• Journal of Environmental Science International
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• v.9 no.1
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• pp.81-88
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• 2000

Every year, 1.1 million tons of rice-hull are produced in South Korea by the by-product in pounding rice. But they has mainly been utilized as a fuel, agricultural compost and moisture proofs. So, it's very valuable to use waste rice-hull for activated carbon manufacture. SiO2 content was the highest among inorganics in rice-hull. Therefore, the SiO2 extraction experiments were carried out under the various conditions of pH 9 to 14, reaction time from 2 to 24 hrs and various temperature of 20 to 100℃. The results showed that increase in pH and temperature enhanced SiO2 extraction from the carbonized rice-hull. The surface area of the carbonized rice-hull indicating activated carbon adsorption capacity was very small as 178∼191 m2/g at first. However, it was increased to 610∼675 m2/g when extracted in alkali solution at 100℃. When the mixing rate of carbonized rice-hull and NaOH was 1:1.5, iodine No. and surface area of activated rice-hull during 10 min at 700℃ were 1,650 mg/g and 1837 m2/g, respectively. Subsequently, an activated carbon with specific surface area of 1,300∼1,900m2/g was manufactured in a short contact time of 10∼30 min with a mixing rate of 1:1.5 in carbonized rice-hull and NaOH, and iodine No. and specific surface area increased as the amount of SiO2 removal increased.

• Proceedings of the Korean Society of Organic Agriculture Conference
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• 2009.12a
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• pp.317-317
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• 2009

The effects of environment-friendly materials carbonized rice hull and wood vinegar on the improvement of rice quality and soil fertility were investigated. Combined application of carbonized rice hull and chemical fertilizer resulted in lower protein in rice, similar amylose content and generally higher palatability values. Combined application of wood vinegar and chemical fertilizer obtained high protein and amylose contents, and palatability values. However, both carbonized rice hull and wood vinegar did not exhibit weed control. In the carbonized rice hull treatments, soil K was high during heading stage while soil pH during harvest stage was low. In the case of wood vinegar treatments, clear distinction between total K and Ca was observed. K was high during tillering stage while Ca was high until harvest stage.

• Korean Journal of Soil Science and Fertilizer
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• v.14 no.3
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• pp.130-136
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• 1981

Rice hull was reduced to ash by carbonization grades to illcuidate alkalinity increase and extract of inorganic nutrients in the rice hull charcoal. Alkaline reaction of water extraction was neutral at less carbonized charcoal, but much carbonized ash from 65% weight loss reached over 10 of pH value, also origin shape of rice hull was maintained until near 65% carbonized grade. Therefore, physical properties sustained good condition for seedling bed. The more charcoal carbonized to ash, the pH value and concentration of inorganic nutrient in their extracts were increased gradually. Nitric acid concentrations for neutralizing extract from charcoal were stronger in proportion to the carbonized grade but 0.1 N nitric acid solution was very reasonable to neutralize the 65% carbonized charcoal for mixing with heavy texture acidy soil(pH 5.3) of uncultivated deep horizon to transplant the tobacco seedlings. Volume ratio mixing for seedling bed is adequate at five of ash to one of acid solution. Neutralization with nitric acid solution also accelerated extraction of the inorganic nutrient in rice hull ash. Tobacco seedlings grown on bed mixed with neutralized rice hull charcoal and soil had shown better results on the agronomic measurement than alkaline ash bed, and phosphorus and cations were uptaken more amounts.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.5
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• pp.340-350
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• 2015

