• Title/Summary/Keyword: Ceramic recycling

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A Study on the Preparation of SiC Nano powder from the Si Waste of Solar Cell Industry (태양전지 산업(産業)에서 배출(排出)되는 Si waste로부터 SiC 분말 제조에 관한 연구(硏究))

  • Jang, Eun-Jin;Kim, Young-Hee;Lee, Yoon-Joo;Kim, Soo-Ryong;Kwon, Woo-Teck
    • Resources Recycling
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    • v.19 no.5
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    • pp.44-49
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    • 2010
  • SiC powders have been recovered from silicon-containing waste slurry by carbothermal reduction method with carbon black. Large amount of silicon-containing waste slurry is generated from Solar Cell industry. In an environmental and economic point of view, retrieve of the valuable natural resource from the silicon waste is important. In this study, SiC powder recovered by the reaction ball-milled silicon powder from waste and carbon black at $1350^{\circ}C$ for 3h under vacuum condition. Physical properties of samples have been characterized using SEM, XRD, Particle size analyzer and FT-IR spectroscopy.

The Characterization and Sintering Behavior of Alumina Powder Prepared by Heat-treatment of Artificial Marble Waste Containing $Al(OH)_3$ Powder ($Al(OH)_3$ 함유(含有) 인조대리석폐기물(人造大理石廢棄物)로부터 제조(製造)된 알루미나 분말(粉末)의 특성(特性) 및 소결거동(燒結擧動) 연구(硏究))

  • Ryu, Sung-Soo;Seo, Sung-Gyu;Kim, Hyung-Tae;Kim, Hyeong-Jun;Park, Jun-Gyu;Yang, Jae-Gyu
    • Resources Recycling
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    • v.18 no.2
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    • pp.69-76
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    • 2009
  • Alumina powder was prepared from heat-treatment of artificial marble waste fine aggregate containing $Al(OH)_3$ for the purpose of the feasibility of its recycling. Artificial marble waste was heat-treated between $500^{\circ}C$ and $1000^{\circ}C$ and XRD, BET surface area, BJH pore size distribution and adsorption of As were analyzed for heat-treated powder. It was found that the adsorption efficiency of As was significantly affected by phase composition of alumina powder rather than its physical characteristic. Heat-treated powder compact was sintered to produce the pellet. Alumina pellet with porosity more than 60% could be obtained after sintering below $1200^{\circ}C$ and also the addition of glass powder as a sintering aid had a positive effect on lowering sintering temperature, led to the high porosity near 60% and adsorption of As over 60% even at $900^{\circ}C$.

Compressive Strength Properties of Geopolymers from Pond Ash and Possibility of Utilization as Synthetic Basalt

  • Kim, Byoungkwan;Lee, Bokyeong;Chon, Chul-Min;Lee, Sujeong
    • Journal of the Korean Ceramic Society
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    • v.56 no.4
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    • pp.365-373
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    • 2019
  • Pond ash is a mixture of mostly coarser fly ash and bottom ash. The recycling rate of pond ash is low because pond ash is mixed with seawater and deposited in ponds. The pond ash is also subjected to natural weathering over a period of time. In this study, we investigated whether pond ash can be used as a raw material of geopolymers, without any purification process or through a minimal purification process. In addition, we investigated whether synthetic basalt made by adding foaming agent to geopolymer or casting it into a mold can show the surface of the natural basalt as it is. The highest 7-day compressive strength in geopolymers from pond ash without purification process was 26 MPa. The highest 7-day compressive strength in geopolymers from pond ash with impurities removed through dry sieve analysis was found to improve to 80 MPa. On the other hand, synthetic basalt made with geopolymer was shown to be more advantageous aesthetically when produced by casting it in a silicone mold rather than by adding a foaming agent. Non-purified pond ash can be made into geopolymers having low strength. Pond ash purified by sieving can, without use of an aggregate, be made into geopolymer having high-strength. Also, it is possible to produce synthetic basalt with the same appearance as natural basalt and sufficient strength for commercialization. This process will contribute to the mass consumption and recycling of pond ash.

