• Restorative Dentistry and Endodontics
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• 제42권2호
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• pp.125-133
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• 2017

Objectives: This study compared the effect of hexamethyldisiloxane (HMDSO) and ammonia ($NH_3$) plasmas on the bond strength of resin cement to fiber posts with conventional treatments. Materials and Methods: Sixty-five fiber posts were divided into 5 groups: Control (no surface treatment); $H_2O_2$ (24% hydrogen peroxide for 1 min); Blasting (blasting with aluminum oxide for 30 sec); $NH_3$ ($NH_3$ plasma treatment for 3 min); HMDSO (HMDSO plasma treatment for 15 min). After the treatments, the Ambar adhesive (FGM Dental Products) was applied to the post surface (n = 10). The fiber post was inserted into a silicon matrix that was filled with the conventional resin cement Allcem Core (FGM). Afterwards, the post/cement specimens were cut into discs and subjected to a push-out bond strength (POBS) test. Additionally, 3 posts in each group were evaluated using scanning electron microscopy. The POBS data were analyzed by one-way analysis of variance and the Tukey's honest significant difference post hoc test (${\alpha}=0.05$). Results: The Blasting and $NH_3$ groups showed the highest POBS values. The HMDSO group showed intermediate POBS values, whereas the Control and $H_2O_2$ groups showed the lowest POBS values. Conclusion: Blasting and $NH_3$ plasma treatments were associated with stronger bonding of the conventional resin cement Allcem to fiber posts, in a procedure in which the Ambar adhesive was used.

• 폴리머
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• 제32권6호
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• pp.555-560
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• 2008

폴리머를 혼입한 폴리머 시멘트 모르타르 및 콘크리트는 인장강도, 휨강도, 접착성, 수밀성, 내마모성 그리고 내약품성 등을 개선시키는데 우수한 효과가 있어 고성능이 요구되어지는 건축 구조물의 외장재, 바닥 마감재, 포장재, 방수재, 장식 코팅재, 그리고 보수재 등의 용도로 많이 사용되고 있다. 또한, 기존의 시멘트 콘크리트의 취약성을 보완하는 측면뿐만 아니라 보다 내구적이고 안정적인 구조재료의 역할을 할 수 있어 다양한 용도의 개발이 이루어지고 있다. 본 연구에서는 폴리머를 건축재료인 시멘트 콘크리트에 적용하기 위한 기초적 실험으로써 폴리머 시멘트 모르타르를 제작하여 그 특성을 파악하고 건축재료로서의 폴리머 이용 가능성을 확인하고자 하였다. 폴리머를 시멘트 모르타르에 혼입하여 적용해 본 결과, 보통 시멘트 모르타르에 비해 폴리머 시멘트 모르타르의 강도와 내구성 증진효과가 높게 나타나는 것을 알 수 있었다.

• 공업화학
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• 제16권2호
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• pp.180-186
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• 2005

본 논문은 유기물과 중금속이 함께 포함되어 있는 폐수 슬러지의 시멘트 고형화를 위해 포졸란물질인 실리카흄을 고화보조재로 사용한 연구결과이다. 실리카흄을 고화보조재로 사용할 경우 고화체의 일축압축강도는 현저히 증가하는 결과를 보여주었으며, 실리카흄의 시멘트 대체가 전체 배합물의 15%까지 증가하였을 때 일축압축강도는 실리카흄을 전혀 사용하지 않았을 경우에 비하여 66.7%까지 증가하는 결과를 보여주었다. 또한 시멘트가 실리카흄으로 대체되는 양이 증가하면서 총 유기탄소와 중금속인 크롬의 용출량은 감소하는 결과를 보여주었으며, 배합물 중 실리카흄이 5%를 차지할 때 중성의 용출액에서 총 유기탄소의 85%가 용출억제되었으며, 산성의 용출액에서 0.76 mg-Cr/g-Cr의 크롬만이 용출되었다. 전자주사현미경과 X-선 회절분석, 적외선 분광분석 등을 이용한 미세구조분석 결과 실리카흄은 시멘트경화 초기에 크링커 입자를 피복하여 초결(initial setting)과 수화를 저해하는 에트링가이트(ettringite)의 형성을 감소시키는 것으로 나타났다. 본 연구결과 중금속과 유기물이 혼합된 슬러지의 시멘트 고형화에 있어서 실리카흄의 첨가는 유기물질이 시멘트 수화반응에 미치는 악영향을 억제하고 중금속 및 유기물의 용출을 감소시키는 것으로 나타났다.

• 한국환경과학회지
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• 제15권5호
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• pp.431-438
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• 2006

The strength, water permeability, and photo-degradation efficiency of NOx of porous concrete with a new concept were studied in this paper. The porous concrete was comprised of coarse aggregate of maximum size 40 mm, cement, silica fume, water and air-entraining(AE) water reducing agent. The strength of porous concrete was strongly related to its matrix proportion and compaction energy. An experimental test was carried out to study the parameters of cement proportions and silica fume content for pavement applications of porous concrete which were paving a footpath, a bikeway, a parking lot, and a driveway. The regressed equations of relation-ships between compressive strength and flexural strength, and coefficient permeability and void ratios were indicated as y=7.69x+71.74 and $y=0.42e^{0.28x}$. A method of making an air purification-functioning road, which was spraying a mixture of a photocatalyst, cement, and water onto the surface of the road, was suggested.

