• Title/Summary/Keyword: Carbon dioxide (CO2)

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Development of the Efficiency-Evaluation Model for the Mechanism of CO2 Sequestration in a Deep Saline Aquifer (심부 대염수층 CO2 격리 메커니즘에 관한 효율성 평가 모델 개발)

  • Kim, Jung-Gyun;Lee, Young-Soo;Lee, Jeong-Hwan
    • Journal of the Korean Institute of Gas
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    • v.16 no.6
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    • pp.55-66
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    • 2012
  • The practical way to minimize the greenhouse gas is to reduce the emission of carbon dioxide. For this reason, CCS(Carbon Capture and Storage) technology, which could reduce carbon dioxide emission, has risen as a realistic alternative in recent years. In addition, the researcher is recently working into ways of applying CCS technologies with deep saline aquifer. In this study, the evaluation model on the feasibility of $CO_2$ sequestration in the deep saline aquifer using ANN(Artificial Neural Network) was developed. In order to develop the efficiency-evaluation model, basic model was created in the deep saline aquifer and sensitivity analysis was performed for the aquifer characteristics by utilizing the commercial simulator of GEM. Based on the sensitivity analysis, the factors and ranges affecting $CO_2$ sequestration in the deep saline aquifer were chosen. The result from ANN training scenario were confirmed $CO_2$ sequestration by solubility trapping and residual trapping mechanism. The result from ANN model evaluation indicated there is the increase of correlation coefficient up to 0.99. It has been confirmed that the developed model can be utilized in feasibility of $CO_2$ sequestration at deep saline aquifer.

Simulation Study on the Performance Improvement of a Transcritical Carbon Dioxide Cycle (초월임계 이산화탄소 사이클의 성능향상에 관한 시뮬레이션 연구)

  • 조홍현;김용찬;서국정
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.2
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    • pp.158-166
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    • 2004
  • The performance of a heat pump using $CO_2$ is predicted and analyzed by using a cycle simulation model developed in this study. Cycle simulations are conducted by varying design parameters and operating conditions with the applications of advanced techniques to improve system performance. The applied systems in the simulations are internal heat exchanger, expander, and 2-stage compression with intercooling. As a result, the applications of advanced techniques improve the heating and cooling performances of the transcritical $CO_2$ cycle by 8∼26% and 20∼30%, respectively, over the basic cycle.

Distribution Characteristics between Line and Line for Indoor Air Pollutant Factors at Subway Stations in Seoul Area (서울지역 지하철역의 공기 중 오염인자의 노선별 분포 특성)

  • 김민영;라승훈;신도철;한규문;최금숙;정일현
    • Journal of Environmental Health Sciences
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    • v.24 no.2
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    • pp.134-144
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    • 1998
  • A comprehensive air quality monitoring was carried out to investigate the criteria concentration of air pollutant in indoor of subway stations of Seoul City. The samples were collected twice per year (the first and the second half of the year) at each sampling point from February to September in 1997. Sampling point of subway stations was ticket office and platform. The measurement of indoor air pollutants such as sulfur dioxide(SO$_2$), nitrogen dioxide(NO$_2$), carbon monoxide(CO), carbon dioxide(CO$_2$), total suspended particulate(TSP) was performed to determine the indoor air quality. Heavy metals(Pb, Cd, Cu, Cr, As, Hg) were also measured together with those air pollutants. The annual average concentration of CO$_2$ and TSP in subway stations were relatively high while those of heavy metals were within 10% of environmental recommended standard concentration in all stations. As results of regression analysis between line and line of air factors, the concentrations of CO, CO$_2$, TSP, Pb, Cd, Cr and Cu were highly correlated, but those of $SO_2, NO_2$ and Hg were not correlated. As results of regression analysis between ticket office and platform, the concentrations of heavy metals such as Cr and Cu were highly correlated. Results of oneway analysis of variance between the first and the second half of the year air factors also indicated that CO, CO$_2$, Cd, Cu, Hg were significant($\alpha$=0.01), respectively. The average contration of total suspended particulate(TSP) in subway line No. 1 was shown high concentration(200 $\mu g/m^3\cdot$ day) level.

