• 한국지하수토양환경학회지:지하수토양환경
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• 제21권4호
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• pp.20-29
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• 2016

Although a number of chemical accidents have been occurred in South Korea, the effective prevention act for soil contamination has not been established so far. To effectively protect soil contamination from chemical accidents, decision support laws and regulations are absolutely essential. Regarding this situation, this study was aimed at diagnosing problems in current chemical safety management and prevention and response system against chemical accidents through analyzing the domestic and foreign causes of chemical accidents and the accident response procedures and finally suggesting policy measures for solving those problems. In order to clarify management of soil contamination by chemical accident, this study suggests the establishment of chemical accident preparedness, response, and making of local chemical management law and policy. This law needs to be supported by a clear management framework to guide government officials and all other stakeholders in the management of soil contamination by chemical accident.

• Korean Chemical Engineering Research
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• 제60권1호
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• pp.20-24
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• 2022

고분자전해질연료전지 (PEMFC) 장기사용과정에서스택요소의부식및공급가스의오염에의해막전극합체 (MEA)의 화학적 열화가 발생한다. 본 연구에서는 화학적으로 열화된 MEA를 산 세척해서 성능을 회복시킬 수 있는지 연구하였다. 철 이온을 오염시키고 황산 수용액으로 세척하여 PEMFC 셀에서 성능을 측정해 비교했다. 0.5 ppm의 철 이온 오염에 의해 약 25%의 성능 감소가 있었고 0.15 M 황산 세척에 의해 97.1% 성능회복이 가능했다. 고분자 막의 철 이온 오염에 의해 막 저항이 증가했고, 저농도 황산 수용액 세척에 의해 전극 촉매의 손실을 최소화하면서 막에서 철 이온을 세척함으로써 이온전도도가 회복되었다. PEMFC MEA의 화학적 오염에 의한 내구성 감소를 산 세척에 의해 해결할 수 있는 가능성을 확인하였다.

• KSTLE International Journal
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• 제8권1호
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• pp.1-6
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• 2007

Chromatic device was developed using light emitting diodes, optic fibers and photodiodes. Chromatic ratio and total contamination parameters based on transmitted light intensity in Red, Green, and Blue wavelengths were used for oil chemical and particulate contamination assessment. Chromatic ratio criterion was found independent of the particulate contamination of oil; but depended on chemical degradation, being more sensitive for synthetic than mineral hydraulic oil. Total contamination index of the sensor depended on both the chemical degradation and particulate contamination of the oil; being most sensitive in blue wavelength, and least in the red. Test results for synthetic hydraulic oils monitored corroborated with results of other tests such as viscosity, total acid number, elemental optical emission spectroscopy, particulate counts and UV-VIS photospectrometry. Chromatic ratio showed a clearer indication of oil degradation, compared to key monitoring parameters such as total acid number, viscosity and particle counts. The results showed that these parameters are effective criteria for the condition monitoring of synthetic hydraulic oils.

• Journal of Animal Science and Technology
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• 제47권3호
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• pp.481-490
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• 2005

Nitrate contamination in water system is a critical environmental problem caused by excessive application of chemical fertilizer and concentration of livestock. In order to prevent further contamination, therefore, it is necessary to understand the origin of nitrate in nitrogen loading sources and manage the very source of contamination. The objective of this study was to examine the nitrate contamination sources in different agricultural system by using nitrogen isotope ratios. Groundwater and runoff water samples were collected on a monthly basis from February 2003 to November 2003 and analyzed for nitrogen isotopes. The nitrate concentrations of groundwater in livestock fanning area were higher than those in conventional and organic fanning area and exceeded the national drinking water standard of 10mg N/ l. The ${\delta}^{15}N$ranges of chemical fertilizer and animal manure were - 3.7${\sim}$+2.3$\textperthousand$ and +12.5${\sim}$26.7$\textperthousand$, respectively. The higher ${\delta}^{15}N$ of animal manure than those of chemical fertilizer reflected isotope fractionation and volatilization of '''N. The different agricultural systems and corresponding average nitrate concentrations and ${\delta}^{15}N$ values were: conventional farming, 5.47mg/e, 8.3$\textperthousand$; organic fanning, 5.88mg/e, 10.1$\textperthousand$; crop-livestock farming, 12.5mg/e, 17.7%0. These data indicated that whether conventional or organic agriculture effected groundwater and runoff water quality. In conclusions, relationship between nitrate concentrations and ${\delta}^{15}N$ value could be used to make a distinction between nitrate derived from chemical fertilizer and from animal manure. Additional investigation is required to monitor long-term impact on water quality in accordance with agricultural systems.

