• Title/Summary/Keyword: Charge-discharge density

Search Result 188, Processing Time 0.026 seconds

Electrochamical Properties of $LiFePO_4$ Electrodes for Lithium Polymer Battery (리튬 폴리머 전지 $LiFePO_4$의 전기화학적 특성)

  • Kong, Ming-Zhe;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.05b
    • /
    • pp.5-9
    • /
    • 2005
  • $LiFePO_4$ is a potential candidate for the cathode material of the lithium polymer batteries. $LiFePO_4$ cathode active materials were synthesized by coating on the $LiFePO_4$ was tried using $TiO_2$ and corbon in oreder to increase cyclic performance and electronic conductivity. Highly dispersed on the particles enhances the electronic conductivity and increases the capacity. For lithium polymer battery applications, $LiFePO_4$/SPE/Li and $LiFePO_4$-$TiO_2$/SPE/Li 'cells were characterized electrochemically by cyclic volatammetry and charge/discharge cycling. The $LiFePO_4$-carbon-$TiO_2$ cathode in PVDF-PC-EC-$LiCIO_4$ electrolyte showed high capacity at high current density.

  • PDF

Analysis of luminous efficacy of a PDP cell using a hybrid simulation with an electron-fluid and ion-particle model

  • Lee, Hae-June;Shim, Seung-Bo;Song, In-Cheol;Lee, Ho-Jun;Park, Chung-Hoo
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2009.10a
    • /
    • pp.24-27
    • /
    • 2009
  • A hybrid model has been developed which adopts a fluid model for electrons and a particle-in-cell (PIC) model for ions. Using the hybrid simulation, the discharge characteristics are investigated with the diagnostics for the electric field and the wall charge profile, density distributions of charged and excited particles, distributions of ultraviolet lights on phosphor, and the visible lights emitted from the PDP cell. Also, energy and angle distributions of the ions at the MgO protective layer are obtained for the analysis of material effect. The comparison of hybrid simulation results with experimental results as well as that with the conventional fluid simulation shows that the new model is more adequate for the simulation of PDP cells.

  • PDF

DISCHARGE CHARACTERISTICS OF NICKELOXIDE ELECTRODE PREPARED FROM ELECTROCHEMICAL IMPREGNATION

  • Takenoya, K.;Sasaki, Y.;Yamashita, T.
    • Journal of the Korean institute of surface engineering
    • /
    • v.32 no.3
    • /
    • pp.363-365
    • /
    • 1999
  • The improved method comprises electrochemically deposition of nickel hydroxide into the sintered nickel plaque cathode from nickel aqueous electrolyte at acid pH in a treating zone containing an anode. The electrochemical impregnation was examined under various conditions. Deposition condition of fine active material was obtained from the impregnation of a high temperature and also high current density. This method also could be decreased swelling and buckling of the plaque. A nickel electrode prepared by electrochemical impregnation is useful as the positive in nickel-cadmium cells. The utilization of the active material indicated almost 100% based on a one electron charge.

  • PDF

Development of Advanced Polymeric Binders for High Voltage LiNi0.5Mn1.5O4 cathodes in Lithium-ion batteries (고전압 LiNi0.5Mn1.5O4 양극 고성능 바인더 개발 연구)

  • Dae Hui Yun;Sunghun Choi
    • Journal of Industrial Technology
    • /
    • v.43 no.1
    • /
    • pp.43-48
    • /
    • 2023
  • Spinel LiNi0.5Mn1.5O4 (LNMO) has been considered as one of most promising cathode material, because of its low-cost and competitive energy density. However, 4.7V vs. Li/Li+ of high operating potential facilitates electrolyte degradation on cathode-electrolyte interface during charge-discharge process. In particular, commercial polyvinylidene fluoride (PVDF) is not sutaible for LNMO cathode binder because its weak van der waals force induces thick and non-uniform coverage on the cathode surface. In this review, we study high performance binders for LNMO cathode, which forms uniform coating layer to prevent direct contact between electrolyte and LNMO particle as well as modifying high quality cathode electrolyte interphase, improved cell performace.

Modeling of the dynamic behavior of a 12-V automotive lead-acid battery (12V 차량용 납축전지의 동적 거동 모델링)

  • Kim, Sung Tae;Lee, Jeong Bin;Kim, Ui Seong;Shin, Chee Burm
    • Journal of Energy Engineering
    • /
    • v.22 no.2
    • /
    • pp.175-183
    • /
    • 2013
  • For the optimal design of the vehicle electric system, it is important to have a reliable modeling tool to predict the dynamic behavior of the automotive battery. In this work, a one-dimensional modeling was carried-out to predict the dynamic behaviors of a 12-V automotive lead-acid battery. The model accounted for electrochemical kinetics and ionic mass transfer in a battery cell. In order to validate the modeling, modeling results were compared with the experiment data of the dynamic behaviors of the lead-acid batteries of two different capacities that were mounted on the automobiles manufactured by Hyundai Motor Company. The discharge behaviors were measured with various discharge rates of C/3, C/5, C/10, C/20 and combination. And dynamic behaviors of charge and discharge were measured. The voltage curves from the experiment and simulation were in good agreement. Based on the modeling, the distributions of the electrical potentials of the solid and solution phases, and the current density within the electrodes could be predicted as a function of charge and discharge time.

