• Title/Summary/Keyword: Carbon dioxide (CO2)

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Anion co-doped Titania for Solar Photocatalytic Degradation of Dyes

  • Lee, Young-Seak;Kim, Sang-Jin;Venkateswaran, P.;Jang, Jeen-Seok;Kim, Hyuk;Kim, Jong-Gyu
    • Carbon letters
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    • v.9 no.2
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    • pp.131-136
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    • 2008
  • In order to investigate the effect of doping C, N, B and F elements on $TiO_2$ for reducing the band gap, the heat treatment of $TiO_2$ was carried out with tetraethylammonium tetrafluoroborate. Through XRD and XPS analysis, the C, N, B and F doped anatase $TiO_2$ was confirmed. According to the increase of temperature during treatment, the particle size was increased due to aggregation of $TiO_2$ with elements (B, C, N and F). To investigate the capacity of photocatalyst for degradation of dye under solar light, the degradation of acridine orange and methylene blue was conducted. The degradation of dyes was carried out successfully under solar light indicating the effect of doping elements (B, C, N and F) on $TiO_2$ for reducing the band gap effectively.

Chromosome Aberration Test of Water Extract of Decaffeined Green Tea using Supercritical Carbon Dioxide With Mammalian Cell Line (초임계이산화탄소를 이용한 탈카페인녹차 열수추출물의 포유동물 세포주를 이용한 염색체이상시험)

  • Koo, Yun-Chang;Lee, Hyun-Sun;Park, Byung-Gyu;Kim, Eun-Jin;Lee, Sun-Joo;Kim, Kyoung-Hoen;Kim, Young-Suk;Kim, Kwang-Ok;Chung, Young-Shin;Lee, Kwang-Won
    • Environmental Mutagens and Carcinogens
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    • v.26 no.3
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    • pp.63-68
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    • 2006
  • There are $10{\sim}30%$ polyphenol and $2{\sim}4%$ caffeine in green tea. Caffeine is a kind of alkaloid containing nitrogen which cause stimulation, impatience, headache, insomnia, low birth weight infant. Because of these negative effect, decaffeined beverage came out and decaffeined coffee already have a big market since 1970s. Having proving the physiologic functions of green tea, high consumption of coffee is shifting to green tea. Because of the carcinogenic effect of the organic solvents, decaffeine processing with supercritical carbon dioxide has industrialized and have an advantage in environment-friendly and minimized flavor loss. Decaffeined green tea using supercritical carbon dioxide is considered to be safe but there are not enough study, We investigated the chromosome aberration test with mammalian cell line, CHL. When the cells were treated with 5000, 2000, 1000 ${\mu}g/ml$ and compared with the negative controls, there were no significant (P>0.05) increased chromosome aberration. Same results was observed when adding S9 mixture or not. As a result, water extract of decaffeined green tea using supercritical carbon dioxide does not induce chromosome aberration.

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Chromosome Aberration Test of Water Extract of Decaffeined Green Tea using Supercritical Carbon Dioxide with Mammalian cell line (초임계이산화탄소를 이용한 탈카페인녹차 열수추출물의 포유동물 세포주를 이용한 염색체이상시험)

  • Koo, Yun-Chang;Lee, Hyun-Sun;Park, Byung-Gyu;Kim, Eun-Jin;Lee, Sun-Joo;Kim, Kyoung-Hoen;Kim, Young-Suk;Chung, Young-Shin;Lee, Kwang-Won
    • Environmental Mutagens and Carcinogens
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    • v.26 no.4
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    • pp.119-124
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    • 2006
  • There are $10{\sim}30%$ polyphenol and $2{\sim}4%$ caffeine in green tea. Caffeine is a kind of alkaloid containing nitrogen which cause stimulation, impatience, headache, insomnia, low birth weight infant. Because of these negative effect, decaffeined beverage came out and decaffeined coffee already have a big market since 1970s. Having proving the physiologic functions of green tea, high consumption of coffee is shifting to green tea. Because of the carcinogenic effect of the organic solvents, decaffeine processing with supercritical carbon dioxide has industrialized and have an advantage in environment-friendly and minimized flavor loss. Decaffeined green tea using supercritical carbon dioxide is considered to be safe but there are not enough study. We investigated the chromosome aberration test with mammalian cell line, CHL. When the cells were treated with 5000, 2000, 1000 ${\mu}g/ml$ and compared with the negative controls, there were no significant(P>0.05) increased chromosome aberration. Same results was observed when adding S9 mixture or not. As a result, water extract of decaffeined green tea using supercritical carbon dioxide does not induce chromosome aberration.

