• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.218-222
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• 2004

Batch slurry experiments were conducted to develop cement/slag/Fe(II) system that could treat hazardous liquid wastes containing halogenated organic solvents. Portland cement in combination with Fe(II) was reported to reductively dechlorinate chlorinated organics in a modified solidification/stabilization process. TCE (trichloroethylene) was used a model halogenated organic solvent. The objectives of this study were to assess the feasibility of using cement and steel converter slag amended with Fe(II) as a low cost abiotic reductive dechlorination and to investigate the kinetics of TCE dechlorination over a wide range of TCE concentration. From the result of screening experiments, cement/slag/Fe(II) system was identified as a potentially effective system to treat halogenated organic solvent. Kinetic studies were carried out to further investigate degradation reaction of TCE NAPL (Non Aqueous Phase Liquids) in cement/slag/Fe(II) systems by using batch slurry reactors. Degradation rate of TCE solution in this system can be explained by pseudo-first-order rate law because the prediction with the rate law is in good agreement with the observed data.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.10
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• pp.1034-1038
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• 2008

Degradative Solidification/Stabilization(DS/S) is a modification of conventional Solidification/Stabilization(S/S) that incorporates degradative processes for organic contaminant destruction with the low cost of conventional S/S. Inorganic contaminants are immobilized and chlorinated organic contaminants are destroyed by DS/S treatment. In this study, a DS/S using cement/slag/Fe(II) systems as binder was investigated to assess its effectiveness in degrading chloroform(CF) and methylene chloride(MC) contained in hazardous liquid wastes. The initial concentration of CF was 0.26 mM, 1.0 mM, 8.4 mM, 25 mM and 42 mM and Fe(II) was 200 mM. The result showed that degradation of CF in various concentration was in one kind reaction as pseudo-first-order and 95% of 0.26 mM initial concentration of CF was removed in five days. 50 mg/L of heavy metal was added in order to accelerate the rate of degradation of MC and initial concentration of MC was 3.50 mM however, degradation did not occur in system. Thus additional studies needed for degradation of MC and more studies on other reaction pathways products will help elucidate reaction mechanisms and pathways for chlorinated methanes in cement/slag/Fe(II) systems.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.1B
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• pp.97-103
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• 2009

The decompostion characteristics of NAPL TCE in cement/slag/Fe(II) system were studied with various TCE concentration and amounts of binders (cement/slag) For analyses of the TCE degradation by cement/slag/Fe(II), TCE solution injected using gas-tight syringe after TCE solution dissolved a methanol. Initial concentrations of TCE are 0.42 mM, NAPL condition 11.7 mM and saturated condition 16.8 mM respectively. The result showed that the cases of 8.4 mM and 4.2 mM are decreased 88% of total TCE concentration within 18 days. NAPL condition 11.7 mM was decreased 84% within 50 days and saturated condition 16.8 mM was decreased 60% of total TCE concentration within 60 days respectively. This showed that degradations of TCE in various concentrations were in one kind reaction as pseudo-first-order. TCE was dissolved as aqueous solution before degraded. The reaction rate was increased $0.12day^{-1}$, $0.24day^{-1}$, $0.31day^{-1}$ when the mass of media 0.1, 0.2, 0.3 S/L rate was increased. TCE reaction speed is affected by cement/slag surface ares in this system. When HDTMA, experimental facter, was added, TCE decomposition rate was high despite the high concentration of NAPL. and The decompostion characteristics of NAPL TCE in cement/slag/Fe(II) system were studied by using modeling.