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Si/SiO2 Multilayer-based Fabry-Perot Filter for 4.26 ㎛ Filtering in Carbon Dioxide Detection (이산화탄소 감지를 위한 4.26 ㎛ 필터용 poly-Si/SiO2 다층 박막 기반의 패브리 페로-필터)

  • Do, Nam Gon;Lee, Junyeop;Jung, Dong Geon;Kong, Seong Ho;Jung, Daewoong
    • Journal of Sensor Science and Technology
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    • v.30 no.1
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    • pp.56-60
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    • 2021
  • In this study, the relationship between the transmitted light intensity and full-width-at-half-maximum (FWHM) of a Fabry-Perot filter was investigated. The measured refractive indices and absorption coefficients of the fabricated thin films were applied to the Fabry-Perot filter via simulations using optical software. Although considerable research has been conducted on Fabry-Perot filters, this study focused on the usefulness of 4.26-㎛ infrared filtering in carbon dioxide detection. Optical analysis was performed considering the effects of the thickness, refractive indices, and number of thin films in a distributed Bragg reflector. Ultimately, a clear trade-off relationship was observed wherein the transmitted light intensity decreased as the number of multilayers increased; however, the FWHM was observed to be narrower.

CO2 Gasification of Carbon Materials by Microwave Heating (마이크로파 가열에 의한 탄소물질의 CO2 가스화)

  • SONG, HEE GAEN;KIM, EUN HYUK;CHUN, YOUNG NAM
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.1
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    • pp.35-42
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    • 2019
  • Recently, the gradual increase in energy acceptance is mostly satisfied by fossil fuels, but research and development of renewable energy sources are attracting attention due to fossil fuel supply and greenhouse gas problem. The disadvantage is that renewable energy can not be produced continuously. This being so, energy storage is an important technology in renewable energy. In this study, microwave was used to convert carbon receptor-carbon dioxide to gas fuel.

Separation of EPA and DHA from Fatty Acid of Fish Oil by Urea Adduct Formation Using Supercritical Carbon Dioxide Solvent (초임계 이산화탄소 용매하의 요소부가법에 의한 어유지방산으로부터 EPA와 DHA의 분리)

  • Kim, Jae-Duck;Lim, Jong-Sung;Lee, Youn-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.2
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    • pp.41-48
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    • 1997
  • Separation of EPA and DHA from fish oil fatty acid ethyl ester (FAFE) by urea adductive crystallization method was carried out in the supercritical carbon dioxide (SC $CO_2$) as a solvent. Our results showed that SC $CO_2$ is a good candidate as a solvent in the urea adductive crystallization to separate FAFE by the number of unsaturated bonds. Compared to the separation process using methanol. SC $CO_2$ yielded better performance in the overall selectivity of EPA and DHA. The effect of process variables on separation of EPA and DHA was discussed in detailed. A hybrid technology of SC $CO_2$ fractionation and urea adductive crystallization with SC $CO_2$ was conformed as a viable process to separate and concentrate EPA and DHA from fish oil.

A Study on Engine Performance and Exhaust Emission Characteristics of Gasoline Engine using Bio-ethanol Blended Fuel (가솔린 엔진(3.8L)에서 바이오에탄올 혼합연료의 성능 및 배출특성에 관한 연구)

  • Lee, Chi-Woo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.11 no.4
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    • pp.131-137
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    • 2012
  • This article is about using the fuel mixed with 10% and 20% bio-ethanol to gasoline for the engine as a way to reduce carbon emission before commercializing future automobiles like fuel cell cars. The fuel mixed with 10% and 20% bio-ethanol showed output equivalent to that of the previous gasoline fuel. CO and $CO_2$ emission was somewhat reduced, but the difference was not significant. And the consumption of the fuel increased slightly. However, bio-ethanol is produced from bio mass growing with the absorption of carbon dioxide, so the total amount of carbon dioxide did not increase according to the result. In NOx, as the use of ethanol increases, the effect of reduction gets greater, and the emission of oxygen showed almost no change compared with gasoline.

Field Applications of Carbon Dioxide Pellet for Underground Pipe Cleaning (지중 매설관의 세정을 위한 카본 다이옥사이드 펠릿의 현장 적용성 검토)

  • Choi, Jae-Soon
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.4
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    • pp.75-82
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    • 2017
  • In this study, a new cleaning method using carbon dioxide pellet in the part of underground pipe cleaning method was proposed and verified. First of all, the commentary of The Society for Protective Coatings was examined in detail to determine the quantitative cleaning effects. Also, field tests were carried out to confirm the application of the new method. In the test, the surface condition of inner pipe after the application of the new method was investigated and two types of nozzles were compared in the tests. Also, the tests to measure the final impact pressure of air and carbon dioxide pellet mixtures were performed to investigate the losses of air pressure were investigated. Through this verification on the new method, it was found that the new method is very efficient for the removal of the rust in the pipe cleaning works. Also, the nozzle with excellent cleaning effect was also selected. As a result, this method will be able to largely contribute to the recycling of $CO_2$ which is limited to the use as a cooling agent or the storage of waste.

