• 제목/요약/키워드: Cement Waste Form

검색결과 37건 처리시간 0.024초

Comparative Study Between Geopolymer and Cement Waste Forms for Solidification of Corrosive Sludge

  • Lee, Juhyeok;Kim, Byoungkwan;Kang, Jaehyuk;Kang, Jaeeun;Kim, Won-Seok;Um, Wooyong
    • 방사성폐기물학회지
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    • 제18권4호
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    • pp.465-479
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    • 2020
  • Two waste forms, namely cement and geopolymer, were investigated and tested in this study to solidify the corrosive sludge generated from the surface and precipitates of the tubes of steam generators in nuclear power plants. The compressive strength of the cement waste form cured for 28 days was inversely proportional to waste loading (24.4 MPa for 0wt% to 2.7 MPa for 60wt%). The corrosive sludge absorbed the free water in the hydration reaction to decrease the cementation reaction. When the corrosive sludge waste loading increased to 60wt%, the cement waste form showed decreased compressive strength (2.7 MPa), which did not satisfy the acceptance criteria of the repository (3.45 MPa). Meanwhile, the compressive strength of the geopolymer waste form cured for 7 days was proportional to waste loading (23.6 MPa for 0wt% to 31.9 MPa for 40wt%). The corrosive sludge absorbed the free water in the geopolymer when the water content decreased, such that a compact geopolymer structure could be obtained. Consequently, the geopolymer waste forms generally showed higher compressive strengths than cement waste forms.

Evaluation of cementation of intermediate level liquid waste produced from fission 99Mo production process and disposal feasibility of cement waste form

  • Shon, Jong-Sik;Lee, Hyun-Kyu;Kim, Tack-Jin;Kim, Gi-Yong;Jeon, Hongrae
    • Nuclear Engineering and Technology
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    • 제54권9호
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    • pp.3235-3241
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    • 2022
  • The Korea Atomic Energy Research Institute (KAERI) is planning the construction of the KIJANG Research Reactor (KJRR) for stable supply of 99Mo. The Fission 99Mo Production Process (FMPP) of KJRR produces solid waste such as spent uranium cake and alumina cake, and liquid waste in the form of intermediate level liquid waste (ILLW) and low level liquid waste (LLLW). This study thus established the operating range and optimum operating conditions for the cementation of ILLW from FMPP. It also evaluated whether cement waste form samples produced under optimum operational conditions satisfy the waste acceptance criteria (WAC) of a disposal facility in Korea (Korea radioactive waste agency, KORAD). Considering economic feasibility and safety, optimum operational conditions were achieved at a w/c ratio of 0.55, and the corresponding salt content was 5.71 wt%. The cement waste form samples prepared under optimum operational conditions were found to satisfy KORAD's WAC when tested for structural stability and leachability. The results indicate that the proposed cementation conditions for the disposal of ILLW from FMMP can be effectively applied to KJRR's disposal facility.

해체 콘크리트 폐기물 최종처분을 위한 시멘트 고화체 특성 평가 (Characterization of Cement Waste Form for Final Disposal of Decommissioned Concrete Waste)

  • 이윤지;황두성;이기원;정경환;문제권
    • 방사성폐기물학회지
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    • 제11권4호
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    • pp.271-280
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    • 2013
  • 원자력 발전소와 연구시설의 해체 시 다량의 오염된 방사성 콘크리트 폐기물이 발생한다. 현재 국내에는 연구로 1, 2호기의 해체와 제염사업이 진행 중이며, 약 800여 드럼 (200 L)의 콘크리트 폐기물이 발생하였다. 이들 방사성 콘크리트 폐기물은 최종처분을 위해 200 L 드럼에 덩어리 크기의 콘크리트를 채우고, 시멘트 모르타르 형태로 제조한 입자상 폐기물로 빈 공간을 채우며 혼용 고정화 및 안정화하는 일련의 과정이 필요하다. 이에 본 연구에서는 콘크리트 폐기물, 물, 시멘트의 최적의 혼합비율을 찾고, 처분장 폐기물 인수기준에 준하기 위한 고화체의 특성을 평가하였다. 모르타르 유동도, 고화체 압축강도, 침출에 대한 안정성, 열 저항성 등의 인자에 따라 평가한 결과, 콘크리트 폐기물, 물, 시멘트의 배합비 75:15:10wt%에서 평가인자 기준에 도달하였으며, 콘크리트 폐기물 75%에 미분말 콘크리트 폐기물을 최대 40wt%까지 포함시켜 시멘트 고화체를 제조한 경우에도 압축강도를 만족하였다. 입자의 충진 밀도의 증가로 scale-up실험에서는 75:10:15wt%의 배합비에서 작업도 및 압축강도 범위를 만족하였다.

