• Corrosion Science and Technology
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• v.16 no.3
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• pp.115-127
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• 2017

Coal tar-coated pipes buried in a domestic nuclear power plant have operated under the cathodic protection. This work conducted the simulation of the coating performance of these pipes using a FEM method. The pipes, being ductile cast iron have been suffered under considerably high cathodic protection condition beyond the appropriate condition. However, cathodic potential measured at the site revealed non-protected status. Converting from 3D CAD data of the power plant to appropriate type for a FEM simulation was conducted and cathodic potential under the applied voltage and current was calculated using primary and secondary current distribution and physical conditions. FEM simulation for coal tar-coated pipe without defects revealed over-protection condition if the pipes were well-coated. However, the simulation for coal tar-coated pipes with many defects predict that the coated pipes may be severely degraded. Therefore, for high risk pipes, direct examination and repair or renewal of pipes are strongly recommended.

• Journal of Welding and Joining
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• v.19 no.2
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• pp.182-190
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• 2001

A marine structural material was well known to have high tensile strength, good weldability and proper corrosion resistance. Cu-containing high strength low alloy(HSLA) steel was recently developed for their purposes mentioned above. And the steel is free about preheating for welding, therefore it is reported that shipbuilding cost by using it can be saved more or less. However the marine structural materials like Cu-containing HSLA steel are being generally adopted with cathodic protection method in severe corrosive environment like natural sea water but the high strength steel may give rise to Hydrogen Embrittlement due to over protection at high cathodic current density for cathodic protection. In this study Cu-containing HSLA steel using well for marine atructure was investigated about the susceptibility of Hydrogen Embrittlement as functions of tensile strength, strain ratio, fracture time, and fracture mode, etc. and an optimum cathodic protection potential by slow strain rate test(SSRT) method as well as corrosion properties in natural sea water. And its corrosion resistance was superior to SS400 steel, but Hydrogen Embrittlement susceptibility of Cu-containing HSLA steel was higer than that of SS400 steel. However Hydrogen Embrittlement of its steel by SSRT method was showed with pheonomena such as decreasing of fracture time, strain ratio and fracture mode of QC(quasi-cleavage). Eventually it is suggested that an optimum cathodic protection potential not presenting Hydrogen Embrittlement of Cu-containing of HSLA steel by SSRT method was from-770mv(SCE) to - 900mV(SCE)under natural sea water.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.2
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• pp.492-501
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• 1990

It was known that the fracture incidences of offshore structure were mostly originated from the surface defects. Especially, in the case of the welded structures, since the welded region has some defects and incomplete beads which are apt to behave like the surface cracks, it has been necessary to evaluate the environmental effects on crack growth at HAZ for the design crack growth behaviour at multi-pall HAZ for SWS41 steel under free corrosion and cathodic protection(-0.9V vs Ag/Agcl) conditions. The results are summarized as follows ; (1) Crack growth rate of the as weld in air was faster than that of the parent and PWHT specimens over all .DELTA.K rang. (2) In free corrosion test, surface crack growth rate of the as welded was decreased in comparison with that of the parents. (3) In fatigue test under cathodic protection, cathodic electric potential(-0.9V vs Ag/Agcl) for the SWS41 steel parent was effective, while for the as welded ineffective. (4) There was a tendency that the exponent(m) of the Paris' equation was decreased in order of microhardness magnititude in air and under cathodic protection conditions and vise versa in free corrosion. (5) Fracture surface has dimples and ductile striations in air test, but transgranular cracks and brittle striations under cathodic protection test.

• Journal of the Korea Institute of Building Construction
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• v.10 no.5
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• pp.21-29
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• 2010

Cathodic Protection has been introduced as a method of protecting metals under the ground or sea from corrosion. Since 1970, it has been applied to reinforced concrete structures as a corrosion protection method. After 1990, it became used around the world, and its usability has been well confirmed. But this method has some problems in terms of construction and economy. To solve these problems, a Cathodic Protection Method using a highly-durable metal spray was developed. First, the specimen was covered with anodic materials (Zn, Al) by using metal spray. The corrosion protection performance was confirmed by measuring the corrosion current of the specimen. Through the experiment, it is possible to confirm that the Cathodic Protection Method using a high metal spray provides effective protection against corrosion to reinforced concrete structures.

• Journal of Korea Ship Safrty Technology Authority
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• s.22
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• pp.34-53
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• 2007

In the case of hull material. large sized merchant ships are made of steel, on the other hand FRP or wood are used for small sized fishing boats. At present in Korea approximately 88,500 fishing boats are in operation of which 70% are made of FRP In the meantime, stainless steel is frequently used as shaft materials of the small-size FRP fishing boat. Namely, the kinds of shaft materials are STS 304(18Cr-8Ni), STS 316(18Cr-12Ni-2.5Mo steel) and STS 630(17Cr-Ni-Nb steel)etc. Among these things, STS 304 which is the cheapest and having ordinary corrosion resistance is most widely used as 2nd class shaft material. But, using STS 304 for shaft system material of the small-size FRP fishing boat on seawater environments entails a severe corrosion which causes shaft system troubles. Particularly, the corrosions tend to be concentrated of the stern and bow side, propeller shaft surface of inside of stern tube and the boat having no stern cooling pipe line system. As a solution for those problems, research on the ways to mitigate corrosion on the part of 2nd class stainless steel shaft have been undertaken. In the result, not only clarification for the reason of corrosion of the part of stainless steel shaft used mainly for the small-size FRP fishing boat was done, but also most optimal corrosion protection system was developed by experimenting shaft's protection simulation based of the electrochemical cathodic protection principle. In addition, verification through the field test on the optimal cathodic corrosion protection method by means of aluminum sacrificial anode was carried out. In this study, effective and economical shaft's protection system is suggested to the small-size FRP fishing boat operator by substantiating the results obtained from the research on the optimal cathodic protection.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.87-92
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• 2001

