• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2007.05a
• /
• pp.329-329
• /
• 2007

• Journal of Environmental Health Sciences
• /
• v.33 no.5
• /
• pp.456-461
• /
• 2007

This study was carried out two point view that reuse of sludge and adsorption of benzene, toluene and o-xylene of VOCs in cast, carbonized cast and activated carbon. The cation exchange capacity of cast and carbonized cast were 59.2, 112 meq/100g, respectively. The specific surface were 560, $800m^2/g$, respectively. The average removal rates of benzene by 50g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 15.0, 41.2, 88.2, 99.4% in 60min of retention time. The average removal efficiency of toluene by 50 g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 12.5, 34.2, 88.2, 99.5% in 60 min of retention time. The average removal rates of o-xylene 50 g cast of 50% hydrous cast, anhydrous cast, carbonized cast, activated carbon were 8.8, 28.5, 84.8, 98.1% in 60min of retention time. The adsorption efficiency of test absorbent was in order of Activated Carbon > Carbonized Cast > Cast.

• Korean Chemical Engineering Research
• /
• v.43 no.1
• /
• pp.125-128
• /
• 2005

Oil formation rate, composition of crude oil and formation of side products such as ${\alpha}-methyl$ styrene, ethyl benzene, benzene, toluene, dimer and trimer on thermal degradation of polystyrene were affected by various factors. Especially, formation of organic residue formed during reaction gave an important influence on formation of oil and composition of crude oil. Also, composition of formed crude oil showed a significant difference on reaction time. These results were caused by organic residue and carbonized solid formed during continuous reaction. Increase of residue and carbonized solid gave a decrease of yield of styrene and an increase of formation of ${\alpha}-methyl$ styrene, ethyl benzene, benzene, toluene. New reaction system was proposed for continuous operation at the thermal degradation of polystyrene.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
• /
• 1989.10a
• /
• pp.65-70
• /
• 1989

This paper presents resarch results on the use of a corona detector and a pulse counter in order to diagnose for oil transformers. Using these experimental apparatus, tests were carried out on a typical transformer oil containing different carbonized paper and various moisture contents to measure the picocoulomb val-ues and pulse count. Through the result of this study it was found that the picocoulomb values and pulse count of corona were depended on the getting stained in transformer oil. The amplitude of the partial discharge amount and the number of pulse were decreased up to 70 [。c] and then was increased as the oil temperature goes up. It was concluded that the determinati-on level for diagnosis of oil transform-er was taken into account the temperatu-er of transformer oil, The use of pulse counter method, which have been taken the same property of voltage and temperature variation for the corona measurement mothod, considera-bly increase insulator avilability.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2023.11a
• /
• pp.29-30
• /
• 2023

Wood is a construction material that has the advantages of carbon dioxide storage ability, noise reflection, and eco-friendliness. In order to use wood for a long time, you must use wood-specific paint, which is called oil stain. Oil stain improves water resistance and moisture resistance, but has the disadvantage of being weak against fire. This is because the oil contained in the oil stain causes a chemical reaction, and this chemical reaction causes the oil stain to spontaneously ignite, igniting nearby combustible materials and causing frequent fires. To improve this, in this study, different flame retardants were mixed and added to oil stain to produce functional oil stain. In addition, we would like to apply it to wood to check glow time and carbonization area. As a result of the experiment, it shows the best performance when mixed at 30(15 + 15)(%) and added to oil stain. The remaining burn time is satisfied from 10% for all samples, and the carbonized area is satisfied when it is 30%.

• Fibers and Polymers
• /
• v.2 no.4
• /
• pp.178-183
• /
• 2001

A pitch precursor for a general purpose carbon fiber was prepared by condensation of pyrolized fuel oil (petroleum residual oil) with bromine under nitrogen blowing. such a condensation raised the softening point of the pitch from 4$0^{\circ}C$ to $265^{\circ}$ with a yield of 43%. The pitch precurosr showed an enhanced aromaticity and enlarged molecular size, which led to a reduction in molecular mobility and optical isotropy. The precursor was spun into fibers of $20\mu\textrm{m}$ diameter at a take-up speed of 700m/min. The fiber was stepwise stabilized in air and carbonized in Ar gas to obtain an isotropic carbon fiber. The carbon fiber exhibited tensile strengths of 500-800 ㎫though the fiber was formed via a crude method. The electric conductivity of the carbon fiber was relatively high, 2.2$\times$$10^2$S/cm, sufficient to be used as electrode materials.