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Bi-electrolyte Carbon Dioxide Gas Sensor Based on Paste Sodium-Beta Alumina and Yttria-stabilized Zirconia

  • Han, Hyeuk Jin;Park, Chong Ook
    • Journal of Sensor Science and Technology
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    • v.23 no.3
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    • pp.170-172
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    • 2014
  • $CO_2$ sensor was used only one solid electrolyte in many cases. To improve the sensing characteristics of $CO_2$ sensors, solid electrolyte $CO_2$ sensor has been developed by bi-electrolyte type sensor using Na-Beta-alumina and YSZ. However, in many further studies, bi-electrolyte type sensor was made by pellet pressed by press machine and additional treatment for formation of interface. In the aspect of mass production, using thick film and additional treatment is not suitable. In this study, $CO_2$ sensor was fabricated by bi-electrolyte structure which was made by an NBA paste layer deposited on YSZ pellet and fired at $1650^{\circ}C$ for 2 hour. The formation of stable interface between YSZ and NBA were confirmed by SEM image. When the type IV electrochemical cell arrangement represented by $CO_2,O_2,Pt{\mid}Li_2CO_3-CaCO_3{\parallel}NBA{\parallel}YSZ{\mid}O_2,Pt$ is used to measure the $CO_2$ concentration in air. This sensor EMF should depend only on the concentration of $CO_2$ by logarithmic. Also, sensor shows $P_{CO_2}$ and EMF relationship like nerstian reaction at a temperature of $450^{\circ}C$.

Study on Fuel Specificity and Harmful Air Pollutants Factor of Agglomerated Wood Charcoal (시중에 유통되고 있는 성형목탄의 연료특성과 유해인자에 대한 연구)

  • JEOUNG, Taek Yong;YANG, Seung Min;KANG, Seog Goo
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.2
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    • pp.253-266
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    • 2020
  • This study selected three types of agglomerated wood charcoal (Agglomerated wood charcoal with charcoal powder, Carbonized wood briquette, Ignition-type of perforated charcoal) that are in circulation in Korea among fuel-type wood products and analyzed the fuel characteristics, harmful substance content, and emissions of air pollutants generated by combustion. The first results showed that charcoal-grilled carbon, which is the raw material of charcoal, produced higher CO than saw-billed carbon. The second result is that the emission standards of air pollutants generated by the combustion of molded wood coal are not up to the emission standards of nitrogen oxides and sulfur oxides in the entire product, compared with the emission criteria of the atmospheric environment preservation method (based on 2019, carbon monoxide: 200 ppm, nitrogen oxides, 150 ppm sulfur oxides: 100 ppm), but the carbon dioxide moulding and carbon dioxide levels were not up. Based on the analysis of combustion gas generated during combustion derived from this study, future research is needed for comparing with the emission standards of pellets, which are wood products for fuel, among the existing biomass burning standards and for reducing carbon monoxide generated during incomplete combustion of agglomerated wood charcoal.

Characteristic of Precipitated Metal Carbonate for Carbon Dioxide Conversion Using Various Concentrations of Simulated Seawater Solution (해수 농축수 내 금속 이온 농도에 따른 이산화탄소 전환 생성물의 특성연구)

  • Choi, Eunji;Kang, Dongwoo;Yoo, Yunsung;Park, Jinwon;Huh, Il-sang
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.539-546
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    • 2019
  • Global warming has mentioned as one of the international problems and these researches have conducted. Carbon Capture, Utilization and Storage (CCUS) technology has improved due to increasing importance of reducing emission of carbon dioxide. Among of various CCUS technologies, mineral carbonation can converted $CO_2$ into high-cost materials with low energy. Existing researches has been used ions extracted solid wastes for mineral carbonation but the procedure is complicated. However, the procedure using seawater is simple because it contained high concentration of metal cation. This research is a basic study using seawater-based wastewater for mineral carbonation. 3 M Monoethanolamine (MEA) was used as $CO_2$ absorbent. Making various concentrations of seawater solution, simulated seawater powder was used. Precipitated metal carbonate salts were produced by mixing seawater solutions and $rich-CO_2$ absorbent solution. They were analyzed by X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Thermogravimetric Analysis (TGA) and studied characteristic of producing precipitated metal carbonate and possibility of reusing absorbent.