Test Run of the Pilot Plant for Recycling of the Waste Aluminum Dross (알루미늄 페드로스 재활용 파일롯트플랜트 시운전 결과)

  • Park, Hyung-Kyu;Lee, Hoo-In;Choi, Young-Yoon
    • Resources Recycling
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    • v.14 no.4 s.66
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    • pp.41-46
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    • 2005
  • Waste aluminum dross is a major waste in the aluminum scrap smelters and its major components are alumina and metallic aluminum. In this study, waste aluminum dross was leached with sodium hydroxide solution to extract the remained aluminum into the solution, and aluminum hydroxide was recovered from the leached solution. The dross residue generated at the leaching step was recycled into alumina base ceramic materials through a series of treatments such as washing, drying and roasting. Also, a pilot plant was constructed and tested to demonstrate the developed technology. Four tons of waste aluminum dross could be processed per day. From the test run of the pilot plant, it was confirmed that the developed technology could be applied to commercialization.

Synthesis of High Value-added Carbide Materials (MXenes) from Recycled Oxides (재활용 산화물로부터 고부가가치 탄화물(맥신) 소재 합성)

  • Hanjung Kwon
    • Resources Recycling
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    • v.33 no.4
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    • pp.29-35
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    • 2024
  • The recycling of waste resources, such as spent catalysts, primarily involves leaching and extracting metal components via smelting. These metal components are then recovered as salts, such as sulfates and nitrates. When crystallization occurs during the calcination of the recovered salts, the salts are converted into oxides, which are then reduced to form metals or ceramic materials. Common reducing agents used in oxide reduction include hydrogen and carbon, and metal powders are obtained upon reduction. Carbide synthesis can occur if the recycled element is a transition metal and carbon is used as the reducing agent. Despite being ceramic materials, transition metal carbides exhibit excellent conductivity owing to their metallic bonding. Recently, MXene, a two-dimensional transition metal carbide, has gained attention for electromagnetic wave shielding, secondary battery electrodes, and water purification owing to its electrical conductivity and large surface area. This study developed a process for synthesizing high-value MXene materials from waste resources. The properties of these MXenes were evaluated to confirm the potential of using waste resources as raw materials for MXenes.

Development of Ceramic Body using Waste Celadon (청자 파도자기를 활용한 도자기 소지 개발)

  • Lee, Jea-Il;Park, Joo-Seok;Lee, Yong-Seok;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.602-608
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    • 2009
  • The yield is increasing as the manufacturing technology of ceramics progresses, however, there are many ceramics of poor quality due to variables upon producing ceramics. Some of those waste ceramics are recycled by sanitary ware or tile manufacturers, but most of them are filled in making environmental problem. Therefore, a research begins to recycle waste ceramic ware as alternative to some imported ceramic ware materials and to reduce environmental pollution. This study, succeeding last study which applied waste white ware as ceramic body material, aimed to solve problems of environment and materials by recycling waste ceradon generated in specially formed areas for ceramic in Gyeonggi-do such as Icheon, Yeoju and Gwangju as the ceramic body material. Consequently, the addition of waste ceramic ware into the ceramic body was judged to have limit up to 30% according to plasticity measurement. As we added shredded waste ceramic ware as much as 30% into basic ceramic body and checked its features, the pore rate and absorption rate were good to be average 4% and 3% respectively. In addition, it showed strength more than 720 kgf/$cm^2$ which is higher than existing ceradon body on the market with good sinter state; so it is judged to be available or developed as new ceramic body.

