• Title/Summary/Keyword: Carbon equivalent

Search Result 360, Processing Time 0.034 seconds

Carbonation Reaction and Strength Development of Air Lime Mortar with Superplasticizer (고성능 감수제가 혼입된 기경성 석회 모르타르의 탄산화 반응 및 강도발현 특성)

  • Kang, Sung-Hoon;Hwang, Jong-Kook;Kwon, Yang-Hee
    • Journal of the Architectural Institute of Korea Structure & Construction
    • /
    • v.35 no.7
    • /
    • pp.179-186
    • /
    • 2019
  • Air lime is a traditional building material of Korea. It had been used in roofs, walls, floors and masonry joints of traditional buildings until the advent of Portland cement. However, due to its low strength and durability, the lime is currently avoided as a repair or restoration material for the preservation of architectural heritage. Furthermore, due to the current practice of using hydraulic materials such as Portland cement, understanding of the material characteristics of air lime is very poor in practice. In this context, this study intended to improve the mechanical properties of the air lime mortar by reducing water contents, and also the carbonation reaction of the mortar was quantitatively evaluated to clearly understand the characteristics of this material. Accordingly, air lime mortar with a water-to-binder ratio of 0.4 was manufactured using polycarboxylate-type superplasticizer. During the 7 days of sealed curing period, the mortar did not harden at all. In other words, there was no reaction required for hardening since it could not absorb carbon dioxide from the atmosphere. However, once exposed to the air, the compressive strength of the mortar began to rapidly increase due to the carbonation reaction, and the strength increased steadily until the 28th day; after then, the strength development was significantly slowed down. On the 28th day, the mortar exhibit a compressive strength of about 5 MPa, which is equivalent to the European standard regarding strength of hydraulic lime used for preservation of architectural heritage.

Synthesis and performance assessment of modified epoxy resins containing fatty acid (지방산 변성 에폭시수지 합성과 성능평가)

  • Lee, Dong-Chan;Kim, Jin-Wook;Choi, Joong-So
    • Journal of the Korean Applied Science and Technology
    • /
    • v.33 no.4
    • /
    • pp.634-646
    • /
    • 2016
  • In this work, modified epoxy resins which were well melted in mild solvent were synthesized and solubility assessment was carried out for synthesized epoxy resins. Bisphenol-A type, phenol novolac type and ortho-cresol novolac type epoxy resins were used and fatty acid, dodecyl phenol (DP) and toluene diisocyanate (TDI) were added for synthesis of modified epoxy resins containing fatty acid (MEFA). Composition was epoxy resin/fatty acid = 1.0/0.5 and fatty acid/DP = 0.25/0.25 by equivalent weight and twelve MEFAs were synthesized according to epoxy resins. Viscosity and solubility were measured for twelve MEFAs. As a result, solubility of MEFA was excellent for mild solvent according to increasement of contents of benzene ring, glycidyl group and carbon number of alkyl group. And physical properties were measured for each coating of paints after preparing transparent paints of MEFA to melt well in mild solvent among twelve MEFAs. As a result, they showed an optimal performance on conditions of equivalent ratio of bisphenol-A type epoxy resin/fatty acid/DP/TDI; 1.0/0.25/0.25/0.5 and equivalent ratio of phenol novolac type epoxy resin/fatty acid/DP; 1.0/0.25/0.25 for drying time, adhesion, hardness, impact resistance and alkali resistance.

Calibration of CR-39 for Hadron Radiotherapy using 400 MeV/u C ions (400 MeV/u 탄소 이온에 대한 방사선치료 선량 측정용 고체비적검출기의 교정)

  • Kim, Sunghwan;Nam, Uk-Won;Lee, Jaejin;Park, Won-Kee;Pyo, Jeonghyun;Moon, Bong-Kon
    • Journal of radiological science and technology
    • /
    • v.39 no.1
    • /
    • pp.43-49
    • /
    • 2016
  • In this study, equivalent dose and LET (Linear Energy Transfer) calibration of CR-39 SSNTD (Solid State Nuclear Track Detector) were performed using 400 MeV/u C heavy ions in HIMAC (Heavy Ion Medical Accelerator in Chiba) for high LET radiation therapy. The irradiated CR-39 SSNDTs were etched according the etching condition of JAXA (Japan Aerospace Exploration Agency). And the etched SSNTDs were analyzed by using Image J. Determined frequency mean dose (${\bar{y_D}}$)and dose-mean lineal energy (${\bar{y_F}}$)of 400 MeV/u C are about 8.5keV/mm and 10.1 keV/mm, respectively by using the CR-39 SSNTD. This value is very similar to the results calculated by GEANT4 Monte Carlo simulation and measured with TEPC (Tissue Equivalent Proportional Counter) active radiation detector. We could determine the equivalent dose and LET calibration factors of CR-39. And we confirmed that the CR-39 SSNTD was useful for high LET radiation dosimetry in hadron radiotherapy.

