• Title/Summary/Keyword: Chemical phenomena

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고형 폐기물층 연소에 관한 연구 (A study on the bed combustion of solid waste)

  • 신동훈;최상민
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
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    • pp.1-8
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    • 1998
  • Waste combustion above a grate is the core process of incineration systems, stability of which should be guaranteed for emission minimization. However, complicated reactions and heat and mass transfer phenomena make understanding the process difficult. One dimensional bed combustor with a numerical combustion model is utilized to investigate the combustion process of the bed, using cubic wood particles as a simulated fuel. Bed combustion behavior is characterized with apparent flame propagation speed, which has close relationship with air supply rate and chemical and physical characteristics of the fuel. Base on the availability of oxygen, two distinct reaction zone is identified; the oxygen-limited and the reaction-limited zone leading to the extinction by excessive convection cooling. The numerical modeling shows good agreement with the experimental results. The transient bed combustion behavior of local temperature and oxygen consumption rate is adequately reproduced. The numerical model is extended to model the waste bed combustion of a commercial incineration plant, which shows meaningful results as well.

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에탄올아민화합물 첨가에 대한 니켈의 전기화학적 특성 (Electrochemistry Characterization of Nickel Using Ethanolamine Compound Additives)

  • 박근호
    • 한국응용과학기술학회지
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    • 제27권4호
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    • pp.531-538
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    • 2010
  • The electrochemistry characterization of metal is important in many industrial applications. In this study, we investigated the C-V diagrams related to the electrochemistry characterization of nickel. We determined electrochemical measurement by using cyclic voltammetry with a three electrode system. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650mV and measured to the initial point. The scan rate were 100, 150, 200 and 200mV/s. As a result, the C-V characterization of nickel using ethanolamine and ethylethanolamine inhibitor appeared irreversible process caused by the oxidation current from the cyclic voltammogram. After adding ethanolamine compound additive, adsorption film constituted, and the passive phenomena happened. According to the results by cyclic voltammetry method, it was revealed that the effect of the electrochemistry characterization of nickel depends on ethanolamine structure interaction to adsorption complex.

$n-TiO_2$ 분말의 저압화염 합성에 미치는 전구체 전달속도의 영향 (The Effect of the Precursor Delivery Rate on low Pressure Flame Synthesis of $n-TiO_2$ Powder)

  • 김태형
    • 한국분말재료학회지
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    • 제6권1호
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    • pp.75-80
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    • 1999
  • The formation of $n-TiO_2$ powder by oxidation of Ti-ethoxied vapor in a flat flame burner reactor maintained under 20 torr has been studied. The produced powder were characterized in terms of crystal structure, chemical composition by XRD and TEM. The results showed that the powder consisted of loose agglomerated anatase and rutile particles and their size were about 10 nm and 20 nm, respectively. In the course of synthesis, changes of the flame color were happened to each condition during heating up the bubbler. The flame color transition phenomena reveled that a critical precursor delivery rate was needed for the powder formation (obtainable powder yield). The critical precursor delivery rate was estimated by a simple function of the bubbler temperature and the carrier gas flow rate. The critical precursor delivery rate was reviewed as an important variable of the nanopowder synthesis.

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IR 불꽃화재감지기 개발

  • 권오승;이복영;박상태
    • 방재기술
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    • 통권29호
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    • pp.39-45
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    • 2000
  • All objects emit thermal radiation and this radiation is the basis of the techniques used to detect flames. The usual phenomena occurring in the initial stage of a fire are generally invisible products of a combustion and visible smoke. Liquid or gaseous materials do not undergo a smoldering stage such fires develop very rapidly. Also, the heat generated by the initial flames is usually not sufficient to active a heat detector. In this case the most effective criterion for automatic fire detection is the flame. In fire regulation of korea, the compulsory standard provided that a flame detector shall be installed a place of the attachment hight of detector is higher than 20 m, chemical plants, hangar, refinery, etc.. The result of the research and development are discriminated between a flame and other radiant emitters, developed PZT pyroelectric element is based on the use of photo-voltanic cell, developed IR band-pass filter that only allow a 4.3 radiation wavelength to reach the sensors and developed IR flame detector.

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가황(加黃)고무에 함유(含有)된 충전제(充塡劑)에 대(對)한 적외선분광분석(赤外線分光分析) 연구(硏究) (Infrared Studies of the Rubber-Filler System)

  • 서원동;백남철
    • Elastomers and Composites
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    • 제13권2호
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    • pp.99-107
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    • 1978
  • The measurement of the infrared absorption spectrum of supporting reinforcing filler which is oltained from the domestic area of Korea, Japan and U.S.A., is used by the method of KBr pellet. As a result of experiment, each absorption fond of the filler had appeared differently, because of each filler is consisted of different chemical composition, different crystalline form, different method of preparation, and the different ways of use etc. According to the above phenomena, each filler seems to have a different characteristic infrared absorption band, We can find what filler is used for sample rubber.

