• Title/Summary/Keyword: Carbon molecular sieve

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In vivo action of RNA G-quadruplex in phloem development

  • Cho, Hyunwoo;Cho, Hyun Seob;Hwang, Ildoo
    • BMB Reports
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    • v.51 no.11
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    • pp.547-548
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    • 2018
  • Phloem network integrates cellular energy status into post-embryonic growth, and development by tight regulation of carbon allocation. Phloem development involves complicated coordination of cell fate determination, cell division, and terminal differentiation into sieve elements (SEs), functional conduit. All of these processes must be tightly coordinated, for optimization of systemic connection between source supplies and sink demands throughout plant life cycle, that has substantial impact on crop productivity. Despite its pivotal role, surprisingly, regulatory mechanisms underlying phloem development have just begun to be explored, and we recently identified a novel translational regulatory network involving RNA G-quadruplex and a zinc-finger protein, JULGI, for phloem development. From this perspective, we further discuss the role of RNA G-quadruplex on post-transcriptional control of phloem regulators, as a potential interface integrating spatial information for asymmetric cell division, and phloem development.

Development of high permeable $C-SiO_2$membranes derived from poly (imide siloxane) / PVP blends (폴리 이미드 실록산과 PVP 혼합물로부터 유도된 고 투과성 $C-SiO_2$ 막의 개발)

  • Lee, Ji-Min;Kim, Youn-Kook;Park, Ho-Bum;Lee, Young-Moo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.188-191
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    • 2004
  • Carbon molecular sieve (CMS) membranes have superior gas permeation and separation performance compared with polymeric membranes$^{1.3}$ . Up to now, CMS membranes mostly have been mostly focused on the kinds of precursor and pyrolysis condition (pyrolysis temperature, heating rate, pyrolysis atmosphere).(omitted)

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Experimental Study on PSA Process for High Purity CH4 Recovery from Biogas (바이오가스로부터 고순도 CH4 회수를 위한 PSA 공정의 실험적 연구)

  • Kim, Young-Jun;Lee, Jong-Gyu;Lee, Jong-Yeon;Kang, Yong-Tae
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.4
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    • pp.281-286
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    • 2011
  • The objective of this study is to optimize the four-bed six-step pressure swing adsorption(PSA) process for high purity $CH_4$ recovery from the biogas. The effects of P/F(purge to feed) ratio and cycle time on the process performance were evaluated. The cyclic steady-states of PSA process were reached after 12 cycles. The purity and recovery rate of product gas, pressure and temperature changes were constant as the cycle repeated. It was shown that the P/F ratio gave significant effect on the product recovery rate by increasing the amount of purge gas in purge and regeneration step. The optimal P/F ratio was found to be 0.08. As the cycle time increased, the product purity decreased by increasing the feed gas flow rate. It was found that the optimal operating conditions were P/F ratio of 0.08 and total cycle time of 1,440 seconds with the purity of 97%.

A Study on the Synthesis of Hydrocarbon by Fisher-Tropsch Synthesis over Cobalt Catalysts with High Surface Area Support (비 표면적 큰 코발트계 담지촉매를 사용한 피셔-트롭스 반응에 의한 탄화수소의 제조에 관한 연구)

  • Kim, Chul-Ung;Kim, You-Sung;Jeong, Soon-Yong;Jeong, Kwang-Eun;Chae, Ho-Jeong;Lee, Kwan-Young
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.3
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    • pp.279-287
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    • 2009
  • Fisher-Tropsch synthesis for the production of hydrocarbon from syngas was investigated on 20% cobalt-based catalysts (20% Co/HSA, 20% Co/Si-MMS), which were prepared by home-made supports with high surface areas such as high surface alumina (HSA) and silica mesopores molecular sieve (Si-MMS). In the gas phase reaction by syngas only, 20% Co/Si-MMS catalyst was shown in higher CO conversion and lower carbon dioxide formation than 20% Co/HSA, whereas the olefin selectivity was higher in 20% Co/HSA than in 20% Co/Si-MMS. In the effect of n-hexane added in syngas, the selectivities of $C_{5+}$ and olefin were increased by comparing the supercritical phase reaction with the gas phase reaction in addition to reduce unexpected methane and carbon dioxide.

Synthesis and Characterization of Zeolite 4A on Activated Carbon Supports (활성탄 지지체상에서 제올라이트 4A 합성 및 특성)

  • Park, Jeong-Hwan;Suh, Jeong-Kwon;Jeong, Soon-Yong;Lee, Jung-Min;Doh, Myung-Ki
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.204-210
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    • 1997
  • Zeolite 4A-impregnated complex molecular sieve was prepared by hydrothermal reaction after aluminosilicate gel was penetrated into the pore of activated carbon granule. The crystals of zeolite 4A mainly were formed in the macropore of activated carbon, and their average diameter is $0.8{\mu}m$. The pore volume of activated carbon granule is $0.67m{\ell}/g$, and the pore volume of the sample including 21.6wt% of zeolite 4A crystal is $0.41m{\ell}/g$ decreasing the pore volume by 40% due to the crystallization of zeolite 4A crystals on the internal surface of activated carbon. The calcium ion exchange capacity of zeolite 4A-impregnated sample is 320mg $CaCO_3/g$ zeolite, and this value is almost the same as that of zeolite 4A powder. The crystal of zeolite 4A was not separated from the support of activated carbon granule in the course of ultrasonic dispersion. The adsorption isotherm of water on zeolite 4A-impregnated sample shows the intermediate shape between types, I and III. In addition, zeolite 4A-impregnated sample shows the hydrophilic and hydrophobic properties simultaneously.