This experiment was carried out to find out the mitigation of greenhouse gases (GHGs) emission and changes of soil carbon contents in the cropland. In order to minimize the soil disturbance, this study was conducted without crop cultivation at the pots treated with different biomass. Different biomass was buried in the soil for 12 months. Decomposition rates of expander rice hull, pig manure compost and carbonized rice hull were 18%, 11~11.5% and 0.5~1.2%, respectively. It was appeared that carbonized rice hull was slightly decomposed. No difference was shown between chemical fertilizer treatment plot and non-application plot. It was appeared that soil carbon content in the non chemical fertilizer application plot was high when compared to its chemical fertilizer. Its content at soil depth of 20 cm more decreased than the upper layer of soil. Accumulative emission of $CO_2$ with different treatments of biomass was highest of 829.0~876.6 g $CO_2m^{-2}$ in the application plot of PMC (Pig Manure Compost) regardless of chemical fertilizer treatment during 16 months of experiment. However, the emission for expander rice hull treatment plot was lowest of 672.3~808.1 g $CO_2m^{-2}$. For application plot of the carbonized rice hull, it was shown that non chemical fertilizer plot, 304.1 mg $N_2Om^{-2}$, was higher than the chemical fertilizer treatment, 271.6 mg $N_2Om^{-2}$. Greenhouse gas emissions in the PMC treatment were highest of 0.94 ton $CO_2eqha^{-1}yr^{-1}$. However, it was estimated to be the lowest in the expander rice hull treatment.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.43 no.2
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• pp.72-76
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• 2011

Antimicrobial activities of the Acidic Liquid originated from Carbonized Rice Hull(ALCRH) and the paper treated with ALCRH were investigated to apply ALCRH to functional paper products as a natural antimicrobial agent. ALCRH showed antimicrobial activity for bacteria and yeast, with higher performance for bacteria than for yeast. Antimicrobial activity was not developed on paper coated with ALCRH by bar coater probably due to the evaporation of antimicrobial compounds of ALCRH from the paper surface with time. Saturation of paper with ALCRH was essential to develop antimicrobial activity on the paper. Dipping paper in ALCRH solution was recommended as one of the effective ways to make antimicrobial paper.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2011.10a
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• pp.335-343
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• 2011

We examined the effect of the acidic liquid from carbonized rice hull(ALCRH) treatments to molded fiber packages(MFP) on weight, Haugh unit, pH and microbial activity of egg to extend the shelf life in egg packaging. Higher concentration and surface spray treatment of the acidic liquid extended the shelf life of egg. ALCRH treatment to MFP improved the performance of the packaging for egg in terms of decreased weight loss and retarded microorganism growth of eggs during storage.

• Journal of Bio-Environment Control
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• v.7 no.2
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• pp.151-158
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• 1998

This study was carried out to evaluate the effect of substrates and nutrient solution supplying methods in the media culture using perlite and its mixtures with rice hull, carbonized rice hull. cocopeat on the growth and fruit qualify of hydroponically grown cucumber. Three substrates. Perlite(70%) +rice hull(30%) perlite(70%) +carbonized rice hull(30%) and perlite(70%)＋cocopeat(30%) were compared with perlite medium. Supplying methods of nutrient solution were composed of drip irrigation, modified drip irrigation(covered with cheesecloth between drip hose and substrate) and mist system Leaf area of cucumber Plants was lowest in perlite medium while it was highest in mixture of perlite and cocopeat. NAR was higher in the plot of mixture with cocopeat. and same trend was observed in LAI and CGR. T/R ratio was higher in Perlite and perlite mixture with rice hull. Fruit Yields increased in the plot of modified drip irrigation system. When perlite mixture with rice hull used as a substrate. mist system was recommended. Perlite mixture with carbonized rice hull was observed favored in conventional drip irrigation system. Marketable yield and the number of fruit per plant increased and the malformed fruit decreased in the plot of modified drip irrigation system with the mixtures of Perlite and cocopeat.