Reinforced concrete have defect in durability due to carbonation, freezing and thawing, and penetration of chloride ions with time in spite of superb structure. Especially steel corrosion in concrete due to penetration of chloride ions have result in a marked decline in service life. The principal purpose in this study is to see effect of sacrificial anode cathodic system, one of the electrochemical methods in order to the control of steel corrosion in concrete. There are chloride content in concrete in cracked and no cracked specimen with cathodic protection. To recognize the effect of sacrificial anode cathodic protection, Instant-off potential are measured. We have the excellent effect for control steel corrosion adaption sacrificial anode cathodic system.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.1207-1212
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• 2001

Reinforced concrete has defects in durability due to carbonation, freezing and thawing, and penetration of chloride ions with elapse of time in spite of super structure. Especially steel corrosion in concrete due to penetration of chloride ions has result in a severe decline in service life. The principal purpose of this study is to estimate effects of sacrificial anode cathodic system, one of the electrochemical methods in order to control of steel corrosion in concrete. There are chloride content in concrete in cracked and non cracked specimen with cathodic protection. To investigate the effect of sacrificial anode cathodic protection, potential-decay with current density, corrosion ratio, etc. are measured. We have the excellent effect for control steel corrosion adaption sacrificial anode cathodic system.

• Corrosion Science and Technology
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• v.2 no.4
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• pp.202-206
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• 2003

Fusion Bonded Epoxy(FBE) systems have been widely used to protect pipelines for over 30 years. Numerous attempts have so far been made to improve the properties of FBE coatings such as chemical resistance, adhesion, water resistance, cathodic disbondment resistance, impact resistance, and flexibility to protect pipelines at a wet and a high temperature condition. But these attempts have not been successful in reducing some weakness, for instance, in pipeline operating at high temperature due to poor hot water resistance and cathodic protection. The purpose here is to build a basis for getting better corrosion resistance of FBE systems. Cresol-novolac epoxy coating systems were studied compared to bisphenol A type epoxy systems. After the immersion of the film in water at a high temperature for a long period, good adhesion to metal substrate and excellent cathodic disbond resistance were observed in the cresol-novolac epoxy resin systems. It is well known that the adhesion of organic coatings to metal substrate might be decreased due to the disruption of a chemical bond across the film and metal interface induced by water molecules. A high crosslinking density might decrease water permeability and improve cathodic disbonding protection in the coatings. Other factors are studied to understand anti-corrosion mechanism of Cresol-novolac epoxy coatings. In addition, the water absorption rate and the effect of cure temperature on the adhesion and cathodic disbonding resistance ofthe films were studied in different epoxy coatings and the effect of substrate was evaluated. The results of field application are proved that the Cresol-novolac epoxy coating system developed recently is one of the most suitable coatings for protection of pipelines.

• Journal of Advanced Marine Engineering and Technology
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• v.9 no.2
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• pp.126-142
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• 1985

The plane bending corrosiion fatigue test for the welded metal parats was performed in the air and in the natural sea water with and without applying cathodic protection. The specimens tested were the weld of SM41 steel plates, SM58 steel plates and of SM41 to SM58, which were all prepared by submerged arc welding. The main results obtained from the experiment are summarized as follows: (1) In case with SM41 and SM58 steel plates, lower value of impact strength, higher value of hardness and more noble electrode potential were observed in the welded metal part than in the HAZ and base metal. Also the lowest hardness zone in the HAZ was observed with SM58 which was not found with SM41. In case with weld specimen of SM41 to SM58, the impact strength and the electrode potential of the welded metal part showed again the lowest and most noble value but the hardness value was located between those of SM41 and SM58 base metal. (2) In the fatigue test, the specimens tested in the air and under the cathodic protection were both cracked in a purely mechanical mode, but the specimens tested without cathodic protection were cracked by the combination of mechanical fracture and electro-chemical corrosion. (3) The corrosion fatigue limit of the welded metal parts of the specimen was increased by the cathodic protection. As the protection potential was varied down to -800 mV vs. SCE the fatigue limit was increased to the value tested in the air, and the maximum fatigue limit appeared at the -1, 000 - -1, 200 mV vs. SCE. However, as the protection potential was further decreased below -1, 200 mV vs.SCE, the fatigue limit of weld of SM58 and of SM41-SM58 joining was decreased but the limit was almost constant in the case of weld of SM41. (4) It is suggested that when designing steel ship the corrosion fatigue limit of welded metal parts should be stressed as a designing strength of the structure of steel ship in addition to the conventional basis considering simply tensile strength of steel and safety factor.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10a
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• pp.503-507
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• 2000

The corrosion protection methods of reinforcing steel in concrete are the various methods such as increasing thickness of cover concrete, using of reinforcing bars coated with epoxy, dosage of corrosion inhibitor as concrete admixture, cathodic protection method and etc. In this study, the performance of corrosion protection was investigated for the test specimens using corrosion inhibitors and cathodic protection, respectively. For this purpose, the accelerated corrosion tests for reinforcing steel were conducted according to the periodic cycles(140 days) of wetting($65^{\circ}C$, 90% R.H) and drying period($15^{\circ}C$, 65% R.H) for the test specimens. As a result, it can be concluded from the test that the effect of corrosion inhibitor was found to be variable with products, the cathodic protection method was found to be independent of salt concentration in concrete.