제지산업의 지속가능한 처리공정을 위한 제지슬러지 재활용 기술

  • Im, Mi-Hui;Lee, Jong-Gyu;Nam, Seong-Yeong;An, Ji-Hwan
    • Ceramist
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    • v.14 no.2
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    • pp.7-14
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    • 2011
  • This paper has investigated physicochemical properties and conventional and environmental-friendly treatment methods of paper mill sludge to emphasize the importance and necessity of the sludge recycling. The paper mill sludge generally shows high contents of calcium and water, and is mostly discharged by landfill after incineration process rather than being recycled due to technical or economical problems. In recent years, however, several possible methods for recycling the paper mill sludge have been suggested for its sustainable process as follows; compost, raw material for the construction and paper industry, new energy source for reducing fossil fuel use and raw material of activated carbon for treating paper mill wastewater. Thus the authors suggest that practical recycling technologies of the paper mill sludge must be developed for substantiality in the paper industry through comprehending physicochemical compositions and generation status of the sludge and actively performing various related studies. Furthermore, this investigation could be used as preliminary information for the study on recycled paper development using paper mill sludge incineration ash.

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Recycling Technology of Aluminum UBC To Can Body Sheets

  • Lim, Cha-Yong;Kang, Seuk-Bong
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.173-178
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    • 2001
  • The materials processing factors such as remelting and casting, heat treatment and microstructure, sheet rolling and can body forming in the aluminum can-to-can recycling procedure have been investigated. Aluminum used beverage can(UBC) was remelted together with virgin aluminum. The ceramic filter was used during casting to remove large impurities. As-cast microstructure was composed of large intermetallic compound (mainly $\beta$ -phase) distributed in the aluminum matrix. By heat treatment, $\beta$ -phase was transformed to $\alpha$ -phase which was also formed from $Mg_2$Si particles. The heat treated ingots were hot-rolled at 48$0^{\circ}C$ and cold-rolled to thin sheets. Can making from this thin sheets was successful and earing was measured after can making. There was a critical cold reduction rate for minimum earing. Some cracks were initiated from the impurity particles which was not removed during filtering.

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Influence of Fly Ash Addition on Properties of Ceramic Wall Tiles (플라이애시 첨가에 따른 세라믹 벽타일 소지의 물성변화)

  • Kim, Jin-Ho;Cho, Woo-Seok;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Korean Journal of Materials Research
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    • v.27 no.2
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    • pp.76-81
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    • 2017
  • Recently, there have been many efforts to establish suitable processes for recycling fly ash, which is produced in thermal power plants and which poses serious environmental problems. Use of fly ash as a major ingredient of ceramic tiles can increase fly ash utilization, as well as reduce the cost of raw materials in ceramic tile production. In this study, the effects of fly ash addition on ceramic tile properties such as bending strength, water absorption and porosity were investigated. A manufacturing process of ceramic tile was developed for utilization of fly ash with high carbon content. In this approach, it is important to hold the ceramic tiles at a temperature that is sufficient for carbon oxidation, before the pores supplying oxygen to the inside of the ceramic tile are sealed. Ceramic wall tiles were manufactured with 0-40wt% of fly ash addition. The water absorption and porosity of the fired body were slightly changed with increasing fly ash content up to 30wt% and decreased with greater amounts of fly ash addition. The bending strength of ceramic tile including 10wt% fly ash increased, reaching a level comparable to that of ceramic tile without fly ash.

Image and Phase Analysis of Low Carbon Type Recycled Cement Using Waste Concrete Powder (폐콘크리트 미분말을 사용한 저탄소형 시멘트의 조직 및 상분석)

  • Song, Hun;Shin, Hyeon-Uk;Lee, Jong-Kyu;Chu, Yong-Sik;Park, Dong-Chan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.4
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    • pp.314-320
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    • 2014
  • Although the cement industry serves as the cornerstone of the construction industry by supplying one of its fundamental materials, it confronts new environmental challenges due to the problem of the $CO_2$ generated from raw materials and fuel used in the cement manufacturing process. Also, concrete structures can be decomposed and reused as construction materials. Simply in terms of the cyclic processing of $CO_2$, recycling waste concrete to manufacture recycled aggregate or recycling waste concrete powder, which is the material for cement can be considered optimally environment-friendly practices. This study contributes to the aim of manufacturing high value added materials that exploits the chemical properties of the waste concrete powder. From the research results, waste concrete powder is feasible to use to produce low carbon type recycled cement.