A review on the effect of marble waste on properties of green concrete

  • Rachid Djebien;Amel Bouabaz;Yassine Abbas;Yasser N. Ziada
    • Advances in concrete construction
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    • 제15권1호
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    • pp.63-74
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    • 2023
  • All production and consumption activities produce wastes, which often cause damage to our environment and multiple risks to the human health. The valorization of these wastes in concrete technology is a future solution that will allow finding other construction materials sources, optimizing energy consumption and protecting the environment. Among these wastes, there is the marble waste. Every year, huge amount of marble waste is discarded as dust or aggregates form, in open-air storage areas causing serious problems for the environment and public health. In this context, the incorporation of marble waste as a replacement of ordinary aggregates or cement in concrete composition is actively investigated by researchers. This paper presents a comprehensive review of published studies over the last 20 years, dealing the effect of marble waste on fresh and hardened properties of concrete. Most of the studies carried out have used marble waste as dust with substitution rates between 5 and 20%. Besides the economic and ecological benefits, this review showed that marble waste can improve the physical, mechanical and durability properties of concrete. This improvement depends on the form (dust, fine aggregate or coarse aggregate), substitution method (as cement or aggregates replacement) and substitution rate of marble waste. Additionally, the review results showed that the use of 10-15% of marble waste dust as cement substitution can lead to increase the compressive strength.

방사성고화체로부터의 $^{60}$ Co, $^{137}$ Cs 침출에 대한 표준시험법의 상호비교 (Comparative Evaluation of Various Standard Methods in Leaching Test of Radioactive Waste Form)

  • 김기홍;유영걸;정경기;홍권표;이락희;정의영;고덕준;김헌
    • 방사성폐기물학회지
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    • 제1권1호
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    • pp.93-103
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    • 2003
  • IAEA, FT-04-020 및 ANS 16.1의 침출시험법을 각각 수행하여 얻은 시험결과를 이용하여 상호 비교 평가하였다. 붕산을 함유한 파라핀 및 시멘트 고화체에서의 $^{60}$Co 과 $^{137}$Cs의 ANS 16.1의 침출지수는 6이상이었으나 고화매질과 탈염수의 종류에 따라 상반되는 침출거동을 보였다. 침출수로 합성해수와 탈염수를 사용하였을 경우 $^{60}$Co는 시멘트 고화체에서는 합성해수, 파라핀 고화체에서는 탈염수에서 침출이 높았다. 반면에 $^{137}$Cs의 침출정도는 시멘트에서는 탈염수, 파라핀에서는 합성해수에서 높았다. $^{60}$Co의 침출분율은 시멘트 고화체에서 IAEA > ANS > FT의 순으로 높았으며, 반대로 파라핀고화체에서는 이의 역순이었다.

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방사성고화체로 부터의 Co, Cs침출에 대한 표준시험법의 상호비교 (Comparative Evaluation of Various Standard Methods in Leaching Test of Radioactive Waste Form)

  • 김기홍;유영걸;정경기;홍권표;이락희;정의영;고덕준;김헌
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2003년도 가을 학술논문집
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    • pp.21-31
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    • 2003
  • IAEA, FT-04-020, ANS 16.1의 침출시험법을 각각 수행하여 얻은 시험결과를 이용하여 상호비교 평가하였다. 붕산을 함유한 파라핀 및 시멘트 고화체에서의 Co-60과 Cs-137의 침출지수는 6이상이었으나 고화매질과 탈염수의 종류에 따라 상반되는 침출거동을 보였다. 침출수로 합성해수와 탈염수를 사용하였을 경우 Co는 시멘트 고화체에서는 합성해수, 파라핀 고화체에서는 탈염수에서 침출이 높았다. 반면에 Cs의 침출정도는 시멘트에서는 탈염수, 파라핀에서는 합성해수에서 높았다. Co의 침출분율은 시멘트 고화체에서 IAEA > ANS > FT의 순으로 높았으며, 반대로 파라핀 고화체에서는 이의 역순이었다.

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재생시멘트를 이용한 콘크리트벽돌의 물성 연구 (The Study Concrete Brick Material of Recycle Cement Using)

  • 서경호;박차원;안재철;강병희
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2004년도 학술대회지
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    • pp.87-90
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    • 2004
  • Serious problems of the environment protection and resource exhaustion are exhibited. due to the increase of the construction materials and activation of the remodeling, recently. Especially, most of the advanced countries. recycling plan for the waste concrete is vigorously progressing. The purpose of this study is making advances in the recycling of waste concrete material for use as recycled aggregate to make secondary concrete product. Using recycled aggregates form demolished concrete, we manufactured cement bricks to experiment overall performance in Korean Standard and feasible performances. On the recycled cement, in the case of cement : aggregate is 1 : 7 is satisfied with KS F 4004 : dimensions, water absorption, compressive strength of quality of a standard. So we concluded that it has great feasibility to apply these products to construction industry.

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