• Title/Summary/Keyword: Carbon-Neutral Society

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Adsorption of Pb(II) Ions from Aqueous Solution Using Activated Carbon Prepared from Areca Catechu Shell: Kinetic, Isotherm and Thermodynamic Studies

  • Muslim, A.;Aprilia, S.;Suha, T.A.;Fitri, Z.
    • Journal of the Korean Chemical Society
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    • v.61 no.3
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    • pp.89-96
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    • 2017
  • This study proposed adsorption of Pb(II) ions from aqueous solution using activated carbon prepared from areca catechu shell (ACS AC) using Timphan Method. The effects of independent variables on adsorption kinetic and isotherm have been investigated by conducting experiments in batch mode at neutral pH. The structural characterization of adsorbent was done by FT-IR and SEM analysis. The Pb(II) adsorption was correlated very well with the pseudo second-order kinetic (PSOKM) and Langmuir isotherm models (LIM). Increasing NaOH mass for activation and adsorption temperature increased weakly all the parameters of adsorption kinetic and isotherm. The Pb(II) ions adsorption capacity of the ACS AC at 27 and $45^{\circ}C$ was 50.51 and 55.25 mg/g, respectively. Thermodynamic parameters were determined, and the results confirmed the Pb(II) ions adsorption should be endothermic and spontaneous process, and both physical and chemical adsorption should be taken place.

Removal of Tar from Biomass Gasification Process (Biomass Gasification 공정에서 발생하는 Tar 제거연구)

  • Kim, Ju-Hoe;Jo, Young-Min;Kim, Jong-Su;Kim, Sang-Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.8
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    • pp.552-561
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    • 2018
  • Biomass, a carbon-neutral resource, is an alternative energy source for exhaustion of fossil fuel and environmental problems. Most of energy production systems using biomass operate with a thermal chemical conversion method. Amongst them, gasification generates syngas and applies to boilers or engines for the production of heat and electricity. However, Tar could be formed during the production of syngas and it is condensed at low temperature which may cause to clog the pipelines and combustion chamber, ultimately resulting in decrease of process efficiency. Thus this work utilized water and oily materials such as soybean oil, waste cooking oil and mineral oil for scrubbing liquid. The removal efficiency of Tar appeared 97%, 70%, 63% and 30% for soybean oil, waste cooking oil, mineral oil and water respectively.

Toxicity Assessment of Gas Phase in Cigarette Smoke Using Cell-free Assay

  • Park, Chul-Hoon;Sahn, Hyung-Ok;Shin, Han-Jae;Lee, Hyeong-Seok;Min, Yaung-Keun;Hyun, Hak-Chul
    • Journal of the Korean Society of Tobacco Science
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    • v.29 no.2
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    • pp.110-117
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    • 2007
  • In vitro toxicity tests such as cytotoxicity, mutagenicity and genotoxicity assay are useful for evaluating the relative toxicity of smoke or smoke condensates obtained from different cigarette configurations. A major disadvantage of these tests is relatively time-consuming, complicated and expensive. Recently, a cell-free glutathione consumption assay (GCA) as a rapid and simple screening method for the toxicity assessment of smoke has been reported by Cahours et al. (CORESTA, 2006). This study was carried out to assess the GCA application capable of predicting the toxicity of gas/vapor phase (GVP) of cigarette smoke and to identify individual compounds responsible for the glutathione (GSH) consumption in smoke. Each GVPs from 2R4F, standard cigarette, carbon filter cigarette (ExC) and new carbon filter cigarette (ExN), test cigarettes were collected by automatic smoking machine and evaluated the relative toxicity by GCA and neutral red uptake (NRU) assay. Toxic compounds existed in smoke were also chosen, relative toxicities of these compounds were screened by using two methods and compared individually. The overall order of toxicity by GCA was 2R4F > ExC > ExN, which was consistent with the result of Neutral Red Uptake assay. The levels of carbonyl compounds of ExN were lower than those of 2R4F and ExC, indicating that GSH consumption was associated with carbonyl compound yields. A major toxicant under current study is acrolein, which contributed to more than half of the GSH consumption. Collectively, the toxicity of GVP determined by GCA method may be mainly attributed to acrolein.

