• Title/Summary/Keyword: Chemical additives

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MODELLING STUDY OF THE EFFECT OF CHEMICAL ADDITIVES ON SOOT PRECURSORS REDUCTION

  • Park, J.K.
    • International Journal of Automotive Technology
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    • v.7 no.4
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    • pp.501-508
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    • 2006
  • The effect of chemical additives, such as dimethyl ether(DME), ethanol, carbon disulfide on the soot formation were examined numerically. ill this study, the Frenklach soot mechanism was used as a base mechanism to predict the soot formation in the ethane flame. The combination of Westbrook's DME mechanism, Marinov's ethanol mechanism, and chemical kinetic mechanism for hydrogen sulfide and carbon disulfide flames was made with the base mechanism because the DME, ethanol, $CS_2$ additives are added into the ethane fuel. CHEMKIN code was used as a numerical analysis software to simulate the effect of chemical additives on reduction of the polycyclic aromatic hydrocarbons(PAH's) which are soot precursors. From the numerical results it is observed that addition of DME, ethanol and $CS_2$ into ethane fuel can reduce PAH species significantly. That means theses additives can reduce soot formation significantly. Results also strongly suggest suppression of soot formation by these additives to be mainly a chemical effect. Hand OH radicals may be the key species to the reduction of PAH species for additives.

Use of Chemical Blend Additives for Decreasing Pathogens in Poultry Litter (육계 깔짚내 유해성 병원균 감소를 위한 화학제재의 이용)

  • Chung, Tae-Ho
    • Journal of Environmental Science International
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    • v.27 no.2
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    • pp.143-146
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    • 2018
  • This study was conducted to evaluate the effect of chemical blend additives (a combination of ferrous sulfate and aluminum chloride) on decreasing pathogens in poultry litter. A total of 240 broiler chickens were assigned to 4 chemical treatments with 4 replicates of 15 chickens per pen. The four chemical blend additives were a control (no treatment), 25 g ferrous sulfate + 75 g aluminum chloride/kg poultry litter, 50 g ferrous sulfate + 100 g aluminum chloride/kg poultry litter and 100 g ferrous sulfate + 150 aluminum chloride/kg poultry litter. During the 6-wk experimental period, there were significant differences in both E.coli and Salmonella enterica for weeks 4 through 6, but not at weeks 1 and 3, respectively. Consequently, using chemical blend additives that serve as methods to control strict environmental regulations reduced pathogens in poultry litter.

Experimental Study on Flexural Behavior of RC Slabs with Expansive Additives (팽창재를 혼입한 철근콘크리트 슬래브의 휨 거동에 관한 실험적 연구)

  • 박홍용;김철영;최익창;배상욱;이호석
    • Journal of the Korea Concrete Institute
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    • v.12 no.4
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    • pp.31-40
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    • 2000
  • This study aims to improve serviceability of concrete by inducing chemical prestress with the application of expansive additives for concrete. For this purpose, material tests and 4 point-bending tests of RC slabs were performed to verify the effect of expansive additives on the concrete. and the critical aspects of the structural behavior were investigated. The results of the material tests show that the optimal proportion of expansive additives is 13% of total cement weigth and the properties of expansive concrete in that proportion are the same as those of plain concrete. Both the experimental cracking load and service load of the expansive concrete slabs are increased in comparison with those of the plain concrete. In addition to the above results, the deflection of expansive concrete is smaller than that of plain concrete, and permanent strains resulting from cyclic load are decreased. It can be concluded that the use of expansive additives to induce chemical prestress in RC slabs greatly improves the serviceability.

