• 한국수소및신에너지학회논문집
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• 제25권4호
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• pp.355-363
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• 2014

Thermal shock or overheating of WGS catalyst for SEWGS system during hydrogen pre-treatment can cause reactivity decay of the catalyst. To select appropriate pre-treatment condition, temperature profiles of catalyst bed (or outside fluidized particle bed of bed insert) during pre-treatment were measured and then CO conversions of those catalysts during WGS reaction were also measured and compared. Drastic overheating of catalyst took place when we reduce catalyst at fixed bed condition and these catalysts showed low CO conversion during WGS reaction. On the contrary, there was no overheating of catalyst at fluidized bed condition not only physical mixing case but also bed insert case. Spring type bed insert showed acceptable CO conversion even at low WGS content. Consequently, feasibility of high CO conversion without decay of reactivity of catalyst and holding the WGS catalyst inside the SEWGS reactor as tablet shape were confirmed using spring type bed insert.

• 한국수소및신에너지학회논문집
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• 제24권6호
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• pp.535-542
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• 2013

To enhance the performance of SEWGS system by holding the WGS catalyst in a SEWGS reactor using bed inserts, effect of bed insert geometry on CO conversion of WGS catalyst was measured and investigated. Small scale fluidized bed reactor was used as experimental apparatus and tablet shaped WGS catalyst and sand particle were used as bed materials. The cylinder type and the spring type bed inserts were used to hold the WGS catalysts. The CO conversion of WGS catalyst with the change of steam/CO ratio was determined based on the exit gas analysis. Moreover, gas flow direction was confirmed by bed pressure drop measurement for each case. The measured CO conversion using the bed inserts showed high value comparable to previous results even though at low catalyst content. Most of input gas flowed through the bed center side when we charged tablet type catalyst into the cylinder type bed insert and this can cause low $CO_2$ capture efficiency because the possibility of contact between input gas and $CO_2$ absorbent is low in this case. However, the spring type bed insert showed good reactivity and good distribution of gas, and therefore, the spring type bed insert was selected as the best bed insert for SEWGS process.

• 한국항공우주학회지
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• 제34권9호
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• pp.89-96
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• 2006

본 연구에서는 소형 위성용 하이브리드 로켓 점화장치에 적용되는 N2O 촉매 베드의 유동 및 열적 현상에 대한 이론적인 고찰을 하였다. 허니콤 형상을 가지는 촉매 베드 내의 열적 현상을 분석하기 위해서 다공성 매질 접근법을 사용하였다. 유동장은 Brinkman- extended Darcy 모델을 사용하였고, 온도장은 One-equation 모델을 사용하여 촉매 베드 내에서 유동장 및 온도장에 대한 해석해들을 구하였다. 다공성 매질 접근법을 적용한 모델의 해석해와 기존 실험결과를 비교하여 본 모델의 정확성을 검증하였다. 해석해에 근거하여 N2O 촉매 베드에 영향을 미치는 중요한 변수들이 촉매 베드의 기공률, 유효 체적비, 촉매 베드와 기공의 직경비, 공급열, 그리고 펌핑파워임을 확인하였으며 촉매 베드 내에서의 열적현상에 대한 중요 변수들의 효과를 연구하였다.

• 대한화학회지
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• 제6권1호
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• pp.54-60
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• 1962

The water gas shift conversion catalyst prepared by the American Cyanamide Co. was subjected to fluidization in a 2-in. Pyrex glass tube to obtain the basic fluidization characteristic data. The size of the catalyst charged ranged from 70 to 120 meshes and it was supported on a single layer 300-mesh wire gauze through which the fluidizing medium, the air, was passed. Following are some data and facts found by the authors: (1) The catalyst particles were porous, and their surfaces were trough and irregular. (2) The average effective particle density and the average shape factor of these particles were 152.2 lb/$ft^3$ and 0.865 respectively. (3) As the particle diameter of the catalyst increased, the minimum fluid voidage of the bed decreased slightly. (4) Just before the incipient fluidization, pressure drop suddenly fell and the bed expanded simultaneously. (5) After fluidization set in, the expansion characteristics of the catalyst bed were similar to those of sand and glass beads except intense bubbling in the catalyst bed.

