• Title/Summary/Keyword: Chemical factors

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Soil Geochemical Exploration of the Mt. Subang Area of the Southern Part of the Bandung, Indonesia (인도네시아 반둥 남부 수방산지역에서의 토양지화학 탐사)

  • 김인준;이재호;이사로;서정률;김유봉;이규호
    • Economic and Environmental Geology
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    • v.37 no.2
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    • pp.173-184
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    • 2004
  • The geochemical exploration was carried out of the soil systems in the survey areas(Mt. Subang area). The chemical values of soil samples for soil in this area are defined such as over values of Ag : 11 ppm(Average : 1.91 ppm), Au 548 ppb(Average 42.39 ppb), Cu : 89 ppm(Average:51.40 ppm), Pb:190 ppm(Average : 23.69 ppm), Zn : 157 ppm(Average : 61.78 ppm), respectively. Anomalous areas for each element have been chosen based on the factors such as, geologic settings, geochemical survey, chemical analysis of ore, chemical analysis of soil. statistical processing of the chemical analysis. Therefore, multi-elements anomalies area were recognized in the east-center part of the study area.

Process Optimization for Life Extension of Electropolishing Solution using Half Round Bus Bar (반구형 부스바를 이용한 전해연마액 수명연장을 위한 공정 최적화)

  • Kim, Soo Han;Lee, Seung Heon;Cho, Jaehoon;Lim, Dong-Ha;Choi, Joongso;Park, Chulhwan
    • Journal of the Korean institute of surface engineering
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    • v.49 no.5
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    • pp.447-453
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    • 2016
  • In this study, we intended to extend the life of electropolishing solution through the reduction of electric resistance by improving the electrolysis efficiency. The optimum conditions were obtained by half round bus bar and Taguchi method. As the main control factors in the electropolishing process, current density, polishing time, electrolyte temperature and flow rate were selected. The electrolyte temperature was the most significant to the electrolysis efficiency. The optimum conditions for the life extension of electropolishing solution were as follows: current density, $45A/dm^2$; polishing time, 6 min; electrolyte temperature, $70^{\circ}C$; flow rate, 11 L/min. As a results of ANOVA of SN ratios, it was found that the electrolyte temperature was significant factor at the 90% confidence level.

The effect of backing layer for pro membranes and modules (PRO 분리막 및 모듈성능에 지지체가 미치는 영향)

  • Han, Man Jae;Jeon, Eun Joo;Sim, Yeon-Ju;Lee, Jong Hwa
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.5
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    • pp.553-559
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    • 2016
  • There has been increasing global interest in the environmental pollution problems produced by fossil fuel consumption and greenhouse gas emissions. In order to tackle these issues, new renewable energy such as solar, wind, bio gas, fuel cell and pressure retarded osmosis(PRO) have been developed extensively. Among these energy sources, PRO is one of the salinity gradient power generation methods. In PRO, energy is obtained by the osmotic pressure generated from the concentration difference between high and low concentration solutions separated by a semipermeable membrane. The development for high power density PRO membranes is imperative with the purpose of commercialization. This study investigates development of thin film composite PRO membrane and spiral wound module for high power density. Also, the influence of membrane backing layer on power density was identified, and the characteristic factors of PRO membranes was determined. Different backing layers were used to improve power density. As expected, the PRO membrane with more porous backing layer showed higher power density.

A Review on Chemical-Induced Inflammatory Bowel Disease Models in Rodents

  • Randhawa, Puneet Kaur;Singh, Kavinder;Singh, Nirmal;Jaggi, Amteshwar Singh
    • The Korean Journal of Physiology and Pharmacology
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    • v.18 no.4
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    • pp.279-288
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    • 2014
  • Ulcerative colitis and Crohn's disease are a set of chronic, idiopathic, immunological and relapsing inflammatory disorders of the gastrointestinal tract referred to as inflammatory bowel disorder (IBD). Although the etiological factors involved in the perpetuation of IBD remain uncertain, development of various animal models provides new insights to unveil the onset and the progression of IBD. Various chemical-induced colitis models are widely used on laboratory scale. Furthermore, these models closely mimic morphological, histopathological and symptomatical features of human IBD. Among the chemical-induced colitis models, trinitrobenzene sulfonic acid (TNBS)-induced colitis, oxazolone induced-colitis and dextran sulphate sodium (DSS)-induced colitis models are most widely used. TNBS elicits Th-1 driven immune response, whereas oxazolone predominantly exhibits immune response of Th-2 phenotype. DSS-induced colitis model also induces changes in Th-1/Th-2 cytokine profile. The present review discusses the methodology and rationale of using various chemical-induced colitis models for evaluating the pathogenesis of IBD.

Effect of Fillers on the Mechanical and Thermal Properties of Glass/Novolac Composites (충전재의 종류에 따른 유리/노볼락 복합재료의 기계적 및 열적 성질 연구)

  • Lee, Soo;Lee, In-Kyu;Park, Sang-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.1
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    • pp.15-22
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    • 2008
  • The effects of fillers on the mechanical and thermal properties of glass/novolac composites have been studied. The matrix polymer and reinforcement were novolac type phenolic resin and milled glass fiber, respectively. Three different fillers, such as calcium carbonate, aluminum oxide, and wood powder were used for glass fiber reinforced plastic(GFRP) manufacture. Gravity, moisture content, tensile and flexural strength were measured to analyze the mechanical properties of GFRP and the final composites was burned in the electronic furnace at $1000^{\circ}C$ to confirm thermal properties GFRP containing aluminium oxide shows the highest thermal stability with 32% of weight loss at $1000^{\circ}C$ for one hour. GFRP containing calcium carbonate shows the maximum flexural strength (146 MPa), but that containing wood powder dose the highest tensile strength (65 MPa). Conclusively, we found that the characteristics of final composites strongly depend on several factors, such as types of materials, contents and chemical affinity of fillers. Therefore, it is very important to set up the combination of fillers for GFRP manufacturing to improve both mechanical and thermal properties at the same time.

