• Title/Summary/Keyword: Cd concentration

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Assessments of Rainwater Runoff Quality from Soil Roofs According to Layer Thickness (흙 지붕 표층 두께에 따른 빗물의 유출 수질 평가)

  • Parkm, Jongseok;Sim, Chunseok;Moon, Byoungseok
    • Journal of Korean Society on Water Environment
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    • v.27 no.3
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    • pp.300-305
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    • 2011
  • This study aimed at analyzing the runoff quality by the layer thickness and material of soil roof to make best use of the rainwater falling on it in terms of safety and efficiency and resulted in the following assessments. It turned out that the concentrations decreased more in T-N, $NO_3$-N, $NH_4$-N, T-P and $PO_4$-P in roof rainwater except 30 cm for the RW1 soil roof after passing through it than those of first rainwater. On the other hand, the concentrations in rainwater passing through gravel roof turned out to be equal or same to those of the first rainwater. As a result of analysis of metallic stuff in runoff, there was no indication of Cd, Cr, Mn and Pb as well. The concentration of Cu, Fe and Zn in rainwater through soil roof became less than that of the first rainwater. In this research, the soil roof showed the good efficiency in lowering the concentration of such components as nitrogen, phosphorus and metals. Based on the results from this work, more practical study would be required further in the future in relation to soil roof when installing the rainwater-utilizing facilities.

A study on applying random forest and gradient boosting algorithm for Chl-a prediction of Daecheong lake (대청호 Chl-a 예측을 위한 random forest와 gradient boosting 알고리즘 적용 연구)

  • Lee, Sang-Min;Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.6
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    • pp.507-516
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    • 2021
  • In this study, the machine learning which has been widely used in prediction algorithms recently was used. the research point was the CD(chudong) point which was a representative point of Daecheong Lake. Chlorophyll-a(Chl-a) concentration was used as a target variable for algae prediction. to predict the Chl-a concentration, a data set of water quality and quantity factors was consisted. we performed algorithms about random forest and gradient boosting with Python. to perform the algorithms, at first the correlation analysis between Chl-a and water quality and quantity data was studied. we extracted ten factors of high importance for water quality and quantity data. as a result of the algorithm performance index, the gradient boosting showed that RMSE was 2.72 mg/m3 and MSE was 7.40 mg/m3 and R2 was 0.66. as a result of the residual analysis, the analysis result of gradient boosting was excellent. as a result of the algorithm execution, the gradient boosting algorithm was excellent. the gradient boosting algorithm was also excellent with 2.44 mg/m3 of RMSE in the machine learning hyperparameter adjustment result.

Hevey Metal Levels in Urine of Residents in Industrial Area (일부 공단지역 주민의 요 중 중금속 농도에 관한 연구)

  • Jou, Hye-Mee;Choi, Su-Hyeon;Chung, Eun-Kyung;Jung, Soon-Won;Yang, Won-Ho;Son, Bu-Soon
    • Journal of Environmental Science International
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    • v.20 no.5
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    • pp.565-574
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    • 2011
  • This study analyzed the concentration of the heavy metals(Cd, Hg, iAs) of urine(n=576) from May, 2007 to Oct 2007. The subject was residents in G, Y, H industrial area, Jeollanam-do, in which exposure due to the adjacency of the industrial complex. As to the heavy metal concentration in the urine of the residents in the whole exposed region and the comparing region, the content of cadmium, mercury, and inorganic arsenic in the exposed region group were 1.23, 1.85, and 8.80 ${\mu}g$/g_ct respectively, and those of the comparing region group were 1.87, 2.00, and 8.93 ${\mu}g$/g_ct respectively, which indicates that the concentration of the comparing group was higher than that of the exposed group. The heavy metal concentration for each age group increased in proportion to age except those under 10 for some substances(p<0.01). As to geometric mean concentration cadmium and inorganic arsenic in urine according to the smoking history of the subject, the concentration of the smoking group and the non-smoking group were 1.65 ${\mu}g$/g_ct and 9.13 ${\mu}g$/g_ct respectively, while those of the non-smoking group were 1.47 ${\mu}g$/g_ct and 8.91 ${\mu}g$/g_ct respectively, which indicates that the former is higher than the latter. As to the inorganic arsenic concentration in urine according to the food preference, in order of vegetable, fish, and meat showed high concentration (p<0.01). To clarify the factors affecting the heavy metal concentration in urine among the subjects, the multiple regression analysis was conducted. As a result, it turned out that as to cadmium content in urine, gender, age, drinking, and smoking have influence on the subjects, with explanatory adequacy of 37.5 %.