Analysis of the Relationship between CO2 Emissions, OCO-2 XCO2 and SIF in the Korean Peninsula (한반도 지역에서 CO2 배출량과 OCO-2 XCO2 및 SIF의 관계성 분석)

  • Yeji Hwang;Jaemin Kim;Yun Gon Lee
    • Korean Journal of Remote Sensing
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    • v.39 no.2
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    • pp.169-181
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    • 2023
  • Recently, in order to reduce carbon dioxide (CO2) emissions, which is the main cause of global warming, Korea has declared carbon emission reduction targets and carbon neutral. Accurate assessment of regional emissions and atmospheric CO2 concentrations is becoming important as a result. In this study, we identified the spatiotemporal differences between satellite-based atmospheric CO2 concentration and CO2 emissions for the Korean Peninsula region using column-averaged CO2 dry-air mole fraction from the Orbiting Carbon Observatory-2 and emission inventory. And we explained these differences using solar-induced fluorescence (SIF), a photosynthetic reaction index according to vegetation growth. The Greenhouse Gas Inventory and Research Center (GIR) and Emissions Database for Global Atmospheric Research (EDGAR) emissions continued to increase in Korea from 2014 to 2018, but the satellite-based atmospheric CO2 concentration decreased in 2018, respectively. Regionally, GIR and EDGAR emissions increased in 2018 in Gyeonggi-do and Chungcheongbuk-do, but satellite-based CO2 concentrations decreased for the corresponding years. In addition, the correlation analysis between emissions and satellite-based CO2 concentration showed a low correlation of 0.22 (GIR) and 0.16 (EDGAR) in Seoul and Gangwon-do. Atmospheric CO2 concentrations showed a different correlation with SIF by region. In the CO2-SIF correlation analysis for the growing season (May to September), Seoul and Gyeonggi-do showed a negative correlation coefficient of -0.26, Chungcheongbuk-do and Gangwon-do showed a positive correlation coefficient of 0.46. Therefore, it can be suggested that consideration of the CO2 absorption process is necessary for analyzing the relationship between the atmospheric CO2 concentration and emission inventory.

A Study on the Methanation of Carbon Dioxide over Ni/Y-type Zeolites (Y형 제올라이트 담지 니켈촉매상에서 이산화탄소의 메탄화반응)

  • Lee, Kwan-Yong;Kim, Hyung-Wook;Kim, Geon-Joong;Ahn, Wha-Seung
    • Applied Chemistry for Engineering
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    • v.4 no.2
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    • pp.365-372
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    • 1993
  • $CO_2$ methanation was performed over Ni supported on cation-exchanged Y zeolites under atmospheric pressure at $250{\sim}550^{\circ}C$ and $H_2/CO_2$ mole ratio of 4. Adsorption strength between carbon dioxide and nickel was found to be Influenced by the cation exchanged in the zeolite. TPD(Temperature-programmed desorption) results show that the adsorption strength decreases in the order of Ni/NaY>Ni/MaY>Ni/HY. TPSR(Temperature-programmed surface reaction) results indicate that enhanced methanation activity is obtained when the adsorption strength between carbon dioxide and nickel is stroing. As the reduction temperature increases, the methantion activity of the catalyst increase. From this result the larger size nickel particle seems advantageous for $CO_2$ methanation reaction. The maximum activity is obtained when nickel loading is 3.3wt%. Carbon monoxide is produced as a by-product throughout the reaction temperature range, and as the contact time increases, the selectivity to methane increases and the selectivity to carbon monoxide decreases steadily. Thus methane seems to be produced from $CO_2$ via CO as an intermediate species. In the temperature range of $410{\sim}450^{\circ}C$, the methane production rate is found to be dependent on the orders of 3.3~-0.5 and 1.4~3.6 with respect to $CO_2$ and $H_2$ partial pressures, respectively. This clearly shows that $CO_2$ and $H_2$ are competing for adsorption sites and as the reaction temperature increases, it becomes increasingly difficult for $H_2$ to be adsorbed on the catalyst surface.

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