• Journal of the Korean Society of Manufacturing Process Engineers
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• v.19 no.11
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• pp.8-15
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• 2020

The government has announced its Hydrogen Economy Roadmap to strengthen global competitiveness on the hydrogen economy by focusing on hydrogen fuel cell electric vehicles and fuel cells. In this regard, the interest on the economics and safety of the infrastructure of hydrogen stations has also increased. In this study, a test bed similar to an actual hydrogen charging facility was built, and a prototype of a piston-type compressor was modeled. In this model, the piston was hydraulically compressed to progressively test leakage, leakage rate, and durability and to check for any malfunction. Moreover, the leakage rate, cylinder leak performance, and compressor operation durability were evaluated for safety; it was confirmed that there were no abnormalities. Nevertheless, an investigation of the long-term use and operating pressure of the compressor is necessary to verify the safety of developing a100-MPa domestic compressor in the future.

• Journal of Electrochemical Science and Technology
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• v.8 no.4
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• pp.265-273
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• 2017

Solid-state alkaline water electrolysis is a promising method for producing hydrogen using renewable energy sources such as wind and solar power. Despite active investigations of component development for anion exchange membrane water electrolysis (AEMWE), understanding of the device performance remains insufficient for the commercialization of AEMWE. The study of assembled AEMWE devices is essential to validate the activity and stability of developed catalysts and electrolyte membranes, as well as the dependence of the performance on the device operating conditions. Herein, we review the development of catalysts and membranes reported by different AEMWE companies such as ACTA S.p.A. and Proton OnSite and device operating conditions that significantly affect the AEMWE performance. For example, $CuCoO_x$ and $LiCoO_2$ have been studied as oxygen evolution catalysts by Acta S.p.A and Proton OnSite, respectively. Anion exchange membranes based on polyethylene and polysulfone are also investigated for use as electrolyte membranes in AEMWE devices. In addition, operation factors, including temperature, electrolyte concentration and acidity, and solution feed methods, are reviewed in terms of their influence on the AEMWE performance. The reaction rate of water splitting generally increases with increase in operating temperature because of the facilitated kinetics and higher ion conductivity. The effect of solution feeding configuration on the AEMWE performance is explained, with a brief discussion on current AEMWE performance and device durability.

• Journal of Hydrogen and New Energy
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• v.29 no.5
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• pp.450-457
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• 2018

To design the practical core-shell electrocatalysts, combination of core and shell materials is important to meet catalytic activity and durability target. In general, Pd is considered as a good core material due to its best activity caused by strain/ligand effect. Preparing Pd nanoparticles can be a starting point in fabricating core-shell type electrocatalysts, much simplified Pd preparing process is suggested by using carbon monoxide (CO) as a reducing agent and/or capping agent. The solvent composition and reaction temperature can control to nanosheet, tetrahedron, and sphere without using additional stabilizer. Among them, Pd nanosheet which has mainly (111) plane showed about 3 times higher electrocatalytic activity for oxygen reduction reaction (ORR) to the spherical Pd nanoparticles. The enhanced ORR activity of Pd nanosheets can be attributed to the exposure of Pd (111) surface and the high electrochemical surface area. Therefore, we demonstrated that the shape of Pd nanomaterials is easily controlled via a facile reduction method using CO, and (111) plane-oriented Pd nanosheets can be a promising ORR catalysts and core material for polymer electrolyte fuel cells (PEFCs).

• Membrane Journal
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• v.32 no.6
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• pp.496-513
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• 2022

In this study, we sought to verify the applicability of anion exchange membrane water electrolysis system using FAA-3-50, Neosepta-ASE, Sustainion grade T, and Fujifilm type 10, which are commercial anion exchange membranes. The morphology of the commercial membranes and the elements on the surface were analyzed using SEM/EDX to confirm the distribution of functional groups included in the commercial membranes. In addition, mechanical strength and decomposition temperature were measured using UTM and TGA to check whether the driving conditions of the water electrolyte were satisfied. The ion exchange capacity and ion conductivity were measured to understand the performance of anion exchange membranes, and the alkaline resistance of each commercial membrane was checked and durability test was performed because they were driven in an alkaline environment. Finally, a membrane-electrode assembly was manufactured and a water electrolysis single cell test was performed to confirm cell performance at 60℃, 70℃, and 80℃. The long-term cell test was measured 20 cycles at other temperatures to compare water electrolysis performance.