• Fibers and Polymers
• /
• v.1 no.2
• /
• pp.97-102
• /
• 2000

Pitch precursors were synthesized from coal tar(CT) and pyrolysis fuel oil(PFO, petroleum residue oil) at relatively low temperature of $250^{\circ}$, in the presence of horontrifluorideidiethyletherate complex(BFDE) as a catalyst and nitrobenzene(NB) as a co-catalyst. The softening point, nitrogen content and carbon yield increased with an increase of concentration of NB. The pitch precursors with good spinnability were prepared by removing the volatile components through $N_2$ blowing. The precursor pitches were spun through a circular nozzle, stabilized at $310^{\circ}$ and finally carbonized at $1000^{\circ}$. The optically anisotropic structure formed at the absence of NB was changed into isotropic structure, showing a decrease in size of the flow domain. The hollow carbon fiber could be prepared in the process of stabilization. The results proposed that the morphology of carbon materials could be controlled by changing the concentration of catalyst and/or co-catalyst and/or stabilization condition that affect on the mobility of molecules during carbonization.

• Applied Chemistry for Engineering
• /
• v.33 no.5
• /
• pp.496-501
• /
• 2022

In this study, an anode material for lithium secondary batteries was manufactured using petroleum-based residual oil, which is a petroleum refining by-product. Among petroleum-based residual oils, pyrolysis fuel oil (PFO), fluidized catalyst cracking-decant oil (FCC-DO), and vacuum residue (VR) were used as carbon precursors. The physicochemical characteristics of petroleum-based residual oil were confirmed through Matrix-assisted laser desorption/ionization Time-of-Flight (MALDI-TOF) and elemental analysis (EA), and the structural characteristics of anode materials manufactured from residual oil were evaluated using X-ray crystallography (XRD) and Raman spectroscopic techniques. VR was found to contain a wide range of molecular weight distributions and large amounts of impurities compared to PFO and FCC-DO, and PFO and FCC-DO exhibited almost similar physicochemical characteristics. From the XRD analysis results, carbonized PFO and FCC-DO showed similar d₀₀₂ values. However, it was confirmed that FCC-DO had a more developed layered structure than PFO in Lc (Length of a and c axes in the crystal system) and La values. In addition, FCC-DO showed the best cycle characteristics in electrochemical characteristics evaluation. According to the physicochemical and electrochemical results of the petroleum-based residual oil, FCC-DO is a better carbon precursor for a lithium secondary battery than PFO and VR.

• KIEE International Transactions on Electrophysics and Applications
• /
• v.2C no.6
• /
• pp.297-303
• /
• 2002

We have developed an on-line ultrasonic detector to monitor partial discharge in an operating transformer. The ultrasonic sensor has 150[KHz] resonance frequency and contains a pre-amplifier with 60[㏈] gain. The on-line ultrasonic detector has 50~300[KHz] frequency band-pass filter to remove electrical and mechanical noises from the transformer. This detector has an ultrasonic signal discrimination algorithm which discriminates ultrasonic signals due to partial discharge in a transformer. A moving average method of ultrasonic signal number was employed to effectively monitor the increasing trend of the partial discharge. This paper describes an experience of partial discharge detection in a 154[㎸] operating transformer using an ultrasonic detector. With regards to gas analysis in oil, C2H2 gas was produced with a warning level in this transformer We detected ultrasonic signals on the transformer steel wall, and estimated the position of partial discharge. With further inspection, we found carbonized marks due to partial discharge on the supporting bolt which fastens the windings.

• Proceedings of the KIEE Conference
• /
• 1997.07d
• /
• pp.1393-1395
• /
• 1997

In order to investigate the interfacial effects on the aging of power cables, we analyzed recently failed cables using characterization techniques. In this study, some cables showed a convolution which can cause the concentration of electric field and carbonized impurities at the surface of insulation. Also there is a relation between the degree of cross- linking and volume resistivity. From the hot oil test, the sites of water tree and void coincided with each other.