A Study on the control of output power and pulse repetition rate in pulsed Nd:YAG laser (펄스형 Nd:YAG 레이저의 출력 에너지 및 펄스 반복률 제어에 관한 연구)

  • Park, K.R.;Kim, B.G.;Moon, D.S.;Hong, J.H.;Kim, W.Y.;Kang, U.;Kim, H.J.;Cho, J.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.05b
    • /
    • pp.74-77
    • /
    • 2000
  • A pulsed Nd:YAG laser has been used in a wide variety of fields : measuring, material processing and so on. In a material processing, it is very important to control the laser energy density. A pulse repetition rate and a pulse width are regarded as the most dominant factors to control the energy density of laser beam. In this study, pulsed Nd:YAG laser system was designed and manufactured to control the laser output usefully and easily. This system adopted the sequential charge and discharge circuit is controlled by 80196 micro- processor. As a result, it is found that laser output is controlled minutely by changing laser input and pulse repetition rate, and usefully by using 80196 microprocessor.

  • PDF

Anode Characteristics of Tin Oxide Thin Films According to Various Si Additions for Lithium Secondary Microbattery (Si 첨가에 따른 리튬 이차 박막 전지용 주석 산화물 박막의 음극 특성)

  • 박건태;박철호;손영국
    • Journal of the Korean Ceramic Society
    • /
    • v.40 no.1
    • /
    • pp.69-76
    • /
    • 2003
  • For lithium secondary microbattery anode, the tin oxide thin films with Si addition (0, 2, 6, 10, 20 ㏖%) were prepared with R.F. magnetron sputtering at substrate temperature of 30$0^{\circ}C$ and Ar:O$_2$=7:3 atmosphere. As Si addition amount increased, Si-O bonding density increased and Sn-O bonding density decreased. The addition of optimum Si amount led the decrease of Sn oxidation state so that the irreversible capacity reduced and cycle characteristic enhanced during charge-discharge test. SnO$_2$films with 6 ㏖% Si had the highest reversible capacity of 700 mAh/g after 100 cycles.

Optimization of Capacitance Balance for a Hybrid Supercapacitor Consisted of LiMn2O4/AC as a Positive and AC Negative Electrode

  • Cho, Min-Young;Park, Sun-Min;Lee, Jae-Won;Roh, Kwang-Chul
    • Journal of Electrochemical Science and Technology
    • /
    • v.2 no.3
    • /
    • pp.152-156
    • /
    • 2011
  • A hybrid supercapacitor is fabricated using a composite material from $LiMn_2O_4$ (LMO) and activated carbon (AC) as the positive electrode and AC as the negative electrode to form the (LMO + AC)/AC system. Volume ratio (positive : negative) of electrodes is controlled to investigate of the power and energy balance. The (LMO + AC)/AC system shows better performances than the LMO/AC system. Especially, electrochemical impedance spectra, rate charge.discharge and cycle performance testing show that the (LMO + AC)/AC system have an outstanding electrochemical performance at volume ratios of (LMO + AC)/AC = 1 : 1.7 and 1 : 2. Electric double layer capacitor (EDLC) capacitance between AC of the positive electrode and AC of the negative electrode improves power density without loss of capacitance. Stable capacitance is achieved by lowering the positive electrode resistance and balancing the energy and power densities between the positive and negative electrodes by the addition of AC to the positive electrode at high current density.

Nd:YAG laser firmware Design under RTOS operation (RTOS(Real Time Operation System) 환경하의 Nd:YAG 레이저 Firmware 설계)

  • Kim, B.G.;Kim, W.Y.;Park, G.R.;Moon, D.S.;Hong, J.H.;Kim, H.J.;Cho, J.S.
    • Proceedings of the KIEE Conference
    • /
    • 2000.07c
    • /
    • pp.2107-2109
    • /
    • 2000
  • A pulsed Nd:YAG laser is used widely for materials processing and medical instrument. It's very important to control the laser energy density in those fields using a pulsed Nd:YAG laser. A pulse repetition rate and a pulse width are regarded as the most dominant factors to control the energy density of laser beam. In this paper, the alternating charge and discharge system was designed to adjust a pulse repetition rate This system is controlled by microprocessor and allows to replace an expensive condenser for high frequency to cheap one for low frequency. In addition, The microcontroller monitors the flow of cooling water, short circuit. and miss firing and so on. We designed Nd:YAG laser firmware with smart microcontroller, and want to explain general matters about the firmware from now.

  • PDF

Interfacial Reaction between Li Metal and Solid Electrolyte in All-Solid-State Batteries (리튬금속과 고체전해질의 계면 반응)

  • Jae-Hun Kim
    • Corrosion Science and Technology
    • /
    • v.22 no.4
    • /
    • pp.287-296
    • /
    • 2023
  • Li-ion batteries have been gaining increasing importance, driven by the growing utilization of renewable energy and the expansion of electric vehicles. To meet market demands, it is essential to ensure high energy density and battery safety. All-solid-state batteries (ASSBs) have attracted significant attention as a potential solution. Among the advantages, they operate with an ion-conductive solid electrolyte instead of a liquid electrolyte therefore significantly reducing the risk of fire. In addition, by using high-capacity alternative electrode materials, ASSBs offer a promising opportunity to enhance energy density, making them highly desirable in the automotive and secondary battery industries. In ASSBs, Li metal can be used as the anode, providing a high theoretical capacity (3860 mAh/g). However, challenges related to the high interfacial resistance between Li metal and solid electrolytes and those concerning material degradation during charge-discharge cycles need to be addressed for the successful commercialization of ASSBs. This review introduces and discusses the interfacial reactions between Li metal and solid electrolytes, along with research cases aiming to improve these interactions. Additionally, future development directions in this field are explored.