• 한국위성정보통신학회논문지
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• 제8권3호
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• pp.15-19
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• 2013

리튬이온 배터리는 낮은 자체 방전율 특성과 고밀도 에너지 저장장치로 다양하게 응용되고 있으며, 단위 셀 배터리의 전압은 4V 보다 낮아, 직렬로 연결하여 사용해야 하는 것이 일반적이다. 배터리 셀전압의 직렬 연결 동작시, 각각의 단위 셀 배터리는 내부저항이 균일하지 않아, 충전 시, 특정 단위 셀 배터리는 4V 이상이 걸려, 폭발이 발생할 수도 있으며, 또한, 방전 시 배터리의 특성을 떨어뜨릴 수 있는 한계 전압 이하가 되는 심각한 문제가 존재한다. 따라서, 단위 셀 배터리의 충전 및 방전 동작에서는 과충전과 과방전을 사전에 감지하기 위한 전압 센싱 동작이 필요하며, 이에, 본 논문에서는 고속 배터리 전압 센싱 모듈 개발을 소개한다. 제작된 CVM(Cell Voltage Monitoring)은 단위 배터리 셀을 통하여, 전압 및 온도 채널 포함하여, 12채널을 모니터링할 수 있으며, 채널당 12-bits 분해능과 192 kbps 전송 속도를 가진다.

• 대한화학회지
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• 제50권3호
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• pp.243-246
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• 2006

박막은 Pt/Ti/SiO2/Si 기판 위에 구연산 졸을 이용하여 spin coating에 의해 제작하였다. 기판위에 코팅된 구연산 졸을 380oC에서 15분간 건조시킨 후 750oC에서 10분간 열처리하여 박막을 얻었다. 얻어진 박막은 X-선 회절분석 결과 R3m의 결정구조를 가짐을 알수 있었고, 전기화학적 특성의 측정결과 1차 방전용량은 0.35Ah/cm2-m로 측정되었다.

• 공업화학
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• 제5권1호
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• pp.44-53
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• 1994

고성능 니켈-철 축전지를 개발하기 위하여 알칼리 축전지로 이론적 용량밀도가 높고 저공해성, 저렴한 가격, 자원의 풍부성 등의 우수한 장점을 가지고 있는 철전극에 대한 연구를 수행하였다. 충방전반응의 특성을 전위주사법, SEM, XRD 분석으로 조사하였으며, 또한 전극용량을 정전류 충방전시험법으로 조사하였다. 철의 순도와 입자크기가 전극용량에 크게 영향을 미쳤으며, 첨가제 $Na_2S$는 전극의 부동태화를 방지하고 수소과전압을 높여 전극용량을 20% 정도 증대시켰다. 전극의 안정성과 용량은 Ni-fibrex와 foamed Ni집전체를 사용하여 증대시켰으며, 또한 소결온도에 영향을 받았다. 전극용량은 350 mAh/g(0.2 C)으로 나타났는데, 이는 이용률 36%에 해당한다.

• 한국물환경학회지
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• 제28권6호
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• pp.917-922
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• 2012

In order to improve applicability of a microbial fuel cell the laboratory-scaled study has been performed by adopting an air-cathode MFC system with high concentrated anaerobic slugies in this study. The concentrations of microbes are grouped into three types, Type A (TS 1.7%), Type B (TS 1.1%) and Type C (TS 0.51%). The open circuit voltage $(V_{oc})$ characteristics showed that the medium microbes concentration of 1.10% (Type B) kept a constant voltage of 1.0 V for 150 hours, which showed the longest time among three types (Type A and Type C). The discharge charge curves for a closed circuit with $500 \Omega$ also showed that Type B generated a stable discharge voltage of 0.8 V for a longer time as in the open circuit voltage case. This could be explained by the relatively large amount of the attached microbes. Under the $V_{oc}$condition the COD removal efficiency of Type B was found to be low for a long time, but those of Type A and C were found to be high for a short period of time. Therefore, the suspended microbes could decrease the coulombic efficiency. It was concluded that the high $V_{oc}$ was caused by low COD and the $V_{oc}$ became low after the COD removal. The COD reduction resulted in an unstable and low working voltage. From the polarization characteristics Type A was found to show the highest power density of $193\;mW/m^2$ with a fill factor of 0.127 due to the relatively high remaining COD even after the MFC reaction.

• 한국결정학회:학술대회논문집
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• 한국결정학회 2002년도 정기총회 및 추계학술연구발표회
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• pp.16-16
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• 2002