Comparative Studies on Microbioassay and Chemical Procedure for Quantitative Determination of Niacin in Feed Additives (사료첨가제중(飼料添加劑中) Niacin의 미생물학적정량법(微生物學的定量法)과 화학적정량법(化學的定量法)의 비교시험(比較試驗))

  • Cho, Jong-Hoo;Hwang, Dae-Woo;Han, Suu-Nam
    • Applied Biological Chemistry
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    • v.17 no.1
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    • pp.49-53
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    • 1974
  • Mohan's aniline procedure for the quantitative determination of niacin in feed additives containing various vitamines and minerals was compared with microbiological procedure utilizing growth rate of Lactobacillus arabinosus 17-5. Microbioassay was more sensitive than chemical procedure to the detection of standard niacin and was applicable to the determination of minute amounts of niacin. while both microbioassay and chemical proce dure were discovered to be unsatisfactory by the recovery test for the determination of niacin in feed additives containing much interfering substances. But the possibility of the determination of niacin in feed additives on chemical prccedure together with microbioassay was proved.

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A Study on Rheological Properties of Cement Paste using Expansive Additives by Kind & Replacement Ratio (팽창재 종류 및 치환율에 따른 시멘트 페이스트의 레올로지 특성)

  • Park, Chun-Young;Kang, Byeung-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.2
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    • pp.99-106
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    • 2008
  • To improve concrete tensile strength and bending strength, New plan that have more economical and simple manufacture process is groped. By an alternative plan, chemical pre-stressed concrete is presented. In this study, we analyzed the rheological properties of cement paste with the kind and replacement ratio of k-type CSA type expansive additives that is used mainly in domestic. and we suggested that the algorithm of a mixing plan in the chemical pre-stressed concrete and from this, we presented the basic report for the right mixing plan. From the results, Flow increased more or less according to use of expansive additives. This phenomenon was observed by increasing paste amount that shows as substitution for expansive additives that specific gravity is smaller than that of cement. As linear regression a result supposing paste that mix expansive additives by Bingham plastic fluid. The shear rate and shear stress expressed high interrelationship. therefore, flow analysis of quantitative was available. The plastic viscosity following to replacement ratio of expansive additives is no change almost, the yield value is decreased in proportion to the added amount of expansive additives. Through this experiment, we could evaluate rheological properties of cement paste using the expansive additives. Hereafter by an additional experiment, we must confirm stability assessment of material separation by using the aggregate with the kind and replacement ratio of expansive additives.

Adsorption Kinetics for Polymeric Additives in Papermaking Aqueous Fibrous Media by UV Spectroscopic Analysis

  • Yoon, Sung-Hoon;Chai, Xin-Sheng
    • Bulletin of the Korean Chemical Society
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    • v.27 no.11
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    • pp.1819-1824
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    • 2006
  • The general objective of the present study was to investigate the potential application of the UV spectroscopic method for determination of the polymeric additives present in papermaking fibrous stock solutions. The study also intended to establish the surface-chemical retention model associated with the adsorption kinetics of additives on fiber surfaces. Polyamide epichlorohydrin (PAE) wet strength resin and imidazolinium quaternary (IZQ) softening agents were selected to evaluate the analytical method. Concentrations of PAE and IZQ in solution were proportional to the UV absorption at 314 and 400 nm, respectively. The time-dependent behavior of polymeric additives obeyed a mono-molecular layer adsorption as characterized in Langmuir-type expression. The kinetic modeling for polymeric adsorption on fiber surfaces was based on a concept that polymeric adsorption on fiber surfaces has two distinguishable stages including initial dynamic adsorption phase and the final near-equilibrium state. The simulation model predicted not only the real-time additive adsorption behavior for polymeric additives at high accuracy once the kinetic parameters were determined, but showed a good agreement with the experimental data. The spectroscopic method examined on the PAE and IZQ adsorption study could potentially be considered as an effective tool for the wet-end retention control as applied to the paper industry.