• Proceedings of the KIEE Conference
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• 1992.07b
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• pp.847-849
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• 1992

Fluorine-doped ($SnO_2$:F) thin films obtained by pyrosol deposition method have been exposed to R.F. excited pure hydrogen plasma under the following conditions; substrate temperature of 200$^{\circ}C$, $H_2$ pressure of 1 Torr, R.F. input power of 50 mW/$\textrm{cm}^{2}$, $H_2$ flow rate of 30cc/min and exposure time of 15-600 seconds. It is found that the sheet resistance of the films remains unchanged or rather slightly reduces for initial exposure time of 30-60 seconds, but increases sharply with further increasing the exposure time. The optical transmittance of $SnO_2$:F films slows a rapid fall with increasing exposure time except for a film obtained with a solution having $CH_3OH/H_2O$ mol ratio of 2.65, its degradations at the exposure time of 30-60 seconds are about 7-15%. In addition, the exposure of the films to hydrogen plasma atmosphere leads to remarkable changes in the microstructure and chemical composition, which should be attributed to the reduction of $SnO_2$ to SnO and to elemental Sn.

• 한국태양에너지학회:학술대회논문집
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• 2008.04a
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• pp.257-262
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• 2008

In this paper, we study the electric characteristics of shading effects in photovoltaic module in case of outdoor operation. When fabricating PV module, solar cells are connected serially to obtain the high voltage because of its low open circuit voltage. And total current is determined by lowest current among solar cells. When the shading happens on PV module's surface, the current of shaded solar cell determine the total current flow. Because of this, generally by-pass diode is installed on junction box. The bypass diode operate when revered and shaded solar cell's voltage is over 0.6 voltage. The reverse-biased solar cell gives reduced maximum power of PV module and might give negative effect on durability. So, adequate by-pass installation and selection is needed.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.81.2-81.2
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• 2011

The gas diffusion layer (GDL) consists of two main parts, the GDL backing layer, called as a substrate and the micro porous layer (MPL) coated on the GDBL. In this process, carbon particles of MPL penetrates to the GDBL consequently forms MPL penetration part. In this study, the micro porous layer (MPL) penetration thickness is determined as a design parameter of the GDL which affect pore size distribution profile through the GDL inducing different mass transfer characteristics. The pore size distribution and water permeability characteristics of the GDL are investigated and the cell performance is evaluated under fully/low humidification conditions. Transient response and voltage instability are also studied. In addition, to determine the effects of MPL penetration on the degradation, the carbon corrosion stress test is conducted. The GDL that have deep MPL penetration thickness shows better performance in high current density region because of enhanced water management, however, loss of penetrated MPL parts is shown after aging and it induces worse water management characteristics.

• 한국태양에너지학회:학술대회논문집
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• 2009.11a
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• pp.104-109
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• 2009

If the Photovoltaic(PV) Module should get physical load, the PV module will be warped according to elongation of the front glass and then micro-crack will be occurred in the heat sealed Solar Cell. This micro-crack drops output of the short circuit current and the open circuit voltage of the PV Module. This is because of increase of resistance component by micro-crack. Micro-crack at specific Solar Cell in the module reduces the durability of PV Module such as less output, Hot-Spot in the PV module caused by Solar Cell output mismatch, heat generating as resistance component caused by micro-crack. In this study, among some factors which effect to the output of crystalline PV Module, we will see how the micro-crack caused by mechanical stress effects to the electrical output of PV Module.

• Journal of the Korean Ceramic Society
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• v.54 no.3
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• pp.200-204
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• 2017

Molybdenum (Mo), an electrode material of alkali metal thermal-to-electric converters (AMTEC), facilitates grain growth behavior and forms Mo-Na-O compounds at high operating temperatures, resulting in reduced performance and shortened lifetime of the cell. Mo/TiN composite materials have been developed to provide a solution for such issues. Mo is a metal that possesses excellent electrical properties, and TiN is a ceramic compound with high-temperature durability and catalytic activity. In this study, a dip-coating process with an organic solvent-based slurry was used as an optimal coating method to achieve homogeneity and stability of the electrodes. Cell performance was evaluated under various conditions such as the number of coatings, ranging from 1 to 3 times, and heat treatment temperatures of $800-1100^{\circ}C$. The results confirmed that the cell yielded a maximum power of 9.99 W for the sample coated 3 times and heat-treated at $900^{\circ}C$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.25-26
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• 2007

In this paper, we studied the shadow effect which is one of environmental cause for hot-spot phenomenon on PV by considering electrical effects. We fabricated PV module in case of existence and nonexistence of bypass diode. And maximum output power and thermal distribution was analyzed by shadowing solar cell by increase of 5%. From the results, the PV module's(without bypass diode) maximum output power was reduced by hot-spot gradually. But the PV module's(with bypass diode) maximum output power had no reduction by operation of bypass diode, though solar cell is shadowed more than 60%. The solar cell temperature of PV module(without bypass diode) was $10^{\circ}C$ higher compared to module's one. This is a reason for shortening of durability of PV module.