• Title/Summary/Keyword: Charge-discharge density

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The Surface Modification of Electrode with Solid Electrolyte Interphase for Hybrid Supercapacitor

  • Choi, Min-Geun;Kang, Soo-Bin;Yoon, Jung Rag;Lee, Byung Gwan;Jeong, Dae-Yong
    • Journal of Electrical Engineering and Technology
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    • v.10 no.3
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    • pp.1102-1106
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    • 2015
  • A hybrid supercapacitor (HS) is an energy storage device used to enhance the low weight energy density (Wh/kg) of a supercapacitor. On the other hand, a sudden decrease in capacity has been pointed out as a reliability problem after many charge/discharge cycles. The reliability problem of a HS affects the early aging process. In this study, the capacity performance of a HS was observed after charge/discharge. For detailed analysis of the initial charge/discharge cycles, the charge and discharge curve was measured at a low current density. In addition, a solid electrolyte interphase (SEI) layer was confirmed after the charge/discharge. A HC composed of a lithium titanate (LTO) anode and active carbon cathode was used. The charge/discharge efficiency of the first cycle was lower than the late cycles and the charge/discharge rate was also lower. This behavior was induced by SEI layer formation, which consumed Li ions in the LTO lattice. The formation of a SEI layer after the charge/discharge cycles was confirmed using a range of analysis techniques.

Quantitative estimation of reversibility of the discharge process undergone by nickel hydroxide film cathodically deposited on pure nickel as a positive supercapacitor electrode using cyclic voltammetry and potential drop method

  • Pyun Su-Il;Moon Sung-Mo
    • Journal of the Korean Electrochemical Society
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    • v.1 no.1
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    • pp.8-13
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    • 1998
  • This work presents the way how to evaluate the degree of reversibility of the discharging process undergone by the nickel hydroxide film cathodically deposited on pure nickel as a positive electrode for electrochemical capacitor using the combined cyclic voltammetry and potential drop method, supplemented by galvanostatic discharge and open-circuit potential transient methods. The time interval necessary just to establish the current reversal of anodic to cathodic direction from the moment just after applying the potential inversion of anodic to cathodic direction, was obtained on cyclic voltammogram. The cathodic charge density passed upon dropping the applied potential, was calculated on potentiostatic current density-time curve. Both the time interval and the cathodic charge density in magnitude can be regarded as being measures of the degree of reversibility of the discharging process undergone by the positive active material for supercapacitor, i.e. , the longer the time interval is, the lower is the degree of reversibility and the greater the cathodic charge density is, the higher is the degree of reversibility. From the applied potential dependences of the time interval and cathodic charge density, discharge at $0.42 V_{SCE}$ was determined to be the most reversible.

The Discharge Characteristic Analysis of a Ramp Reset Waveform Using a 2-Dimensional Numerical Simulation in AC PDP (AC PDP에서 2차원 수치해석을 이용한 Ramp Reset 구동파형에 따른 방전 특성 분석)

  • Park Suk-Jae;Choi Hoon-Young;Seo Jeong-Hyun;Lee Seok-Hyun
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.12
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    • pp.606-615
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    • 2004
  • The discharge characteristics of a ramp reset waveform in the alternating current plasma display panel(ac PDP) were studied using a 2-dimensional numerical simulation. We analyzed the wall charge variation during the reset discharge, address discharge and sustain discharge adopting a ramp reset waveform. Then we investigated the principal parameters for a successful discharge. In this paper, we suggest a new parameter, printing particles' density and its effects on the stability of the ramp discharge. The maximum current flows of the three electrodes during the ramp reset period were decreased with the increase in the priming particles's density which was explained with the wall charge characteristics and the current flow characteristics obtained by a 2-D simulation.

Electrostatic Discharge Energy Estimation of the Charged Human Body by the Rompe-Weisel Model (Rompe-Weisel Model에 의한 대전 인체의 정전기 방전 에너지 평가)

  • 이종호;김두현;강동규
    • Journal of the Korean Society of Safety
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    • v.18 no.3
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    • pp.54-59
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    • 2003
  • The discharge energy by electrostatic discharge of the charged human body is calculated under the assumption that the stored charge is dissipated completely. However, it is well-known that the charge is slightly remained after electrostatic discharge. Therefore, The Rompe-Weisel model of the discharge analysis, which has somewhat more of a physical justification than the conventional energy equation, is proposed. It is proposed that the electrical conductivity of the arc should be proportional to the energy density transferred to it by Ohmic dissipation. For the electrostatic discharge energy analysis, the Rompe-Weisel model was compared by quasi static analysis. As a consequence, a study on a reliable energy evaluation based on simulation models during electrostatic discharge is carried out in this paper and is adopted to estimate the explosion hazards of flammable gases.

Electrohydrodynamic Analysis of Dielectric Guide Flow Due to Surface Charge Density Effects in Breakdown Region

  • Lee, Ho-Young;Kang, In Man;Lee, Se-Hee
    • Journal of Electrical Engineering and Technology
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    • v.10 no.2
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    • pp.647-652
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    • 2015
  • A fully coupled finite element analysis (FEA) technique was developed for analyzing the discharge phenomena and dielectric liquid flow while considering surface charge density effects in dielectric flow guidance. In addition, the simulated speed of surface charge propagation was compared and verified with the experimental results shown in the literature. Recently, electrohydrodynamics (EHD) techniques have been widely applied to enhance the cooling performance of electromagnetic systems by utilizing gaseous or liquid media. The main advantage of EHD techniques is the non-contact and low-noise nature of smart control using an electric field. In some cases, flow can be achieved using only a main electric field source. The driving sources in EHD flow are ionization in the breakdown region and ionic dissociation in the sub-breakdown region. Dielectric guidance can be used to enhance the speed of discharge propagation and fluidic flow along the direction of the electric field. To analyze this EHD phenomenon, in this study, the fully coupled FEA was composed of Poisson's equation for an electric field, charge continuity equations in the form of the Nernst-Planck equation for ions, and the Navier-Stokes equation for an incompressible fluidic flow. To develop a generalized numerical technique for various EHD phenomena that considers fluidic flow effects including dielectric flow guidance, we examined the surface charge accumulation on a dielectric surface and ionization, dissociation, and recombination effects.