The presently commercialized lithium-ion batteries use layer structured LiCoO₂ cathodes. Because of the high cost and toxicity of cobalt, an intensive search for new cathode materials has been underway in recent years. Recently, a concept of a one-to-one solid state mixture of LiNO₂ and LiMnO₂, i.e., Li[Ni/sub 0.5/Mn/sub 0.5/]O₂, was adopted by Ohzuku and Makimura to overcome the disadvantage of LiNiO₂ and LiMnO₂. Li[Ni/sub 0.5/Mn/sub 0.5/]O₂ has the -NaFeO₂ structure, which is characteristic of the layered LiCoO₂ and LiNiO₂ structures and shows excellent cycleability with no indication of spinel formation during electrochemical cycling. Layered Li[Ni/sub x/Co/sub 1-2x/Mn/sub x/]O₂ (x = 0.5 and 0.475) materials with high homogeneity and crystallinity were synthesized using a mechanical alloying method. The Li[Ni/sub 0.475/Co/sub 0.05/Mn/sub 0.475/]O₂ electrode delivers a high discharge capacity of 187 mAh/g between 2.8 and 4.6 V at a high current density of 0.3 mA/㎠(30 mA/g) with excellent cycleability. The charge/discharge and differential capacity vs. voltage studies of the Li[Ni/sub x/Co/sub 1-2x/Mn/sub x/]O₂ (x = 0.5 and 0.475) materials showed only one redox peak up to 50 cycles, which indicates that structural phase transitions are not occurred during electrochemical cycling. The magnitude of the diffusion coefficients of lithium ions for Li[Ni/sub x/Co/sub 1-2x/Mn/sub x/]O₂(x = 0.5 and 0.475) are around 10/sup -9/ ㎠/s measured by the galvanostatic intermittent titration technique (GITT).

• 전기전자학회논문지
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• 제15권4호
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• pp.324-329
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• 2011

휴대 기기가 고기능화, 다기능화 됨에 따라 다양한 멀티미디어 기능이 요구되면서 배터리를 보다 장시간 이용하면서 더 높은 전력과 에너지가 요구되고 있다. 이에 따라 여러 개의 리튬이온 cell을 연결한 배터리팩이 많이 사용되고 있다. 2개 이상의 cell로 구성된 리튬이온 배터리를 안전하게 사용하기 위해서는 과전압 및 과전류, 고온으로 부터 보호해야 됨은 물론, 수명을 연장하기 위해서 각 cell의 전압을 같게 유지시켜주는 balancing 기능이 반드시 요구된다. 본 논문에서 제안한 IC는 모바일 기기뿐만 아니라 E-bike, 하이브리드 자동차, 전기 자동차 분야에도 적용 가능할 것으로 예상되며, 국내 PMIC 발전에 기여할 것으로 기대된다.

• 한국전기전자재료학회논문지
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• 제32권1호
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• pp.70-77
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• 2019

$SiO_x$ nanoparticles were granulated, and their microstructures and effects on electrochemical behaviors were investigated. In spite of the promising electrochemical performance of $SiO_x$, nanoparticles have limitations such as high surface area, low density, and difficulty in handling during slurry processing. Granulation can be one solution. In this study, pelletizing and annealing were conducted to create particles with sizes of several decades of micron. Decrease in surface area directly influences the initial charge and discharge process when granules are applied as anode materials for Li-ion batteries. Lower surface area is key to decreasing the amount of irreversible phase-formation, such as $Li_2Si_2O_5$, $Li_2SiO_3$ and $Li_4SiO_4$, as well as forming the solid electrolyte interface. Additionally, aggregation of nanoparticles is required to obtain further enhancement of the electrochemical behavior due to restrictions that there be no $Li_4SiO_4$-related reaction during the first discharge process.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 추계학술대회 논문집
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• pp.132-132
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• 2009

Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. In this study, Multi-walled carbon nanotube (MWCNT) and Carbon black was added to enhance the electrical conductivity of $LiFePO_4$. $LiFePO_4$, $LiFePO_4$-MWCNT and $LiFePO_4$-C particles were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM) transmission electron microscope (TEM). $LiFePO_4/SPE/Li$, $LiFePO_4$-MWCMT/SPE/Li and $LiFePO_4$-C/SPE/Li cells were characterized electrochemically by charge/discharge experiments at a constant current density of $0.1mA\;cm^{-2}$ in a range between 2.5 and 4.3 V vs. $Li/Li^+$ and cyclic voltammetry (CV).

• 한국수소및신에너지학회논문집
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• 제28권2호
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• pp.200-205
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• 2017

The three electrodes (carbon felt) were tested in all-vanadium redox flow battery (VRFB) to confirm the its usefulness. The electrode property was measured by the CV (cyclic voltammetry) method. The current ratio of maximum peak(IPA/IPC) in GF040BH5 and GF051BH3 had almost the same value compared to that in XF30A. The performances of VRFB using the each electrode were measured during 5 cycles of charge-discharge at the current density of $60mA/cm^2$. An average energy efficiency of the VRFB was 77.8%, 77.3%, and 79.2% for XF30A, GF040BH5 and GF051BH3, respectively. It was confirmed from the data that GF040BH5 and GF051BH3 is well suited for use in a VRFB as a electrode, like XF30A.

• 펄프종이기술
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• 제30권4호
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• pp.11-17
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• 1998

Reducing the effluent discharge from a paper mill is urgently needed due to tightening environmental regulations and economic reasons. For a paper mill to respond to system closure it is required to adopt the best practical retention system that enables the mill to improve fines retention and drainage. In this study, effects of various retention agents on fines retention, drainage and formation were examined using linerboard stock in the laboratory. Among the retention aids tested, high molecular weight cationic polyacrylamides showed good efficiency both in retention and drainage. On the other hand, high charge density, low molecular weight polymeric retention aids showed little improvement both in retention and drainage. The best retention system selected from the laboratory experiment was applied on a paper machine producing linerboard to evaluate its effect on papermaking system closure.