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CO2 PSA Process using Double-Layered Adsorption Column (이단 적층 흡착탑을 이용한 CO2 PSA 공정)

  • Lee, Hwaung;Choi, Jae-Wook;Song, Hyung Keun;Na, Byung-Ki
    • Clean Technology
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    • v.7 no.1
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    • pp.51-63
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    • 2001
  • In this study, PSA, known as the most economic process, was used to recover $CO_2$ from the power-plant flue gas. Activated carbon and zeolite molecular sieve 13X were used as adsorbent. Activated carbon has been deemed inadequated adsorbent for separating $CO_2$ from the flue gas. However, highly concentrated $CO_2$ could be obtained as a product on the activated carbon adsorbent using the new operating cycle modifying the rinse step. Also, the recovery of $CO_2$ was improved using double-layered adsorption column packed with the activated carbon and the zeolite 13X simultaneously. Adsorption column was filled with the activated carbon in the feed-end side, and the zeolite 13X in the product-end side. The recovery of $CO_2$ increased about 40% with only 25% zeolite, and increased 67% with 50% zeolite at the experimental conditions of 13% $CO_2$ concentration, 10 SLPM flow rate and 2.2 atm adsorption pressure.

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Poly(ether block amide) (PEBA) Based Membranes for Carbon Dioxide Separation (이산화탄소 분리를 위한 PEBA공중합체 기반 분리막)

  • Lee, Jae Hun;Patel, Rajkumar
    • Membrane Journal
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    • v.29 no.1
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    • pp.1-10
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    • 2019
  • Poly(ether block amide) (PEBA) is one of the commercially important class of block copolymer very much suitable specifically for $CO_2$ separation. Gas separation membrane need to have good mechanical strength as well as high gas permeability. The crystalline polyamide (PA) block provides the mechanical strength while the rubbery polyether (PE) group being $CO_2$-philic facilitate $CO_2$ permeation though the membrane. Composition of thermoplastic and rubbery phase in the polymer are changed to fit into suitable gas separation application. Although PEBA has good permeability, the selectivity of the membrane can be enhanced by incorporating molecular sieve without affection much the gas permeability. Mixed matrix membrane (MMM), a class of composite membrane combine the advantage of polymer matrix with the inorganic fillers. However, there are some disadvantages based on the compatibility of the inorganic fillers and polymeric phase. This review covers both the advantage and limitations of PEBA block copolymer based composite membrane.

Carbon Dioxide Reforming of Methane over a Ni/KIT-1 Catalyst (Ni/KIT-1 촉매를 이용한 메탄의 이산화탄소 개질반응 연구)

  • Ryn, Seong-Yun;Ahn, Wha-Seung;Park, Sang-Eon
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1070-1078
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    • 1998
  • Thermodynamic analysis on carbon dioxide reforming of methane was performed using a computer program which can handle condensed species in the products, and the reforming experiments were conducted over $Al_2O_3$, $La_2O_3$, ZSM-5, MCM-41, KIT-1 supported nickel catalysts, and a commercial ICI 46-1. It was estabished that a system which consists of $CH_4$, $CO_2$, CO, $H_2$, $H_2O$, and C is appropriate for theoretical equilibrium calculations and addition of water vapor or oxygen was found to diminish the contribution of carbon dioxide in reforming. Silicate molecular sieve-supported catalysts such as Ni/ZSM-5, Ni/MCM-41, Ni/KIT-1 were effective for high $CH_4$ and $CO_2$ conversions as well as for high CO yield. Coke formation was suppressed when CaO was added as a promoter. Ni/Ca/KIT-1 which contains 10% Ni with 3% Ca showed conversion approaching equilibrium levels above $650^{\circ}C$ and maintained constant activity over 20 h. Despite increased space velocity, relatively high conversion and CO yield were observed.

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Antimicrobial Effect of Metal tons Substitution to HAp, Zeolite (HAp, Zeolite에 여러 금속 Ion 치환시 나타나는 항균효과)

  • Kim, Yun-Jong;Kim, Taek-Nam;Kim, Sang-Bae;Jo, Seong-Baek;Jo, Geon-Jun;Lee, Tae-Hyeong
    • Korean Journal of Materials Research
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    • v.11 no.2
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    • pp.120-125
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    • 2001
  • Generally, hydroxyapatite(HAp), zeolite, carbon molecular sieve , activated carbon and alumina are used as heavy metal ions adsorption materials. Among those adsorption materials, HAp which has good positive ion-exchange ability with metal ion, and zeolite are utilized in wastewater treatment. Most of water pollutions are caused by hazardous heavy metals ions as well as bacteria in waste water. In this study, a adsorption materials (HAP and zeolite) are ion-exchanged with a well known antimicrobial metal ions, such as $Ag^+,\;Cu^{2+},\;and\;Zn^{2+}$, in order to give a adsorption of heavy metal ions and a killing effects of bacteria. The antimicrobial effects of adsorption materials are observed using by E. Coli. The results show that there is a complete antimicrobial effect in the adsorption materials with $Ag^+$ at the concentration of $1{\times}10^{-4}$cell/$m\ell$ of E. Coli until 24 hours. However, there is not good antimicrobial effects in the adsorption materials with $Cu^{2+},\;and\;Zn^{2+}$ substitution. Feng et. al. showed the denaturation effects of silver ions which induces the condensed DNA molecules and losing their replication abilities.

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