• 한국자동차공학회논문집
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• 제21권3호
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• pp.74-81
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• 2013

Due to its accuracy and efficiency, reduced kinetic mechanism of diesel surrogate is widely used as fuel model when applying 3-D diesel engine simulation. But for the well-developed prediction of diesel surrogate reduced kinetic mechanism, it is important to know some meaningful factors which affect to ignition delay time. Meanwhile, ignition delay time consists of two parts. One is the chemical ignition delay time related with the chemical reaction, and the other is the physical ignition delay time which is affected by physical behavior of the fuel droplet. Especially for chemical ignition delay time, chemical properties of each fuel were studied for a long time, but researches on their mixtures have not been done widely. So it is necessary to understand the chemical characteristics of their mixtures for more precise and detailed modeling of surrogate diesel oil. And it shows same ignition trend of paraffin mixture with those of single component, and shorter ignition delay at low/high initial temperature when mixing paraffin and toluene.

• Bulletin of the Korean Chemical Society
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• 제18권10호
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• pp.1071-1075
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• 1997

Detonation characteristics of acetylene were studied behind reflected shock waves in the temperature range 800-1350 K by monitoring OH emission and pressure profiles. For a comprehensive measurement of ignition delay time, the mixture composition was varied in a wide range of Ar mole % was varied from 0.625 to 2.5 in stoichiometric ratio of C2H2-O2-Ar. A computer simulation study was also performed to elucidate the important elementary steps determining ignition behavior. The 33-reaction mechanism provides a good agreement in delay time between the observed and the calculated ones.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제44회 KOSCO SYMPOSIUM 초록집
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• pp.279-281
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• 2012

A short chemical mechanism was developed with the chemical model reduction strategy based on the use of Simulation Error Minimization Connectivity Method(SEM-CM). We examined the accuracy resulting from using this mechanism, as compared with the full mechanism, for premixed flames and auto-ignition of methane-air mixture under high pressures. These comparisons are in good agreement, but it has a little divergence to predict the ignition delay time at high pressure conditions as compared with experiment results.

• Bulletin of the Korean Chemical Society
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• 제22권3호
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• pp.303-307
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• 2001

The ignition of propane was investigated behind reflected shock waves in the temperature range of 1350-1800 K and the pressure range of 0.75-1.57 bar. The ignition delay time was measured from the increase of pressure and OH emission in the C3H8-O2-Ar system. The relationship between the ignition delay time and the concentrations of propane and oxygen was determined in the form of mass-action expression with an Arrhenius temperature dependence. The numerical calculations were also performed to elucidate the important steps in the reaction scheme of propane ignition using various reaction mechanisms. The ignition delay times calculated from the mechanism of Sung et al.1 were in good agreement with the observed ones.

• 한국안전학회지
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• 제25권1호
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• pp.17-21
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• 2010

The chemistry and ignition delay of hydrogen/air/HFP premixed mixtures was investigated numerically with unsteady perfectly stirred reactor(PSR). The detailed chemistry of 93 species and 817 reaction mechanism was introduced for hydrogen/air/HFP mixtures. The results shows the temporal concentration variations of major or reactants such as hydrogen and oxygen during autoignition were similar to the spatial distribution of premixed flame while water vapor produced at the ignition temperature was decomposed later, which can be clarified with the relate species production rates that the the re-growth (or shoulder) of OH concentration is a result of F radicals attacking $H_20$ forming OH and HF. For the stoichiometric $H_2$/air mixture inhibited by 20% HFP, HFP thermal decomposition reaction prevails over the radical attack such as H at initial stage. Even though relatively large HFP addition contributes to delay the ignition, chemical effect on the ignition delay is not effective because of late thermal decomposition of HFP. The most small ignition delay was observed at a slightly fuel lean condition ($\phi$ = 0.9), and temperature dependency of ignition delay was clearly shown near 900 K.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.1704-1709
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• 2004

New reduced chemical kinetic mechanism for prediction of autoignition process of HSDI diesel engine was investigated. For precise prediction of the ignition characteristics of diesel fuel, mechanism coefficients were fitted by the experimental results of ignition delay of diesel spray in a constant volume vessel. Ignition delay of diesel engine on various operation condition was calculated based on the new reduced chemical mechanism. The calculation results agreed well with experimental data.

