• Carbon letters
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• 제15권2호
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• pp.146-150
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• 2014

In this work, activated carbon nanofiber (ACNF) electrodes with high double-layer capacitance and good rate capability were prepared from polyacrylonitrile nanofibers by optimizing the carbonization temperature prior to $H_2O$ activation. The morphology of the ACNFs was observed by scanning electron microscopy. The elemental composition was determined by analysis of X-ray photoelectron spectroscopy. $N_2$-adsorption-isotherm characteristics at 77 K were confirmed by Brunauer-Emmett-Teller and Dubinin-Radushkevich equations. ACNFs processed at different carbonization temperatures were applied as electrodes for electrical double-layer capacitors. The experimental results showed that the surface morphology of the CNFs was not significantly changed after the carbonization process, although their diameters gradually decreased with increasing carbonization temperature. It was found that the carbon content in the CNFs could easily be tailored by controlling the carbonization temperature. The specific capacitance of the prepared ACNFs was enhanced by increasing the carbonization temperature.

• Journal of Forest and Environmental Science
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• 제28권4호
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• pp.263-267
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• 2012

Characteristics of charcoals manufactured in each temperature as 400, 600 800, 1,000 and $1,200^{\circ}C$ were examined. Sapwood and heartwood of Quercus variabilis that one of major species in charcoal materials were used for this experiment. Charcoal density was decreased highly 38-60% compared with wood density and density of sapwood was slightly decreased but heartwood was not changed with increasing carbonization temperature increase. Weight loss of sapwood and heartwood charcoal increased as carbonization temperature increases, and there is no difference between sapwood and heartwood charcoal. Refining degree of sapwood and heartwood charcoal was zero in charring over $800^{\circ}C$. Moisture and ash of sapwood and heartwood charcoal in each carbonization temperature were not differed between sapwood and heartwood. Volatile of sapwood charcoal was slightly higher than that of heartwood, and decreased as carbonization temperature increases. As the carbonization temperature increased, fixed carbon of sapwood and heartwood charcoal increased. Calorific values of charcoal prepared at $600^{\circ}C$ were 7,200-7,300 cal/g and then decreased slightly as carbonization temperature increased.

• 한국환경과학회지
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• 제9권4호
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• pp.345-349
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• 2000

Activated carbons were prepared from Korean coal by steam activation in this study. The variation of pore structure of the activated carbons were investigated according to different carbonization temperatures. Yield, surface area, pore volume and pore structure of this activated carbon were compared with those of activated carbon prepared without carbonization. The investigated carbonization temperature ranged from 700${\circ}C$ to 1,000${\circ}C$. Carbonization was carried out in nitrogen atmosphere for 70 minutes and activation was performed by steam at 950${\circ}C$ for 210 minutes. Surface area and pore volume of the resulting activated carbons increased with carbonization temperature. Also pore volume increased by 20% compared to the activated carbon without carbonization. Especially, in mesopore region, the activated carbon carbonized at 900${\circ}C$ had more pores by 60% than that of activated carbon carbonized at other temperature.

• 한국연초학회지
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• 제23권1호
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• pp.19-30
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• 2001

This study was carried out to investigate the influences of environmental condition in storage room, moisture content and packing weight of leaf on the carbonization of processed flue-cured leaf tobacco, and find out a regression model able to pre-estimate the degree of carbonization. The influence of temperature and humidity in storage room on the carbonization was high,, while that of packing weight was relatively low, However, high moisture content and packing weight of leaf accelerated the carbonization under the high temperature and humidity condition. Thus the leaf tobacco under the condition of 4$0^{\circ}C$, 7$0^{\circ}C$ R.H. in storage room, 16% moisture content and 286 kg/box of packing weight could be carbonized within one month. The pH, total sugar content, lightness(L) and yellowness(b) of leaf were closely related to carbonization of leaf during storage. There were significant regression and yellowness of leaf. It is considered that the certification and/or pre-estimation of carbonization during storage may be possible by applying the regression equation.

• 한국연소학회지
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• 제15권1호
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• pp.30-37
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• 2010

Carbonization characteristics of Indonesian bamboos were investigated using lab-scale tube furnace, in order to find optimum design temperature of a carbonizer for producing bamboo charcoal and vinegar. The bamboo samples used in this study are local bamboos from Damyang in Korea, Andong and Petung in Indonesia. Correlation of electric resistance, specific surface area and pH of bamboo vinegar with pyrolysis temperature has been investigated. Electric resistance of the charcoal increased for higher pyrolysis temperature the specific surface area was also increased as carbonization temperature got higher. Charcoal which has specific surface area of over $300\;m^2/g$ could be produced at $700^{\circ}C$. pH of bamboo vinegar was decreased for highter carbonization temperature and vinegar under pH 3 could be produced for all bamboo samples. In this experimental condition, it was found that lower carbonization temperature is better for producing bamboo vinegar of high quality, while higher temperature is better for obtaining bamboo charcoal with larger surface.