• Journal of Bio-Environment Control
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• v.4 no.2
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• pp.159-166
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• 1995

This experiment was aimed to investigate the growth and yield responses of hydroponically grown cucumber as affected by cultural containers and substrates using perlite and mixtures with perlite. Containers used in this experiment were bed and box made of styrofoam, PE film and Wagner pot and substrates used were perlite, peatmoss, rice hull and carbonized rice hull. The results obtained were as follows : Based on the growth and yield responses determined from the leaf area and total fruit weight, bed and box made of styrofoam was considered the best containers among tested for cucumber hydroponics. Recommendable substrates for hydroponically grown cucumber using perlite were evaluated in the order of perlite, perlite with rice hull and perlite with carbonized rice hull in styrofoam bed and box. Increase in marketable yield and decrease in abnormal fruits was observed in the mixed substrates with rice hull or carbonized rice hull when compared to perlite single media.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.2
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• pp.181-193
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• 2016

This experiment was conducted to evaluate the effect of carbonized rice hull (CRH) application on soil carbon storage and $N_2O$ emissions from upland soil. It was used at different rates of 0, 5, 10 and $20Mg\;ha^{-1}$. During the Chinese cabbage cultivation, several soil chemical characteristics such as soil moisture, temperature and soil carbon were observed. Also, $CO_2$ and $N_2O$ emissions were monitored. Soil organic matter contents slightly increased with carbonized rice hull applied in all the treatments. The soil carbon contents with application rate of 0, 5, 10 and $20Mg\;ha^{-1}$ were 0, 1.3, 1.2 and $2.6g\;kg^{-1}$, respectively. It was observed that soil carbon content was higher with increasing CRH application rate. Total nitrogen contents of soil applied with CRH relatively decreased with the course of time. However, $NO_3$-N contents in the soil with CRH application rate of 5, 10 and $20Mg\;ha^{-1}$ were 28.6, 25.7 and $21.5mg\;kg^{-1}$ at the end of experiment, respectively. $CO_2$ emission at the $5Mg\;ha^{-1}$ application of CRH was higher about 18.9% than non-treatment, whereas those of $10Mg\;ha^{-1}$ and $20Mg\;ha^{-1}$ treatment were lower 14.4% and 11.8% compared to non-treatment, respectively. Also, it was shown that $N_2O$ emission reduced by 19.9, 28.3 and 54.0% when CRH was applied at 5, 10 and $5Mg\;ha^{-1}$, respectively.

• Korean Journal of Environmental Agriculture
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• v.39 no.3
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• pp.171-177
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• 2020

BACKGROUND: Recently, biomass conversion from agricultural wastes to carbon-rich materials such as biochar has been recognized as a promising option to maintain or increase soil productivity, reduce nutrient losses, and mitigate greenhouse gas emissions from the agro-ecosystem. This experiment was conducted to select an optimum conditions for enhancing the NH₄-N adsorption capacity of rice hull activated biochar. METHODS AND RESULTS: For deciding the proper molarity of KOH for enhancing its porosity, biochars treated with different molarity of KOH (0, 1, 2, 4, 6, 8) were carbonized at 600℃ in the reactor. The maximum adsorption capacity was 1.464 mg g^-1, and an optimum molarity was selected to be 6 M KOH. For the effect of adsorption capacity to different carbonized temperatures, 6 M KOH-treated biochar was carbonized at 600℃ and 800℃ under the pyrolysis system. The result has shown that the maximum adsorption capacity was 1.76 mg g^-1 in the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis temperature, while its non-treated biochar was 1.17 mg g^-1. The adsorption rate in the rice hull activated biochar treated with 6 M KOH at 600℃ was increased at 62.18% compared to that of the control. Adsorption of NH₄-N in the rice hull activated biochar was well suited for the Langmuir model because it was observed that dimensionless constant (R_L) was 0.97 and 0.66 at 600℃ and 800℃ of pyrolysis temperatures, respectively. The maximum adsorption amount (q_m) and the bond strength constants (b) were 0.092 mg g^-1 and 0.001 mg L^-1, respectively, for the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis. CONCLUSION: Optimum condition of rice hull activated biochar was 6M KOH at 600℃ of pyrolysis temperature.