• 한국연소학회:학술대회논문집
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• 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
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• pp.287-298
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• 2003

A numerical investigation of a catalytically stabilized thermal (CST) combustor was conducted for a multi-channel catalyst bed, and both the catalyst bed and thermal combustor were simultaneously modeled. The numerical model handled the coupling of the surface and gas reaction in the catalyst bed as well as the gas reaction in the thermal combustor. The behavior of the catalyst bed was investigated at a variety of operating conditions, and location of the flame in the CST combustor was investigated via an analysis of the distribution of CO concentration. Through parametric analyses of the flame position, it was possible to derive a criterion to determine whether the flame is present in the catalyst bed or the thermal combustor for a given inlet condition. The results showed that the maximum inlet temperature at which the flame is located in the thermal combustor increased with increasing inlet velocity.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제37회 추계학술대회논문집
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• pp.218-222
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• 2011

이리듐 촉매의 국산화 개발과정에서 고온/고압으로 인한 촉매파손, 유실, 소결현상 등이 관찰되었고, 이렇게 손상된 촉매대로 인하여 추력기의 성능이 저하된다고 보고되었다. 이에 본 논문의 연구에서는 촉매대를 1차원 다공질성 매질로 가정, 모델링하여 수치해석코드를 개발하였다. 개발된 수치해석코드는 실험데이터와 비교하여 검증하였으며, 촉매유실에 의해 변하게 되는 촉매대의 공극률을 변화시켜 다양한 경우의 촉매유실을 가정하여 해석을 수행하였다. 이를 통하여 촉매유실이 하이드라진과 암모니아의 분해반응에 끼치는 영향을 연구하였다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
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• pp.59-67
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• 1998

The aim of this study is to investigate advantages that the catalytically supported combustor can have. For this purpose, the catalytic combustor was prepared which consisted of the catalyst bed and the thermal combustor at the downstream of the catalyst bed. The catalyst bed consisted of two-stage. Pd catalyst was installed in the first stage of the catalyst bed, and Pt catalyst was placed in the second stage. Results showed that the catalytically supported combustion had some advantages. One was that auto-ignition occurred in the thermal combustor. This can give merit that an igniter is not necessary to start flame ignition. Other was that the catalytically supported combustion was stable for lean mixture. When combustion of lean mixture was not supported by surface reaction it became unstable so that big combustion noise was created. Therefore, it is desirable to support flame by catalytic surface reaction to obtain the stable combustion of lean mixture.

• 한국수소및신에너지학회논문집
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• 제24권2호
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• pp.150-159
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• 2013

To enhance the performance of SEWGS system by holding the WGS catalyst in a SEWGS reactor using bed inserts, effects of insert geometry and shape of WGS catalysts on CO conversion were measured and investigated. Small scale fluidized bed reactor was used as experimental apparatus and WGS catalyst (particle and tablet) and sand were used as bed materials. The parallel wall type and cross type bed inserts were used to hold the WGS catalysts. The CO conversion with steam/CO ratio was determined based on the exit gas analysis. The measured CO conversion using the bed inserts showed high value comparable to physical mixing cases. Moreover, gas flow direction was confirmed by bed pressure drop measurement for each case. Most of input gas flowed through the catalyst side when we charged tablet type catalyst into the bed insert and this can cause low $CO_2$ capture efficiency because the possibility of contact between input gas and $CO_2$ absorbent is low in this case. New bed insert geometry was proposed based on the results from this study to enhance contact between input gas and WGS catalyst and $CO_2$ absorbent.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 춘계학술대회
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• pp.33-36
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• 2007

Currently, many structured catalysts using microchannel are researched to apply to fuel reforming. In this paper, ceramic monolith and metal mesh as structured catalysts are investigated for catalytic autothermal reforming. When GHSV increases, each structured catalyst has better performances(hydrogen production, fuel conversion) than packed bed catalyst for autothermal reforming. The major causes seem to be the elevated heat and mass transfer, gas phase reaction and redistribution of packed bed due to high pressure drop.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2007년도 제28회 춘계학술대회논문집
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• pp.163-167
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• 2007

은 촉매는 과산화수소 촉매분해에 많이 사용되지만, 상온에 시동이 어렵고 높은 온도에 적용하기 곤란하다. 본 논문에서는 은이 가지고 있는 단점을 극복하기 위해 기화기와 고온 촉매 베드로 구성된 이원 촉매 베드에 대한 연구를 수행하였다. 백금을 기화기 촉매로, perovskite 구조를 가지는 촉매를 고온 촉매로 선정하였고, 가스발생기를 이용한 시험을 통해 상온에서 예열이 없이도 시동이 가능함과 고온에서 안정적으로 작동함을 보여주었다.