Formation of Hydroxyapatite in Portland Cement Paste

  • Chung, Chul-Woo;Lee, Jae-Yong;Kim, Ji-Hyun
    • Journal of the Korea Institute of Building Construction
    • /
    • v.14 no.1
    • /
    • pp.68-75
    • /
    • 2014
  • In order to increase the integrity of the wellbore which is used to prevent the leakage of supercritical $CO_2$, it is necessary to develop a concrete that is strongly resistant to carbonation. In an environment where the concentration of $CO_2$ is exceptionally high, $Ca^{2+}$ ion concentration in pore solution of Portland cement concrete will drop significantly due to the rapid consumption of calcium hydroxide, which decreases the stability of the calcium silicate hydrate. In this research, calcium phosphates were used to modify Portland cement system in order to produce hydroxyapatite, a hydration product that is strongly resistant to carbonation under such an environment. According to the experimental results, calcium phosphates reacted with Portland cement to form hydroxyapatite. The formation of hydroxyapatite was verified using X-ray diffraction analyses with selective extraction techniques. When using dicalcium phosphate dihydrate and tricalcium phosphate, the 28-day compressive strength was lower than that of plain cement paste. However, the specimen with monocalcium phosphate monohydrate showed equivalent strength to that of plain cement paste.

Size-dependent forced vibration response of embedded micro cylindrical shells reinforced with agglomerated CNTs using strain gradient theory

  • Tohidi, H.;Hosseini-Hashemi, S.H.;Maghsoudpour, A.
    • Smart Structures and Systems
    • /
    • v.22 no.5
    • /
    • pp.527-546
    • /
    • 2018
  • This article presents an analysis into the nonlinear forced vibration of a micro cylindrical shell reinforced by carbon nanotubes (CNTs) with considering agglomeration effects. The structure is subjected to magnetic field and transverse harmonic mechanical load. Mindlin theory is employed to model the structure and the strain gradient theory (SGT) is also used to capture the size effect. Mori-Tanaka approach is used to estimate the equivalent material properties of the nanocomposite cylindrical shell and consider the CNTs agglomeration effect. The motion equations are derived using Hamilton's principle and the differential quadrature method (DQM) is employed to solve them for obtaining nonlinear frequency response of the cylindrical shells. The effect of different parameters including magnetic field, CNTs volume percent and agglomeration effect, boundary conditions, size effect and length to thickness ratio on the nonlinear forced vibrational characteristic of the of the system is studied. Numerical results indicate that by enhancing the CNTs volume percent, the amplitude of system decreases while considering the CNTs agglomeration effect has an inverse effect.

Characterization of Toxic Pollutants in Ash and Flue Gas from Gasification Incinerator of Waste Tires (폐타이어 건류 소각에서 발생되는 재와 배기 가스에서의 독성 오염 물질의 정량)

  • Koo, Ja Kong;Seo, Young Hwa;Kim, Seok Wan;Yoo, Dong Joon
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.13 no.1
    • /
    • pp.213-220
    • /
    • 1993
  • The problem of disposing of huge quantities of used tires is of growing concern to every country. As an economical solid waste management, a gasification followed by incineration process was applied to scrap tires to recover heat and to reduce waste volume for final landfill disposal. The gasification temperature, combustible and non-combustible gasified products and possibly produced air pollutants were predicted by changing equivalent mole ratios of carbon to oxygen by a chemical equilibrium model. For a risk assessment of ash toxic pollutants including heavy metals and toxic organics were thoroughly analyzed. Gasification bottom ash contained much more toxic organic compounds than fly ash, whereas fly ash contained higher concentration of heavy metals such as Pb and Cd. Pretreatment or secure landfill technology is suggested for a safe management of ash produced from the gasification incinerators.