The Effect of Some Additives on the Components of Cigarette Smoke (첨가제가 담배 연기성분에 미치는 영향)

  • Ra Do-Young;J도 Byong-Kwon;Lee Chang-Kook;Cho Si-Hyung;Lee Dong-Wook
    • Journal of the Korean Society of Tobacco Science
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    • v.27 no.1 s.53
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    • pp.40-50
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    • 2005
  • The influence of tobacco additives on the composition of the combustion products in mainstream smoke is discussed. The effect of additives on the chemical composition of smoke have been further evaluated in order to discover additives that would alter the chemical composition of smoke. Tobacco was uniformly treated at a 1-5$\%$ level with 8 classes of additives. Group M treated with alkali metal salt and group S, F, O give lower tar, nicotine and CO values than the control. Group AN treated with natural antioxidant gives higher tar and CO values than the control. The increases are most probably due to the high transfer rate of the ingredients to smoke. M3 and P1 reduced above the $50\%$ of TSNA from the smoke. M4 and P1 reduced above the $50\%$ of HCN from the smoke. These results suggest that tobacco additives alter pyrolysis or combustion product distribution and provide fundamental data to lead the development of a RRP(reduced risk product).

Modification of polyethersulfone hollow fiber membrane with different polymeric additives

  • Arahman, Nasrul;Mulyati, Sri;Lubis, Mirna Rahmah;Razi, Fachrul;Takagi, Ryosuke;Matsuyama, Hideto
    • Membrane and Water Treatment
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    • v.7 no.4
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    • pp.355-365
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    • 2016
  • The improvement of fouling resistance of porous polymeric membrane is one of the most important targets in membrane preparation for water purification in many process like wastewater treatment. Membranes can be modified by various techniques, including the treatment of polymer material, blending of hydrophilic polymer into polymer solution, and post treatment of fabricated membrane. This research proposed the modifications of morphology and surface property of hydrophobic membrane by blending polyethersulfone (PES) with three polymeric additives, polyvinylpyrrolidone (PVP), Pluronic F127 (Plu), and Tetronic 1307 (Tet). PES hollow fiber membranes were fabricated via dry-wet spinning process by using a spinneret with inner and outer diameter of 0.7 and 1.0 mm, respectively. The morphology changes of PES blend membrane by those additives, as well as the change of performance in ultrafiltration module were comparatively observed. The surface structure of membranes was characterized by atomic force microscopy and Fourier transform infra red spectroscopy. The cross section morphology of PES blend hollow fiber membranes was investigated by scanning electron microscopy. The results showed that all polymeric additives blended in this system affected to improve the performances of PES membrane. The ultra-filtration experiment confirmed that PES-PVP membrane showed the best performance among the three membranes on the basis of filtration stability.

The Selective Visualization of Lignin Peroxidase, Manganese Peroxidase and Laccase, Produced by White Rot Fungi on Solid Media

  • Ryu, Won-Youl;Jang, Moon-Yup;Cho, Moo-Hwan
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.2
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    • pp.130-134
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    • 2003
  • A visual method for the selective screen Eng of lignin degrading enzymes, produced by white rot fungi (WRF), was investigated by the addition of coloring additives to solid media. Of the additives used in the enzyme production media, guaiacol and RBBR could be used for the detection of lignin peroxidase (LiP), manganese peroxidase (MnP) and lactase. Syringaldazine and Acid Red 264 were able for the detection of both the MnP and lactase, and the LiP and laccase, respectively, and a combination of these two additives was able to detect each of the ligninases produced by the WRF on solid media.

Investigation of Inhibition Effect on Hydrate Formation by Chemical Additives (화학첨가제를 이용한 하이드레이트 형성 억제 효과 분석)

  • Lee, Jeong-Hwan;Baek, Young-Soon
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.618-621
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    • 2005
  • In this study, the phenomena of hydrate formation and inhibition were investigated according to varying the concentrations using methanol and ethylene glycol as chemical additives. The results reveal that the used additives display better inhibition effects compared to pure water by decreasing the formation temperature and the inhibition performance of methanol is superior to that of ethylene glycol. As a conclusion, the plugging phenomena of flowline in natural gas product ion. subsea and frozen field pipelines can be predicted by examining the hydrate formation and inhibition conditions. Specifically, the results of this study can be applied to the selection of the prevention criteria and method of hydrate formation.

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