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Numerical Analysis of Solid Propellant Ignition ~Numerical Formulation Assessment~

  • Shimada, Toru;Novozhilov, Boris V.
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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    • pp.528-531
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    • 2004
  • For a simple one-dimensional ignition problem a mathematical model is described to investigate the difficulties in numerical simulations. Some computation results are obtained and comparison is made with analytical solution. Discussions are made on topics such as 1) coordinate transformation, 2) gas-phase and solid-phase analysis; (divergence form of the governing system, a finite-volume discretization, implicit time integration, upwind split flux, spatial accuracy improvement are described. Mass, reagent mass, and energy conservations are solved.), and 3) method to determine quantities on the burning surface (matching). Results obtained for small values of the non-dimensional pressure show a steady-combustion and good agreement with the analytical solution. Numerical instability appeared for larger values of the pressure, discussion on the cause of the problem is made. This effort is a part of a study of flame spread phenomena on solid propellant surface.

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온도.습도분포 및 혼화재를 고려한 염분침투에 관한 연구 (A Study About Chloride Penetration Considering Temperature, Humidity Distribution and Admixtures)

  • 최종권;김기현;차수원;장승엽;장승필
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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    • pp.553-556
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    • 2006
  • Chloride penetration is the main reason which causes the deterioration of concrete structures. Chloride penetration of concrete structures due to chemical-physical phenomena can be profitably analyzed by means of model-based simulations. The main purpose of this paper is to analyze chloride penetration considering self-desiccation, convection and admixture(GBFS: granulated blast-furnace slag) effects. Basic governing equations are modified properly to apply these effects to chloride penetration analysis. Temperature and relative humidity data of In-Cheon from Korea Meteorological Administration are used for analyzing chloride penetration.

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Vortex Tube의 부분유입율과 저온 입.출구비가 에너지분리 특성에 미치는 영향 (Effects of the partial admission rate and cold flow inlet-outlet ratio on energy separation of Vortex Tube)

  • 김정수;추홍록;상희선
    • 한국안전학회지
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    • 제13권3호
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    • pp.51-59
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    • 1998
  • The vortex tube is a simple device for separating a compressed fluid stream into two flows of high and low temperature without any chemical reactions. Recently, vortex tube is widely used to local cooler of industrial equipments and air conditioner for special purpose. The phenomena of energy separation through the vortex tube were investigated to see the effects of cold flow inlet-outlet ratios and partial admission rates on the energy separation experimentally. The experiment was carried out with various cold flow inlet-outlet ratios from 0.28 to 10.56 and partial admission rates from 0.176 to 0.956 by varying input pressure and cold air flow ratio. To find best use in a given cold flow inlet-outlet ratio and partial admission rate, the maximum temperature difference of cold air was presented. The experimental results were indicated that there are an optimum range of cold flow inlet-outlet ratio for each partial admission rate and available partial admission rate.

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Dry Coated Particle for Plasma Spraying

  • Briones-Rodriguez, C.;Mayagoitia-Barragan, V.;Cuenca-Alvarez, R
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.156-157
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    • 2006
  • The preparation of composite powders for plasma spraying by an in-house designed mechanofusion process is investigated. Results show that dry particle coating depends on the chemical and mechanical properties of powders. In metal/oxide and metal/oxide/carbide powder mixtures, fine ceramic particles coat the surface of the metallic coarser particles. A nearly rounded shape of the final composite particles is induced by the mechanical energy input with no formation of new phases. However with the carbide/metal powdered system, only an intimate mixture of components is achieved. It is suggested that the coating mechanism is governed by agglomeration and rolling phenomena.

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절연진단용 광섬유 센서의 초음파 검출특성 (Ultrasonic-detection characteristics of optical-fiber sensor for insulation diagnosis)

  • 이상훈;심승환;이광식;김달우
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.183-186
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    • 2002
  • It is well known that a discharge in oil is the source of various physical and chemical phenomena. One of them is ultra-sonic wave, and its detection is a useful method to the diagnosis of the transformer insulation condition. Conventionally, ultra-sonic waves are detected by Piezo-electric trans-ducer(PZT), and we use optical method that has many advantages. In this paper, we constructed a Mach-Zehnder interferometer with optical fiber and investigated the principle of operation. Test of the ultrasonic-detecting ability was performed for both of PZT and fiber-optic sensor. Discharge test arrangement is based on the needle-plane electrode system in oil and applied AC high voltage. Ultrasonic waves were detected and showed time-delay characteristics. We analyzed the data with frequency domain and wavelet transform.

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