• Carbon letters
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• 제15권3호
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• pp.210-213
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• 2014

Nitrogen-doped microporous carbons were prepared using a polyvinylidene fluoride/melamine mixture. The electrochemical performance of the nitrogen-doped microporous carbons after being subjected to different carbonization conditions was investigated. The nitrogen to carbon ratio and specific surface area decreased with an increase in the carbonization temperature. However, the maximum specific capacitance of 208 F/g was obtained at a carbonization temperature of $800^{\circ}C$ because it produced the highest microporosity.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.442-443
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• 2006

Vacuum carbonization of nanometer tungsten powder was investigated in a simple designed apparatus. An X-Y recorder was used to plot differential thermal analysis (DTA) curves to determine starting temperature of carbonization of four samples with different specific surface area. The product was detected by X-ray Diffraction (XRD) and small angle X-ray scattering (SAXS). The results show that finer tungsten powder has lower starting temperature of carbonization. Tungsten powder, which BET surface area is $32.97m^2/g$, is completely carbonized to tungsten carbide at $1050^{\circ}C$, although the starting temperature is $865^{\circ}C$. Particle grows sharply before carbonization.

• 자원리싸이클링
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• 제26권2호
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• pp.25-32
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• 2017

돈분 자체의 저위 발열량은 859~1,075 kcal/kg로 낮게 나타나 열처리 중 한 공정인 탄화공정에 의한 연료의 개질이 필요하다. 돈분의 탄화 공정에서 가장 중요한 인자는 탄화 온도이며 본 연구에서는 탄화온도에 대한 적정 범위의 평가가 돈분의 열적 특성과 돈분의 탄화 반응속도를 통하여 이루어졌다. 열적 특성 분석 결과, 적정 탄화 온도는 높은 수율과 흡열 반응이 일어나는 $240{\sim}320^{\circ}C$로 평가되었다. 돈분 탄화공정에서의 반응속도는 1차 반응식과 Arrhenius 식을 통하여 나타내었으며, 빈도인자(lnA)는 3.05~13.08, 활성화 에너지는 6.94~18.05 kcal/mol로 평가되었다. 돈분 탄화 공정의 높은 효율과 돈분 내부로의 충분한 열전달을 위하여 최적 탄화 시간을 5~20 min로 설정하였을 때, 적정 탄화 온도의 범위는 $260{\sim}300^{\circ}C$로 나타났다.

• 한국해양환경ㆍ에너지학회지
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• 제17권4호
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• pp.268-273
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• 2014

어판장에서 발생되는 생선 손질 폐기물의 자원화를 목적으로 탄화실험을 실시하였다. 어류폐기물의 원소조성을 살펴본 결과 탄소함량과 수소함량이 각각 51.1%와 7.6%, 산소함량이 30.5%로 나타났다. 특히 질소와 황의 함량이 각각 9.8%와 1.0%로 높아 악취문제 등이 심각할 수 있다는 것을 알 수 있었다. 어류폐기물의 원소조성을 다른 폐기물과 비교해볼 때 탄소 및 수소의 함량이 상당히 높은 것으로 나타나 생선폐기물의 최종처리는 열적처리가 적합한 것으로 나타났다. 고등어, 갈치, 조기를 대상으로 내장이나 몸통, 개별 생선이나 이들을 혼합한 시료 모두에 대하여 탄화실험을 실시한 결과 탄화되는 패턴은 시료 종류에 관계없이 유사한 경향을 나타내었다. 탄화시간에 따른 수율변화는 탄화시간 5분, 10분일 때 탄화온도 변화에 따른 수율 변화가 크게 나타났고, 탄화시간 15분 이후에는 탄화온도 변화에 따른 수율 변화가 미미한 것으로 나타났다. 또한 탄화시간 30분 이상부터는 각 온도별로 시간변화에 따른 수율 변화가 미미한 것으로 나타나 탄화시간에 따른 수율변화는 30분 이상부터는 큰 영향을 미치지 않는 것으로 나타났다. 탄화온도에 따른 차이는 탄화온도 $400^{\circ}C$에서는 1차 휘발이 미미하여 2차 휘발이 일어난 $500^{\circ}C$와의 수율차가 크게 나타났다. 또한 탄화온도를 $600^{\circ}C$, $700^{\circ}C$로 하여 10분 이상 탄화시킨 결과 수율차는 미미한 것으로 나타났다.

• Bulletin of the Korean Chemical Society
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• 제33권11호
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• pp.3749-3754
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• 2012

Nanoporous carbons with a high specific surface area were prepared directly from thermoplastic acrylic resin as carbon precursor and MgO powder as template by carbonization over the temperature range, $500-1000^{\circ}C$. The effect of the carbonization temperature on the pore structure and $CO_2$ adsorption capacity of the obtained porous carbon was examined. The textural properties and morphology of the porous carbon materials were analyzed by $N_2/-196^{\circ}C$ and $CO_2/0^{\circ}C$ adsorption/desorption isotherms, SEM and TEM. The $CO_2$ adsorption capacity of the prepared porous carbon was measured at $25^{\circ}C$ and 1 bar and 30 bar. The specific surface area increased from 237 to $1251m^2/g$, and the total pore volumes increased from 0.242 to $0.763cm^3/g$ with increasing the carbonization temperature. The carbonization temperature acts mainly by generating large narrow micropores and mesopores with an average pore size dependent on the level of carbonization of the MgO-templated nanoporous carbons. The results showed that the MgO-templated nanoporous carbons at $900^{\circ}C$ exhibited the best $CO_2$ adsorption value of 194 mg/g at 1 bar.