A Study on the Synthesis of Alkoxides and Sialon (알콕사이드와 사이알론 합성에 관한 연구)

  • Ho Ha;Heecheol Lee
    • Journal of the Korean Chemical Society
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    • v.32 no.3
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    • pp.267-275
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    • 1988
  • Fine powders of amorphous $Al_2O_3,\;SiO_2,\;Al_2O_3-SiO_2$ system were prepared by hydrolysis of solutions containing alkoxides, aluminium tri-isopropoxide and silicon tetra-ethoxide. High purity ultrafine ${\beta}-sialon$ powders were prepared by the carbothermal reduction-nitridation of amorphous $Al_2O_3-SiO_2$ powders mixed with carbon black as a reducing agent. In the hydrolysis step the effect of the factors such as pH, reaction temperature and amount of water on the conversion rate of alkoxides to oxides was investigated. In the carbothermal reduction-nitridation the reaction path was assumed by the analysis of intermediates formed in the process of ${\beta}-sialon$ synthesis and the reaction kinetics of ${\beta}-sialon$ formation was considered.

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Physicochemical Analysis according to Temperature Changes of Iopamidol and Ioversol Formulation Contrast Agents (Iopamidol과 Ioversol 제제 조영제의 온도변화에 따른 물리화학적 분석)

  • Han, Beom-Hee
    • Journal of radiological science and technology
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    • v.43 no.4
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    • pp.273-280
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    • 2020
  • In this study, the P contrast agent of Iopamidol, which is a nonionic iodide contrast agent most commonly used as a vascular contrast agent in medical institutions, and the O contrast agent of Ioversol, were studied. The physicochemical changes according to the temperature change were compared and analyzed using the Bruker Avance 500MHz Nuclear Magnetic Resonance Spectrometer owned by the Korea Basic Science Institute (KBSI). There was no physical or chemical change in the O contrast medium of Ioversol formulation in temperature change. However, in the P contrast agent of Iopamidol, a doublet peak began to appear in the 1.1 ppm region of the sample at 60℃, and the doublet peak was clearly observed in the sample at 80℃. As a result of this study, 1H-NMR analysis revealed that the P contrast agent of the Iopamidol formulation was dissociated from chemical bonds as it rose to a high temperature of 60℃ or higher, resulting in the formation of foreign substances. It was evaluated that the O contrast agent of Ioversol formulation had physico-chemical stability than the P contrast agent of Iopamidol formulation. As shown in this study, it is necessary to analyze the physical and chemical changes of contrast agents according to various environmental factors.

OPTICAL RESOLUTION OF $\alpha$-AMINO ACIDS USING ENANTIOSELECTIVE MEMBRANES

  • Jonggeon Jegal;Kim, Jang-Hoon;Kim, Jee-Hye;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.61-64
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    • 2003
  • Optical resolution of a-amino acid (tryptophan and tyrosine) optical isomers was achieved by a pressure driven membrane separation process, using self-supporting crosslinked membranes base on polysaccharide with different swelling indices that ranged from 100 to 70%. The membranes prepared by casting and drying the polymer solution containing 5wt% acetic acid on an acryl plate followed by crosslinking with glutaraldehyde were characterized using such analytical methods as FTIR and swelling index measurements. On the way of separating the optical isomers, several experimental factors such as the concentration of the feed solutions, operating pressure and temperature, and degree of crosslinking of the membranes have been studied. When the chitosan membranes with 70% of swelling index were used , almost complete optical resolution was obtained; 97.92% of enantiomeric excess (ee %) and 2.26 g/$m^2$ㆍh of flux. The operating pressure and the concentration of feed solutions were respectively 1.0 kgf/$\textrm{cm}^2$ and 0.49 mmol/L.

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Effect of Fabrication Method of Cathode on OCV in Enzyme Fuel Cells (효소연료전지의 Cathode 제조조건이 OCV에 미치는 영향)

  • Lee, Se-Hoon;Kim, Young-Sook;Chu, Cheun-Ho;Na, Il-Chai;Lee, Jung-Hoon;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.171-174
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    • 2016
  • Enzyme fuel cells were composed of enzyme cathode and PEMFC anode. Enzyme cathode was fabricated by compression of a mixture of graphite particle, laccase as a enzyme and ABTS as a redox mediator, and then coated with Nafion ionomer. Open circuit voltage (OCV) were measured with variation of cathode manufacture factors, to find optimum condition of enzyme cathode. Optimum pressure was 4.0 bar for enzyme cathode pressing process. Highest OCV was obtained at 95% graphite composition in enzyme cathodee. Optimum glucose concentration was 0.4 mol/l in cathode substrate solution.

Recent Trends of Light Induced Bonding-Debonding Adhesives (광을 이용한 해체용 접착소재의 최근 동향)

  • Jeong, Jongkoo;Cho, Seong-keun;Lee, Jae Heung
    • Journal of Adhesion and Interface
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    • v.22 no.2
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    • pp.69-77
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    • 2021
  • A variety of efforts are attempted to make the world sustainable in fabrication industries worldwide. To achieve the goals, a new design concept for products is one of crucial factors to be able to dismantle them after use in easy and simple ways. New debonding technologies have been developed in recent years for the recycle and/or repair of bonded structures, where the bonds are broken without the damage of the components and make recycling easier. Some representative technologies of controlled delamination materials (CDM) are reviewed with an emphasis on light induced debonding of adhesives. We also describe current applications of light induced CDMs as temporary bondable films in semiconductor and display industries.