• 한국안전학회지
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• 제36권3호
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• pp.1-6
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• 2021

Hydrogen is considered a cleaner energy source than fossil fuels. As a result, the use of hydrogen in daily life and economic industries is expected to increase. However, the use of hydrogen energy is currently limited because of safety issues. The rate of combustion of the hydrogen mixture is about seven times higher than that of hydrocarbon fuels. The hydrogen mixture is highly flammable and has a low minimum ignition energy. Therefore, it presents considerable risks for fire and explosions in all areas of hydrogen manufacturing, transportation, storage, and use. In this study, the auto-ignition characteristics of hydrogen were investigated numerically for diluted hydrogen mixtures. Auto-ignition temperature, a critical property predicting the fire and explosion risk in hydrogen combustion, was determined in well-stirred reactors. When N₂ and CO₂ were used to dilute the hydrogen/air mixture, the ignition delay time increased with increasing dilution ratios in both cases. The CO₂-diluted mixtures exhibited a longer ignition delay than the N₂-diluted mixtures. We also confirmed that lower initial ignition temperatures increased the ignition delay times at 950 K and above. Overall, the auto-ignition characteristics, such as the concentrations of participating species and ignition delay times, were primarily affected by the initial temperature of the mixture.

• Bulletin of the Korean Chemical Society
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• 제25권2호
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• pp.293-297
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• 2004

The ignition of monomethylamine was studied in reflected shock waves over the temperature range of 1255- 1579 K and the pressure range of 1.04-1.51 bar. The ignition delay time was measured by the sudden increase of pressure profile and the radiation emitted by OH radicals. The relationship between the ignition delay time and the concentrations of monomethylamine and oxygen was determined in the form of mass-action expressions with an Arrhenius temperature dependence. In contrast to the behavior observed in hydrocarbons, monomethylamine acts to accelerate rather than inhibit its own ignition. And numerical modeling of the ignition of $CH_3NH_2$ has also been carried out to test the several kinetic mechanisms.

• 대한화학회지
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• 제48권1호
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• pp.12-16
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• 2004

에탄올-산소-아르곤 혼합기체의 점화 과정을 반사 충격파를 이용 1281-1625 K의 온도 범위 및 0.69-1.06 bar 압력 범위에서 고찰하였다. 점화지연시간은 급격한 압력변화와 광 방출 스펙트럼으로부터 측정하였으며, 에탄올 및 산소 기체의 농도 그리고 반응온도에 따른 점화지연시간의 의존관계를 나타내는 실험식을 구할 수 있었다. 실험결과 에탄올 점화 과정에서 연료인 에탄올의 농도가 커지면 점화지연시간이 길어지는 경향을 보였으며, 이는 메탄올 점화 과정에서 메탄올의 농도가 증가하면 점화 과정이 짧아지는 것과는 다른 경향이었다. 그리고 에탄올 점화 과정에 관하여 보다 자세히 고찰하기 위해 다양한 에탄올 연소반응 메카니즘을 이용하여 모델 연구를 수행하였다.

• 대한기계학회논문집B
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• 제39권12호
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• pp.945-952
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• 2015

본 연구에서는 바이오매스 합성가스를 모사하여 합성가스의 주요성분에 따른 자착화 특성을 실험 및 수치적으로 고찰하였으며, 온도, 혼합물의 조성, 압력의 변화가 자착화 특성에 미치는 영향을 분석하였다. 충격파관(Shock Tube)을 이용하여 모사 합성가스의 점화지연 시간을 측정하였고, 수치해석은 실험결과 검증과 연소과정 중 중간화학종 분석을 위해 상용프로그램인 CHEMKIN-PRO를 사용하였다. 모든 온도 조건에서 혼합물 내의 수소의 몰 비율이 증가함에 따라 점화지연 시간이 감소하는 현상을 확인할 수 있었다. 1150K 이상의 온도 조건에서 압력이 증가함에 따라 점화지연 시간이 감소하는 현상을 확인 할 수 있었다. 하지만 1150K 이하의 온도 조건에서는 압력이 증가함에 따라 점화지연 시간이 증가하는 현상을 확인할 수 있었다.