A Stable Operation Strategy in Micro-grid Systems without Diesel Generators

  • Choi, Sung-Sik;Kang, Min-Kwan;Lee, Hu-Dong;Nam, Yang-Hyun;Rho, Dae-Seok
    • Journal of Electrical Engineering and Technology
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    • v.13 no.1
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    • pp.114-123
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    • 2018
  • Recently, as one of the countermeasures to reduce carbon dioxide($CO_2$) for global warming problems, operation methods in micro-grid systems replacing diesel generator with renewable energy sources including wind power(WP) and photovoltaic(PV) system have been studied and presented in energetic manners. However, it is reported that some operation problems in micro-grid systems without diesel generator for carbon-free island are being occurred when large scaled WP systems are at start-up. To overcome these problems, this paper proposes an operation strategy in micro-grid systems by adapting control devices such as CVCF(constant voltage constant frequency) ESS(energy storage system) for constant frequency and voltage regulation, load control ESS for balancing demand and supply and SVC(static-var compensator) for reactive power compensation. From the simulation results based on the various operation scenarios, it is confirmed that the proposed operation strategy in micro-grid systems without diesel generators is a useful tool to perform a stable operation in micro-grid systems without diesel generator and also make a contribution to reduce carbon dioxide in micro-grid systems.

Gas Absorption Potential of Oak Charcoal and Modelling for Practical Application (참숯의 가스 흡착능 분석 실험과 실용화 모델링)

  • Park, Youn-Moon;Ha, Hyun-Tae
    • Horticultural Science & Technology
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    • v.19 no.2
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    • pp.174-178
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    • 2001
  • Absorption potential of oak charcoal was estimated using simulated static and dynamic systems to establish a model for practical application of the charcoal in modified atmosphere (MA) packaging and during the storage of 'Fuji' apples. Practical MA packaging was performed using $60{\mu}m$ PE film zipper bags in which five apples were placed. Absorption potential of oak charcoal was $58.4{\mu}L/100g$ charcoal for ethylene and 583 mg/100 g charcoal for carbon dioxide. Effects of enclosing a 100 g-charcoal packet inside a MA package seemed not to last long enough for quality maintenance of 'Fuji' apples stored at $0^{\circ}C$ for three months. During extended storage, ethylene and $CO_2$ levels were not significantly reduced by charcoal treatment. Nevertheless, absorption of carbon dioxide appeared to alleviate the incidence of $CO_2$-related internal browning disorder. Modelling study of practical storage and marketing procedure indicates that 0.19 kg charcoal/day is required to offset $CO_2$ production from 15 kg of apples at $0^{\circ}C$. The amount of charcoal should be increased to 3.10 kg/day if ethylene is a target gas. From the practical point of view, the results suggest that charcoal could be used only for small unit packages for a short period.

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A Research of Trends in Development of Bio-Diesel Aviation Fuel Technology using Microalgae (미세조류 이용 바이오디젤 항공유 기술개발 동향 연구)

  • Han-Young Yoon
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.32 no.2
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    • pp.151-158
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    • 2024
  • Microalgae are aquatic microorganisms capable of photosynthetic growth using water, carbon dioxide and sunlight, and can replace petroleum for transportation. It is receiving great attention as a potential next-generation biological resource. The microalgae biodiesel production process is largely based on the development of highly efficient strains and mass production. It consists of cultivation, harvesting, oil extraction, fuel conversion and by-product utilization. Currently, microalgae diesel is 3-5 times more expensive than petroleum diesel. However, with the optimization of each element technology and the development of integrated systems, not only biofuels, but also industrial materials, wastewater treatment, and greenhouse gases As application expands to various fields such as abatement, the timing of commercialization may be brought forward. Oil prices have recently fallen due to the influence of sail gas. Although there has been a significant drop, global warming is an urgent challenge for current and future generations. In particular, Korea, which does not have oil resources, We must always prepare for political environmental changes, high oil prices, and energy crises. In this paper, the need for eco-friendly biofuel for carbon dioxide conversion. In addition to research trends, domestic and international research trends, and economic prospects, the concept of microalgae and the element technologies of the biodiesel production process are briefly discussed introduced.

Effect of carbon dioxide of root zone on emergence and early growth of transplanted ginseng (근권(根圈)의 CO2 농도(濃度)가 묘삼(苗蔘)의 출아(出芽) 및 초기생육(初期生育)에 미치는 영향(影響))

  • Park, Hoon;Lee, Myong-Gu
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.2
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    • pp.127-130
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    • 1989
  • Ginseng seedlings were transplanted in the perlite and grown with various $CO_2$ concentration for 14 days. The days for full emergence was decreased by 3 days at 6 to 8% $CO_2$ but increased above 13%. Stem length showed significant negative linear correlation with $CO_2$ concentration at 14 days but little difference at 64 days. Relative growth (%) to seedling at 64 days tended to increased till 8% $CO_2$ and decrease thereafter without significance. Seedlings showed 65% emergence with short stem (60%) under 22% $CO_2$ for 64 days. Seedlings were all sleeping under 35% $CO_2$ for 64 days. Above results indicates that $CO_2$ may be useful for growth control or post harvest storage of ginseng.

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