• 콘크리트학회논문집
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• 제17권4호
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• pp.663-670
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• 2005

The present study concerns the influence of binder type on the chloride-induced corrosion being accompanied by the chloride threshold level (CTL), chloride transport and as their results the corrosion-free lift. Two levels of cement content, $30\%$ PFA and $65\%$ GGBS concrete were employed. It was found that the most dominant factor to the CTL is the entrapped air void content at the steel-concrete interface, irrespective of the chloride binding capacity, binder type and acid neutralisation capacity of cement matrix. The CTL for lower interfacial air void contents was significantly increased up to $1.52\%$ by weight of cement, whereas a same mix produced $0.35\%$ for a higher level of voids. Because of a remarkable reduction in the diffusion fur GGBS concrete, its time to corrosion ranges from 255 to 1,250 days, while the corrosion-free life for control varies from 20 to 199 days sand for $30\%$ PFA concrete from 200 to 331 days.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2009년도 춘계 학술논문 발표대회 학계
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• pp.93-96
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• 2009

This study is to examine a change of quality and a material performance of fiber reinforced cement composite for mass production. It is necessary to make Strain-hardening cementitious composite(SHCC) by batcher plant for ready-mixed concrete and use the performance of SHCC which made based on laboratory level. This study makes a comparative performance of press and mechanics that is the property of Strain-hardening by direct tension. In case of making by batcher plant. This experiment has demonstrated that even if it takes long after being mixed small and compared with the one which made based on laboratory, it has a tendency to be dissatisfied with fiver's dispersion and lower its performance of Strain-hardening. The reason why the material performance of SHCC for mass production went down is through SHCC that mixed sometimes matrix's viscosity and fiber's dispersion.

• Advances in concrete construction
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• 제5권5호
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• pp.423-436
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• 2017

Today, pozzolans are widely used in construction for various reasons such as technical and economic efficiency. In this research, in order to evaluate some of important properties of concrete, silica fume and fly ash have been used as a replacement for cement in different mass percentages. Concrete mixtures were made from a water-cement ratio of (0.45) and cured under similar conditions. The main focus of this study was to evaluate the permeability and mechanical properties of concrete made from binary and ternary cementitious mixtures of fly ash and silica fume. In this study permeability of concrete was studied by evaluating the sorptivity, water absorption, water penetration depth, electrical resistivity and rapid chloride permeability (RCP) tests. Mechanical properties of concrete were evaluated with compressive strength, splitting tensile strength and modulus of elasticity. Scanning electronic microscopy (SEM) was used to characterize the effects of silica fume and fly ash on the pore structure and morphology of concrete with cement based matrix. The results indicated that the incorporation of silica fume and fly ash increased the mechanical strength and improved the permeability of concrete.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2022년도 가을 학술논문 발표대회
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• pp.167-168
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• 2022

Recently, starting with the permanent suspension of Gori 1 in Korea, the importance of the disposal of concrete structures in nuclear power plants has emerged, and environmental and safety are required to be proved accordingly. Safe radioactive waste disposal technology that immobilizes harmful radioactive elements, which are by-products of nuclear power, inside a solid matrix and recycling measures are needed to secure an efficient waste disposal space. This study was conducted to confirm whether recycled cement generated in the process of radioactive concrete treatment can be used as a solidifying material for radioactive waste treatment. In order to simulate the concrete exposed to radiation, aqueous solutions of Di-water, CsCl 1M, and CoCl₂ 1M were used as blending water at W/B 0.5. Tricalcium phosphate and Prussian blue were substituted with 5 wt.% based on the weight of recycled cement as a binder to improve solidification performance, and their hydration characteristic was analyzed.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 봄 학술논문 발표대회
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• pp.151-152
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• 2023

This study investigates the effect of nano-silica and nano-calcite on the hydration properties and mechanical performance of limestone calcined clay cement (LC³) paste. The pastes were synthesized by replacing limestone with nano-silica and nano-calcite in order to enhance the mechanical properties in both early and late stages of hydration. The nano-calcite enhanced the strength of LC³ pastes at 1 day of hydration, however, the strength decreased compared to the ordinary LC³ pastes afterwards due to excessive amount of carboaluminate produced in the pastes. On the other hand, nano-silica improved the mechanical properties of LC³ pastes at all ages of hydration. This is mainly due to the nucleation effect and pozzolanic reaction of nano-silica, affecting the early age and late ages of hydration, respectively. The nucleation effect of both nanomaterials were confirmed by the analysis of hydration heat, supporting the enhanced early age strength of nanomaterial incorporated LC³ pastes. Furthermore, the dense matrix was shown in the pore size distribution, and the increased C-S-H due to the pozzolanic reaction evidence the improved compressive and splitting tensile strength of nano-silica incorporated LC³ pastes.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.607-610
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• 2005

If cement can be manufactured with industrial byproducts such as granulated blast furnace slag(GBFS), phosphogypsum(PG), and waste lime(WL) instead of clinker as its counterproposal, there would be many advantages, including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by $CO_2$ discharge, and reduction of the production cost. This research investigates the chemical resistance of NSC mortar added PG and WL to GBFS as sulfate and alkali activators. The result of experiment of chemical resistance, showed that NSC is very excellent in acid resistance and seawater resistanc. Such a reasons are that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.