Water Quality and Heavy Metals in the Surface Seawaters of the Saemangeum Area during the Saemangeum-dike Construction (새만금 방조제 체절 과정 중 새만금 주변해역 표층수의 수질과 중금속 분포 특성)

  • Kim, Kyung-Tae;Kim, Eun-Soo;Kim, Seong-Soo;Park, Jong-Soo;Park, Jun-Kun;Cho, Sung-Rok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.1
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    • pp.35-46
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    • 2009
  • In order to investigate spatial and temporal distributional characteristics of major water qualities in the Saemangeum area during the Saemangeum dike construction, salinity, COD, dissolved nutrients(DIN, Silicate) and heavy metals were analyzed from the surface water collected in April, May, August and November 2002. The overall value of Salinity, COD, DIN, and silicate in surface waters were in the range of $13.08{\sim}31.96\;psu$, $0.12{\sim}3.43\;mg/L$, $0.001{\sim}2.638\;mg/L$, and $0.010{\sim}3.181\;mg/L$, respectively. The COD and DIN in each survey showed the highest concentration at the mouth of Mangyeong river estuary(St. 1) where freshwater flow into the Saemangeum area. The concentrations of nutrients were high in the inner part of the Saemangeum dike with low-salinity, and low nutrients in the outer part of the dike with high-salinity, which strongly indicated that concentrations were adjusted by physical mixing. The ranges of dissolved metals and acid-soluble Hg in surface seawater were $0.006{\sim}0.115{\mu}g/L$ for Co, $0.26{\sim}0.114{\mu}g/L$ for Ni, $0.14{\sim}0.93{\mu}g/L$ for Cu, $0.04{\sim}0.53{\mu}g/L$ for Zn, $0.010{\sim}0.043{\mu}g/L$ for Cd, $0.010{\sim}0.795{\mu}g/L$ for Pb, and $0.25{\sim}4.16{\mu}g/L$ for Hg. The highest concentrations of some metals except for Cd were found at the estuary(Sts. 1 or 3). In most cases, a decreasing order of metal concentrations towards open sea(low-salinity$\rightarrow$high-salinity) was observed and showed positive relationship with DIN and silicate caused by land base pollutants input. On the other hand, due to Cd desorption from suspended solids in saline water, dissolved Cd concentrations were high in high-salinity area and low in low-salinity. In November, Co, Zn, Cu and Pb were relatively high in the northern area of the outer-side of Saemangeum, which was only influenced by the Geum river discharge. The concentrations of most dissolved metals of this study were lower than those of the past data in this area, but higher than those in Lena river estuary under the pristine environment.

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[Kimchi Pill] Preparation of a Kimchi Pill Using Cyclodextrin ([김치환] Cyclodextrin을 이용한 김치환의 제조)