Kinetic Studies on the Nucleophilic Addition of Cysteine and Thioglycolic Acid to ${\beta},\;{\beta}$-Dichlorostyrene Derivatives (${\beta},\;{\beta}$-Dichlorostyrene 유도체의 Cysteine 및 Thioglycolic Acid에 대한 친핵성 첨가반응의 반응속도론적 연구)

  • Tae-Rin Kim;Jong-Yol Ryu;Duk-Chan Ha
    • Journal of the Korean Chemical Society
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    • v.32 no.3
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    • pp.260-266
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    • 1988
  • The rate constants for the nucleophilic addition reactions of thioglycolic acid and cysteine to ${\beta},\;{\beta}$-dichlorostyrene derivatives(p-H, p-Cl, $p-CH_3,\;and\;p-OCH_3$) were photochemically determined at various pH and a rate equation which can be applied over a wide pH range was obtained. On the bases of rate equation, general base catalysis and substituent effect, the plausible addition reaction mechanism was proposed: Above pH 9.0, the reaction was initiated by the addition of sulfide anion, and in the range of pH 7.0 to 9.0, the neutral molecules and it's anions attacked to the double bond, competitively. However, below pH 7.0, only the neutral molecules of thioglycolic acid or cysteine added to the carbon-carbon double bond.

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Calculation of Required Coolant Flow Rate for Photovoltaic-thermal Module Using Standard Meteorological Data and Thermal Analysis (표준기상 데이터와 열해석을 이용한 태양광열 모듈의 필요 냉각수량 산출)

  • Lee, Cheonkyu;Jeong, Hyo Jae
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.4
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    • pp.18-22
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    • 2022
  • Photovoltaics (PV) power generation efficiency is affected by meteorological factors such as temperature and wind speed. In general, it is known that the power generation amount decreases because photovoltaics panel temperature rises and the power generation efficiency decreases in summer. Photovoltaics Thermal (PVT) power generation has the ad-vantage of being able to produce heat together with power, as well as preventing the reduction in power generation efficien-cy and output due to the temperature rise of the panel. In this study, the amount of heat collected by season and time was calculated for photovoltaics thermal modules using the International Weather for Energy Calculations (IWEC) data provided by the American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE). Based on this, we propose a method of predicting the temperature of the photovoltaics panel using thermal analysis and then calculating the flow rate of coolant to improve power generation efficiency. As the results, the photovoltaics efficiencies versus time on January, April, July, and October in Jeju of the Republic of Korea were calculated to the range of 15.06% to 17.83%, and the maxi-mum cooling load and flow rate for the photovoltaics thermal module were calculated to 121.16 W and 45 cc/min, respec-tively. Though this study, it could be concluded that the photovoltaics thermal system can be composed of up to 53 modules with targeting the Jeju, since the maximum capacity of the coolant circulation pump of the photovoltaics thermal system applied in this study is 2,400 cc/min.

Strategies for Reserving National Lands Based on Environmental Value (환경가치를 고려한 국유지 비축방안)

  • Jisoo Sim;Yoonsun Park
    • Land and Housing Review
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    • v.15 no.3
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    • pp.45-59
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    • 2024
  • Land reservation policies are twofold: Land Banking and Reserved National Lands. The former purchases land for public development before prices rise and controls supply and demand. The latter reserves land for future administrative needs. Both systems aim to reserve land for future supply if prices increase. However, these policies lack responses to contemporary environmental changes, such as the carbon-neutral society and development-restricted zones. This study proposes policy reform to preserve environmental value by evaluating land in metropolitan areas using six ecosystem service variables. Target areas are Gapyeong-gun, Pocheon-si, and Yeoncheon-gun in Gyeonggi Province. Short-term improvements include evaluating environmental value, mid-term measures involve adding environmental considerations to reservations, and long-term measures include expanding the Ministry of Economy and Finance's role in integrated management.

Enrichment of Hydrogenotrophic Methanogens in Coupling with Methane Production Using Electrochemical Bioreactor

  • Jeon, Bo-Young;Kim, Sung-Yong;Park, Yong-Keun;Park, Doo-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.19 no.12
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    • pp.1665-1671
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    • 2009
  • Anaerobic digestion sludge was cultivated in an electrochemical bioreactor (ECB) to enrich the hydrogenotrophic methanogens. A modified graphite felt cathode with neutral red (NR-cathode) was charged with electrochemical reducing power generated from a solar cell. The methane and carbon dioxide collected in a Teflon bag from the ECB were more than 80 ml/l of reactant/day and less than 20 ml/l of reactant/day, respectively, whereas the methane and carbon dioxide collected from a conventional bioreactor (CB) was around 40 ml/l of reactant/day, respectively. Moreover, the maximal volume ratios of methane to carbon dioxide (M/C ratio) collected in the Teflon bag from the ECB and CB were 7 and 1, respectively. The most predominant methanogens isolated from the CB on the $20^{th}$, $80^{th}$, and $150^{th}$ days of incubation were hydrogenotrophs. The methanogenic diversity analyzed by temperature gradient gel electrophoresis (TGGE) of the 16S rDNA variable region was higher in the ECB than in the CB. The DNA extracted from the TGGE bands was more than 95% homologous with hydrogenotrophic methanogens in the ECB, but was an aceticlastic methanogen in the CB. In conclusion, the ECB was demonstrated as a useful system for enriching hydrogenotrophic methanogens and increasing the M/C ratio of the gas product.