  • PDF

Studies on the Emission control of methanol engine exhaust with modified 3-way catalyst at cold start condition (변형된 삼원촉매에 의한 저온시동조건에서의 메탄올엔진 배가스 정화효과에 관한 연구)

  • 홍종성;정석진
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.9 no.2
    • /
    • pp.160-167
    • /
    • 1993
  • As the major methanol fueled vehicle exhaust components, formaldehyde & methanol conversion over the existing commercial 3-way catalyst was examined in a labolatory tains different Ag loadings on commercial 3-way catalyst, and german commercial catalysts for methanol engine exhaust manufactured by a commercial manufacturer. Silver catalysts were prepared by the wet impregnation of silver nitrate solution on commercial 3-way catalyst. These catalysts were characterized with BET Surface area and pore size distribution. In general, the formaldehyde(HCHO) conversion of the tested catalysts was similar to that of methanol$(CH_3OH)$. At 100$^\circ$C, which is equivalent to the cold start condition, 5wt% Ag cat. showed the most excellent HCHO and $CH_3OH$ conversion. The order of activity for conversion of HCHO & $CH_3OH$ to carbon dioxide and water vapor was as follows ; 5wt% Ag/3-way cat.>2wt% Ag/3-way cat.>german cat. front(1) > german cat. rear(2) > 10wt% Ag/3-way cat.> commercial 3-wat catalyst. However there was no significant activity difference between those tested catalysts in the hot run condition of 400$^\circ$C. Therefore, it could be concluded that the Ag-modified 3-way catalyst was the most effective and practical catalyst system which could be capable of removal the HCHO and methanol at the special condition of low temperature such as cold start condition.

  • PDF

A Study on Mode I Interlaminar Fracture Toughness of Foam Core Sandwich Structures

  • Sohn, Se-Won;Kwon, Dong-Ahn;Hong, Sung-Hee
    • International Journal of Precision Engineering and Manufacturing
    • /
    • v.2 no.3
    • /
    • pp.47-53
    • /
    • 2001
  • This paper investigates the characteristics of interlaminar fracture toughness of foam core sandwich structures under opening mode by using the double cantilever beam (DCB) specimens which are Carbon/Epoxy and foam core composites. Instead of using a DCB specimen of symmetric geometry, a non-symmetric DCB specimen was used to calculate the interlaminar fracture toughness. Three approaches for calculating the energy release rate(G$\sub$IC/) were used and fracture toughness of foam core sandwich structures made by autoclave, vacuum bagging and hotpress were compared. Experiment, analysis using nonlinear beam bending theory, and numerical work by FEM methods were performed. Bonding surface compensation and equivalent moment of inertia were used to calculate the energy release rate in nonlinear analytical work. Conclusions of experimental, nonlinear analytical and FEM methods were compared. It is, also, shown that the vacuum bagging forming can substitute the method of autoclave without serious loss of Mode I energy release rate(G$\sub$I/).

  • PDF

Wear Characteristics of Automotive Disc Brakes: Effect of Gray Cast Iron Microstructures (자동차 브레이크용 디스크의 미세조직에 따른 편마모 특성에 관한 연구)

  • Lee, Jae-Young;Kim, Seong-Jin;Han, Chang-Joo;Jang, Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
    • /
    • 2002.05a
    • /
    • pp.235-239
    • /
    • 2002
  • The objective of the experiment is to investigate the effect of microstructures of gray cast iron oil wear characteristics of automotive disc brakes. Six different gray cast iron rotors were manufactured by changing carbon equivalent and cooling rate. The change of DTV (disc thickness variation) before and after wear tests was measured to examine the wear properties according to the microstructures of gray iron discs since the DTV generation is caused by the circumferential uneven wear. Experimental results showed that the morphology of graphite flake and hardness in gray cast iron were crucially associated with the change of DTV. In particular, the DTV changes of rotor decrease when the length and area fraction of graphite flake in brake rotors increase and hardness of brake discs reduces.

  • PDF

A Study on Effect of PWHT in AH36-TMCP Steel (AH36-TMCP강의 용접후열처리 효과에 관한 연구)

  • 유효선;장원상;안병국;정세희
    • Journal of Welding and Joining
    • /
    • v.16 no.6
    • /
    • pp.44-51
    • /
    • 1998
  • It is well known that the fine bainitic microstructure obtained by TMCP(thermo-mechanical control process) secures the high toughness of base metal. Besides, TMCP steel is very suitable for high heat input in welding as it has low carbon equivalent. In HAZ, however, the accelerated cooling effect imparted on the matrix by the weld thermal cycles is relieved and thus the weldment of TMCP steel has softening zone which shows low fracture toughness compared with base metal. Therefore, PHWT of weldment is carried out to improve the fracture toughness in weldment of TMCP steel which has softening zone. In this study, the effects of PWHT on the weldment of AH36-TMCP steel are investigated by the small punch (SP) test. From the several results such as SP energy and displacement at room temperature, the behavior of transition curves, the fracture strength at -196$^{\circ}C$, distribution of (DBTT)sp and (DBTT)sp, the PWHT condition of A.C. after 85$0^{\circ}C$-1 sec W.C. was suitable condition for recovering a softening zone of HAZ as welded.

  • PDF