  • Ann Yong-Geun;Lee Kyung-Haeng
    • The Korean Journal of Food And Nutrition
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    • v.18 no.3
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    • pp.207-218
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    • 2005
  • In room temperature, Kimchi becomes acidified and a little decayed, scenting a bad smell, and It couldn't be well kept. But if it should be made into a pill, it could be preserved for a long time for marketing, with nutrition highly concentrated as well as with no scent. Therefore, making Kimchi into a pill needs drying. When dried Kimchi, lactic acid and fragrant ingredient will vanish along with volatilization. The cyclodextrin(CD) as a stabilizer shows that the protecting rate of volatility of lactic acid in Kimchi is higher before than that of after fermentation, and it is higher at the addition $2\%\;than\;of\;1\%$ in case of Kimchi with CD. But it doesn't give much effect on total sugar, reducing sugar, protein and amino acid. Evaporation rate of lactic acid is the least in freeze dry, and natural dry, heat dry come next, respectively. In heat dry, if dried at more than $60^{\circ}C$ for a long time, Kimchi exudes boiling and scorched scent, causing bitter taste. The result of HPLC with superose 12 column at 280nm and 210nm shows that place and amount of main peak is almost the same, but the distribution of other peaks are different, with the revelation of various peaks like peptide and amino acid. The Kimchi pill made by the addition of $1\%$ CD shows that concentration is eight times higher than general Kimchi, total sugar is $14.4\%$, reducing sugar is $8.8\%$, protein is $4.8\%$, amino acid is $2.4\%$, and other contents are $74.4\%$, acidity is 32.8, and pH is 3.5 each. The result of letting 20 people with obesity, 20 patients with constipation have 30 pills(total weight 30g) three times a day for 60 days reveals they lost $2.29\%$ in weight on the average, and 7 among 20 were all relieved in constipation, and 8 responded that they experienced its efficacy.

Wet Deposition of Heavy Metals during Farming Season in Taean, Korea (태안지역 강우의 중금속 함량 평가)

  • Jung, Goo-Bok;Kim, Min-Kyeong;Lee, Jong-Sik;Kim, Won-Il;Kim, Gun-Yeob;Ko, Byong-Gu;Kang, Kee-Kyung;Kwon, Soon-Ik
    • Korean Journal of Environmental Agriculture
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    • v.30 no.2
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    • pp.153-159
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    • 2011
  • BACKGROUND: This experiment was conducted to investigate the distribution and burden characteristics of heavy metal in the rainwater sampled at Taean area, in the middle part of Korea, from April 2002 to October 2003. METHODS AND RESULTS: The relationship between concentration of heavy metal and other chemical properties in the rainwaters was also evaluated. Chemical properties in the rainwater were various differences with raining periods and years. It appeared that a weighted average pH values of rainwater was ranged from 5.0 to 5.1. Heavy metal concentrations in the rainwater were ranked as Pb > Zn > Cu > Ni > As > Cr > Cd. As compared with heavy metal concentrations of rainwater in 2002, Cu, Pb, and Zn were higher than other elements in 2003. There were positive correlation between major ionic components, such as ${NH_4}^+$, $Ca^{2+}$, $Mg^{2+}$, $K^+$, $Na^+$, ${SO_4}^{2-}$ and ${NO_3}^-$, and As, Cd, Zn, Cr, and Ni concentrations in rainwater. For heavy metal distribution of rainwater, the order of average enrichment factor was Cd > Pb > As > Cu > Zn > Ni > Cr, and these were relatively higher than the natural components such as Fe, Mg and Ca. The monthly enrichment factor were relatively high, from August to October at Taean. The monthly amount of heavy metal precipitation was high in the rainy season from July to August because of great influence of rainfall. CONCLUSION(s): The results of this study suggest that the heavy metals(Cd, Pb, As, Cu, and Zn) of rainwater is strongly influenced by anthropogenic sources rather than natural sources.

Application of the Artificial Mussel for Monitoring Heavy Metal Levels in Seawater of the Coastal Environments, Korea (Artificial mussel을 이용한 우리나라 연안환경의 중금속 오염도 연구)

