raw materials and sintering process on the structure and properties of the material were studied. The results show that when the content of glass powder reached 20 wt% and the samples were sintered at the temperature of 1,000 ℃, strong bonds were formed between the binder phase and fibers, resulting in a compressive strength of 0.63 MPa. When the sintering temperatures were increased from 1,000 ℃ to 1,200, the open porosity of the samples decreased from 89.08 % to 82.38 %, while the linear shrinkage increased from 1.13 % to 10.17 %. Meanwhile, during the sintering process, a large amount of cristobalite and mullite were precipitated from the aluminosilicate fibers, which reduced the performance of the aluminosilicate fibers and hindered the comprehensive improvement in sample performance. Based on these conditions, after adding 30 wt% glass fiber and being sintered at 1,000 ℃, the sample exhibited higher compressive strength (1.34 MPa), higher open porosity (89.13 %), and lower linear shrinkage (5.26 %). The aluminosilicate fibrous porous ceramic samples exhibited excellent permeability performance due to their high porosity and interconnected three-dimensional pore structures. When the samples were filtered at a flow rate of 150 mL/min, the measured pressure drop and permeability were 0.56 KPa and 0.77 × 10-6 m2 respectively.

BCB Polymer Dielectrics for Electronic Packaging and Build-up Board Applications

  • Im, Jang-hi;Phil-Garrou;Jeff-Yang;Kaoru-Ohba;Masahiko-Kohno;Eugene-Chuang;Jung, Moon-Soo
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 한국마이크로전자및패키징학회 2000년도 Proceedings of 5th International Joint Symposium on Microeletronics and Packaging
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    • pp.19-25
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    • 2000
  • Dielectric polymer films produced from benzocyclobutene (BCB) formulations (CYCLOTENE* family resins) are known to possess many desirable properties for microelectronic applications; for example, low dielectric constant and dissipation factor, low moisture absorption, rapid curing on hot plate without reaction by-products, minimum shrinkage in curing process, and no Cu migration issues. Recently, BCB-based products for thick film applications have been developed, which exhibited excellent dissipation factor and dielectric constant well into the GHz range, 0.002 and 2.50, respectively. Derived from these properties, the applications are developed in: bumping/wafer level packaging, Ga/As chip ILD, optical waveguide, flat panel display, and lately in BCB-coated Cu foil for build-up board. In this paper, we review the relevant properties of BCB, then the application areas in bumping/wafer level packaging and BCB-coated Cu foil for build-up board.

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