Microorganism lipid droplets and biofuel development

  • Liu, Yingmei;Zhang, Congyan;Shen, Xipeng;Zhang, Xuelin;Cichello, Simon;Guan, Hongbin;Liu, Pingsheng
    • BMB Reports
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    • v.46 no.12
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    • pp.575-581
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    • 2013
  • Lipid droplet (LD) is a cellular organelle that stores neutral lipids as a source of energy and carbon. However, recent research has emerged that the organelle is involved in lipid synthesis, transportation, and metabolism, as well as mediating cellular protein storage and degradation. With the exception of multi-cellular organisms, some unicellular microorganisms have been observed to contain LDs. The organelle has been isolated and characterized from numerous organisms. Triacylglycerol (TAG) accumulation in LDs can be in excess of 50% of the dry weight in some microorganisms, and a maximum of 87% in some instances. These microorganisms include eukaryotes such as yeast and green algae as well as prokaryotes such as bacteria. Some organisms obtain carbon from $CO_2$ via photosynthesis, while the majority utilizes carbon from various types of biomass. Therefore, high TAG content generated by utilizing waste or cheap biomass, coupled with an efficient conversion rate, present these organisms as bio-tech 'factories' to produce biodiesel. This review summarizes LD research in these organisms and provides useful information for further LD biological research and microorganism biodiesel development.

Forest Biomass Utilization for Energy Based on Scientifically Grounded and Orthodox (산림바이오매스에너지에 관한 과학적 근거에 따른 통설적 접근)

  • Seung-Rok Lee;Gyu-Seong Han
    • New & Renewable Energy
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    • v.20 no.1
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    • pp.145-174
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    • 2024
  • Addressing climate change necessitates evidence-based policies grounded in science. The use of forest biomass for energy production is based on a broad scientific consensus at the international level. However, some environmental groups in South Korea are opposing this system of energy production. Through this study, the authors aim to reduce unnecessary confusion and foster an atmosphere conducive to meaningful evidence-based policies. We have classified the issue into eight categories: biological carbon cycle, carbon debt, nature-based solutions, air emissions, cascading principles and sustainability certification, forest environmental impacts, climate change litigation, and the behavior of environmental groups and public perception. Consequently, the following key points were derived: (1) the actions of some environmental groups seem to follow a similar pattern to denialist behavior that denies climate change and climate science; (2) the quality of evidence for campaigns that oppose the use of forest biomass for energy production is low, with a tendency to overgeneralize information, high uncertainty, and difficulty in finding new claims.; (3) most of the public believes that forest biomass energy is necessary, and the governments of major countries are aware of its importance. Significantly, Forest biomass for energy is based on an overwhelming level of scientific consensus recognized internationally.

Main-stream Partial Nitritation - Anammox (PN/A) Processes for Energy-efficient Short-cut Nitrogen Removal (주공정에서 아질산화-혐기성 암모늄 산화법에 의한 단축질소제거공정 연구동향)

  • Park, Hongkeun;Rhu, Daehwan
    • Journal of Korean Society on Water Environment
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    • v.34 no.1
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    • pp.96-108
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    • 2018
  • Large efforts have recently been made on research and development of sustainable and energy-efficient short-cut nitrogen removal processes owing to strong attention to the energy neutral/positive wastewater treatment system. Anaerobic ammonium oxidizing bacteria (anammox bacteria) have been highlighted since 1990's due to their unique advantages including 60% less energy consumption, nearly 100% reduction for carbon source requirement, and 80% less sludge production. Side-stream short-cut nitrogen removal using anammox bacteria and partial nitritation anammox (PN/A) has been well established, whereas substantial challenges remain to be addressed mainly due to undesired main-stream conditions for anammox bacteria. These include low temperature, low concentrations of ammonia, nitrite, free ammonia, free nitrous acid or a combination of those. In addition, an anammox side-stream nitrogen management is insufficient to reduce overall energy consumption for energy-neutral or energy positive water resource recovery facility (WRRF) and at the same time to comply with nitrogen discharge regulation. This implies the development of the successful main-stream anammox based technology will accelerate a conversion of current wastewater treatment plants to sustainable water and energy recovery facility. This study discusses the status of the research, key mechanisms & interactions of the protagonists in the main-stream PN/A, and control parameters and major challenges in process development.