  • Ra, Kongtae;Kim, Joung-Keun;Kim, Kyung-Tae;Lee, Seung-Yong;Kim, Eun-Soo;Lee, Jung-Moo;Wu, Rudolf S.S.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.2
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    • pp.131-145
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    • 2014
  • The new passive sampler called "artificial mussel (AM)" offers a potential device to study the spatiotemporal changes of metal concentrations in different marine environment worldwide. The purpose of this study is to characterize metal (Cd, Cr, Cu, Zn, Pb) accumulation on the AM and transplanted mussel (Mytilus edulis) at 5 sites of Lake Shihwa. Both the AMs and mussels showed increasing concentrations of all five metals during the 12 weeks exposure period. Higher concentrations of Zn were showed in both the AMs and Mytilus edulis relative to other metals. The AMs accumulated higher concentrations of Cd, Cr and Zn, but they presented lower levels of Cu and Pb than Mytilus edulis. The correlations for Cd, Cu and Pb were statistically significant between the AMs and Mytilus edulis, indicating that the accumulation patterns for those metals were similar. However, no similarities for Cr and Zn were observed between two monitoring devices across all of the sites in Shihwa Lake. According to relationship for metal concentrations between dissolve phase in seawater and both the AMs and Mytilus edulis, the AMs for Cd, Cu and Zn represent more metal contamination than Mytilus edulis. Our results indicated that the AMs give a better resolution to reveal the spatial differences in dissolved metal concentration. This study suggests that the AMs can provide a time-integrated estimate of metal pollution in marine environments as well as freshwater environments of Korea.

Behavior of Some Metallic Ions in the Process of Ginseng Extracts Preparation (인삼(人蔘) Extract 제조과정(製造過程)중 무기금속(無機金屬)이온의 동태(動態))

  • Cho, Yung-Hyun;Lee, Joung-Sook
    • Korean Journal of Food Science and Technology
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    • v.15 no.2
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    • pp.133-134
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    • 1983
  • Some metallic ions such as copper, manganese, iron, zinc and cadmium in ginseng extract, originated from white ginseng, were determined by atomic absorption spectrophotometry. The extracts were prepared with water, 35% ethanol, 50% ethanol or 75% ethanol solution followed by filtration or centrifugation. Greater amounts of metallic ions were found in the solution filtrated by filter paper (Toyo No. 5A) or by filter cloth than in that of centrifugation. The residual amount of metallic ions in the extract decreased with increasing concentration of ethanol. The percentages of each metallic ion in ginseng extracts on the basis of original amount of metallic ions were as follows: Cu, 10.4-31.9%, Fe,5.1-19.0%, Mn,3.0-12.2% Zn,7.4-12.0%, Cd,5.9-11.8%.

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Salt Acclimation Behavior of the Nitrifier Consortium for the Nitrification of Saline Wastewater

  • Seo, Jae-Koan;Kim, Sung-Koo
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.590-593
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    • 2001
  • The effect of salinity on the nitrification efficiency of the nitrifier consortium was evaluated for the nitrification of saline wastewater. The nitrifier consortium, which was the activated sludge acclimated with ammonium as the only energy source, was used as the nitrifier for the salt acclimation. Airlift reactors for the nitrification of ammonia with increasing concentration in saline synthetic wastewater (35 g/I NaCD, and synthetic wastewater without salt as a control, were continuously operated with the nitrifier consortium for 43 days. The ammonia removal rate was about 23g ammonia-N/$m^3$/day in both the absence and presence of the salt. An accumulation of nitrite was observed in the saline nitrification reactor at an early period. However, the nitrite decreased to less than 1 mg/l after 39 days of operation. The salinity increased the acclimation time of the nitrifier consortium to obtain a stable marine nitrification system. However, the salt acclimated system showed the efficient removal of ammonia which was same as that without salt.

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Comparision of Test Methods for Estimating Chloride Ion Diffusion Coefficient in Concrete (콘크리트중의 염소이온 확산계수 추정 실험법의 비교)

  • 문한영;김홍삼;문재흠;한아름
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.787-790
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    • 1999
  • To estimate durability of reinforced concrete structures located in or nearby seawater, many different kinds of accelerated tests for evaluation of chloride ion permeation in concrete were proposed. At present the only standardized test is the ASTM C 1202(RCP test). This test method is used to estimate the concrete's resistivity of the chloride penetration in concrete by using the total charges passed and sometimes used to calculate the chloride diffusion coefficients. However, this test may lead to an erroneous chloride diffusion coefficient. So this test method was compared with the modified Dhir's test and the traditional concentration diffusion test. Experimental results showed that the diffusion coefficients determined the RCP test and the PD Index gave wrongous values, but the diffusion coefficient acquired by considering a migration term was nearly the same to the CD Test.

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