Charge/discharge Properties of Flyash as a Anode for Lithium Polymer Battery (리튬 폴리머 전지용 Flyash 부극의 충방전 특성)

  • Song, Hee-Woong;Kim, Jong-Uk;Park, Gye-Choon;Gu, Hal-Bon
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.968-970
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    • 1999
  • The trend of increasing of portable electric devices and demand for global environmental conservation have demands the development of high energy density rechargeable batteries. Lithium polymer battery has excellent theoretical energy density and energy conversion efficiency. Lithium polymer battery, included solid polymer electrolyte(SPE), can be viewed as a system suitable for wide applications from thin film batteries for microelectronics to electric vehicle batteries. The purpose of this paper is to research and development of flyash anode for lithium polymer battery. We investigated AC impedance response and charge/discharge characteristics of flyash/SPE/Li cells. The radius of semicircle associated with the interfacial resistance of flyash/SPE/Li cell increased very slowly during discharge process from 3.11V to 0.478V. And then the cell resistance was decreased at discharge process from 10% SOC to 0% SOC. Also, The radius of semicircle associated with the interfacial resistance of flyash/SPE/Li cell decreasing very slowly during charge process. And then the cell resistance was increased after 20th discharge precess. The discharge capacity based on flyash of 1st and 20th cycles was 276mAh/g and 143mAh/g.

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A study of the Improvement for Jitter and Discharge Delay Time in AC-PDP (AC-PDP에서 지터와 방전 늦음 시간 개선을 위한 연구)

  • Kwon, Shi-Ok;Kim, Ji-Sun;Joung, Bong-Kyu;Hwang, Ho-Jung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.506-507
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    • 2005
  • The effects of addition of $D_2$ to conventional gases [Ne-Xe and He-Ne-Xe] on the discharge characteristics were investigated in this work with the aim of improving the voltage margin, the wall charge and the jitter. The addition of an extremely small gas-inlet amounts of $D_2$ increased the number of electrons which improves. the $Xe^*$ density and $Xe_2^*$ density. As a result, the voltage margin, the jitter and the wall charge increased.

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A CFD Modeling of Heat Generation and Charge-Discharge Behavior of a Li-ion Secondary Battery (Li-ion 이차전지의 충방전 시 발열 및 충방전 특성의 CFD 모델링)

  • Kang, Hyeji;Park, Hongbeom;Han, Kyoungho;Yoon, Do Young
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.114-121
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    • 2016
  • This study investigates a CFD modeling of the charge-discharge behavior due to heat generation during charge-discharge cycles of a Li-ion secondary battery(LIB). Present LIB system adopted a current-density equation, heat and mass transfer governing equations upon the 1-dimensional system to the thickness direction for the rectangular pouch configuration. According to the 3-kinds of the charge-discharge current densities of 1C($17.5A/m^2$), 3C($52.5A/m^2$) and 5C($87.5A/m^2$) subject to a 3 V of cut-off voltage, a constant-temperature system at 298 K and three different heat generating systems were analyzed with comparison. Battery capacity decreases with increment of charge-discharge densities not only at the constant-temperature system but also at the heat-generating system. The time for charge-discharge cycles increases at the heat-generating system compare to the constant-temperature system. These trends are considered that the increase of temperature due to heat generation causes the decrement of equilibrium potential of electrodes and the increment of diffusivity of Li ions. Furthermore, cooling effects were discussed in order to control the influence of heat generation due to charge-discharge behavior of a Li-ion secondary battery.

Discharge Characteristics of a KSTAR NBI Ion Source

  • Chang Doo-Hee;Oh Byung-Hoon
    • Nuclear Engineering and Technology
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    • v.35 no.3
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    • pp.226-233
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    • 2003
  • The discharge characteristics of a prototype ion source was investigated, which was developed and upgraded for the NBI (Neutral Beam Injection) heating system of KSTAR (Korea Superconducting Tokamak Advanced Research). The ion source was designed for the arc discharge of magnetic bucket chamber with multi-pole cusp fields. The ion source was discharged by the emission-limited mode with the control of filament heating voltage. The maximum ion density was 4 times larger than the previous discharge controlled by a space-charge-limited mode with fully heated filament. The plasma (ion) density and arc current were proportional to the filament voltage, but the discharge efficiency was inversely proportional to the operating pressure of hydrogen gas. The maximum ion density and arc current were obtained with constant arc voltage ($80{\sim}100V$), as $8{\times}10^{11}cm^{-3}$ and 1200 A, respectively. The estimated maximum beam current was about 35 A, extracted by the accelerating voltage of 80kV.

Charge/Discharge characteristics of Li ion battery according to weight ratio of cathode to anode (리튬이온전지의 정.부극 중량비에 따른 전지의 충방전특성)

  • Eom, S.W.;Doh, C.H.;Hyung, Y.U.;Moon, S.I.;Yeom, D.H.;Yun, S.K.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1412-1413
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    • 1996
  • Li ion battery have many advantages such as high energy density, high voltage and low self discharge, so it will replace conventional Ni/Cd battery. But, charge-discharge characterization of Li battery is controlled by weight ratio of electrodes (Cathode/Anode). So, we performed a study on relation between charge/discharge characterization and weight ratio (cathode/anode).

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