• Environmental Analysis Health and Toxicology
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• 제14권4호
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• pp.165-174
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• 1999

This study was conducted to analyze the priority of environmental problems in Korea by investigating the environmental professionals' perception. The delphi technique was applied to identify their risk perception towards some specific items related with pollution. A standardized questionnaire on environmental problems and their priorities was used to 74 subjects. In the questionnaire, the environmental problems were divided into the general ones,9 items, and the specific ones,30 items. Also, the perception was associated with two points of view which were the risk on general human health or ecosystem, and on the present situation in Korea. The priority of risk from general environmental problems on human health or ecosystem was analyzed in the order of 'water pollution', 'air pollution', 'soil contamination', 'waste', 'toxic chemical pollutants', 'food contamination', 'ocean contamination', 'odor pollution', and 'noise pollution'. The priority of risk on the present situation in Korea was analyzed in the order of 'water pollution','air pollution','waste','toxic chemical pollutants','food contamination','soil contamination','ocean contamination','odor pollution', and 'noise pollution'. And these priorities were significantly related with the characteristics of respondents such as sex, age, and major concerned area. However, for the first five priorities of risk from the specific environmental problems on human health or ecosystem, the environmental professionals agreed with 'automotive vehicle exhaust', 'domestic and industrial source pollutants to surface water', '$CO_2$nd g1oba1 warming effect','toxic air pollutant' and 'industrial source air pollution'. The priorities of risk on the present situation in Korea were similar to these results.

• 대한자원환경지질학회:학술대회논문집
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• 대한자원환경지질학회 2005년도 춘계 학술발표회 논문집
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• pp.7-10
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• 2005

• 한국지하수토양환경학회지:지하수토양환경
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• 제15권6호
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• pp.122-127
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• 2010

Constructing the national inventory that can be used as a tool to identify and assess existing or potential contamination is necessary for efficiently managing the soil and groundwater contamination. In order to start this construction, the first step is how we define and classify potential contamination sources of soil and groundwater. After selecting the basic classification model of contamination sources from developed countries, we suggested the classification and list of the potential contamination sources of soil and groundwater which are appropriate for specific conditions of South Korea. In addition, we investigated several databases to confirm the existence of available data sources and then examined established attribute data through chemical accident response information system (CARIS) and water information system (WIS) in National Institute of Environmental Research and mine geographic information system (MGIS) in Mine Reclamation Corporation. All sorts of attribute data in the existing databases can be utilized as significant assessment factors for determining the management priority of potential contamination sources in the future. Therefore, it is required the expanded investigation of additional database sources and the continual modification so that the classification system of potential contamination sources can be improved.

• Korean Chemical Engineering Research
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• 제50권2호
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• pp.187-190
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• 2012

고분자전해질연료전지(PEMFC)에서 음극 공기에 의한 이온오염은 막전극 합체(MEA)의 성능을 심각하게 열화시킨다. 본 연구에서는 산업단지, 길가, 해변의 공기 중 이온 농도를 측정하였다. 이들 지역에서 $Na^+$, $K^+$, $Ca^{2+}$와 $Fe^{3+}$ 이온 농도가 비교적 높았다. 가습수로부터 이들 이온이 cathode에 유입되어 MEA 성능에 미치는 영향에 대해 연구하였다. 수돗물을 가습수로 사용해 170시간 운전한 후 MEA 성능이 초기의 11%로 감소하였다. 이들 오염 이온들이 수소이온보다 전해질 막의 슬폰산기와 친화력이 더 강해 전해질 막에 쉽게 이온 교환된 결과다. MEA 중에서 전극/막 계면에서 이온 오염이 MEA 성능저하에 미치는 영향이 제일 컸다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1999년도 추계학술발표회
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• pp.57-60
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• 1999

Geochemical study was carried out to find out soil contamination at the heaped soil, moved from bottom of the storage pond in Pohang industrial complex, in Moondug, Chemical analysis showed that contents of heavy metals in the soil were higher than those of the ordinary soil. Contents of Cu and Cd in the soil exceeded Korean standard of soil contamination. Especially content of Cu exceeded Korean standard of soil contamination(50ppm) at the six points and at one point content of Cu was 113.3ppm. Contents of Be were so higher than U.S RCRA standard(0.2ppm) that they can affect soil environment. The followed research about relation between pollutant and soil and proper measures are required to prevent soil contamination from affecting environment of Moondug.

• 한국환경과학회지
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• 제7권4호
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• pp.565-572
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• 1998

This study estimate the degree of contamination in the streamwater around the Sudokwon landfill site. It was sampled at 10 sites in Jan., Apr., Jul. and Oct., 1996. There were analyzed five kinds of toxic chemical material-CN, AES, PCB, As, Org-p, and four kinds of heavy metal-Pb, Hg, Cd, $C^{+6}$ The result are 1)The COD was generally increased to compare before landfall, 2) The Org-P and PCB were not detected at all points, 3) The concentrations of Pb, $C^{+6}$ and As were lower than the environmental criteria values, 4) The CN, Hg and Cd were over envirommental criteria values. and so emergent regulation is needed, 5) The effects of the streamwater contamination were not only the leachate of the landfall, but also the small factories and agricultural land around the landfill.