• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.232-243
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• 2010

Gas hydrates are crystalline solids composed of water and gas molecules. Water molecules are linked through hydrogen bonding and create cavities(host lattice) that can capture a large variety of guest molecules under appropriate conditions, generally high pressure and low temperature. Recently, many researchers try to apply gas hydrates to industrial processes to capture greenhouse gases due to the facts that the process is eco-friendly and target gas molecules can be preferentially captured. In this paper, we introduced recent studies on $CO_2$ and $CO_2-N_2$ mixture hydrates to evaluate the feasibility of industrial application of gas hydrate technology to $CO_2$ capture process. Specifically, we put emphasis on the technical feasibility of $CO_2$ separation in steel industry using gas hydrate formation principles.

• Applied Chemistry for Engineering
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• v.16 no.2
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• pp.206-211
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• 2005

Mediated electrochemical oxidation (MEO) of polyethylene glycols (PEGs) of molecular weight of 1000, 4000 and 20000, was carried out on both platinum (Pt) and titanium-iridium electrodes in 8.0 M nitric acid solution containing 0.5 M Fe(II) and Co(II) ion. The electrochemical parameters such as current densities, kinds of electrode, electrolyte concentration and removal efficiency were investigated in both Fe(III)/Fe(II) and Co(III)/Co(II) redox systems. The PEGs was decomposed into carbon dioxide by MEO in Fe(III)/Fe(II) and Co(III)/Co(II) redox system during 180 min and 210 min at the current density of $0.67A/cm^2$ on the Pt electrode. Removal efficiency of PEGs by MEO was better in Co(III)/Co(II) redox system than Fe(III)/Fe(II) redox system, indicating mediated electrochemical removal efficiency was 100%.

• Korean Journal of Agricultural and Forest Meteorology
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• v.18 no.4
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• pp.274-286
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• 2016

Carbon dioxide ($CO_2$) accounts for about 72% of the total greenhouse gas emissions. It is also widely known as a major cause of global warming. According to the IPCC's fifth evaluation report, the growth rate of atmospheric $CO_2$ has increased by 35% for the last 100 years and global warming is occurring much more rapidly than expected since 1990s. As a result of climate change, global warming is increasing the frequency and severity of extreme weather events around the world, which has changed forest vegetation zone and vegetation phenology. The Kyoto Protocol recognizes the importance of forests and refers to the conservation and enhancement of forests as sinks and reservoirs of greenhouse gases. In this regard, studies of tree responses to climate change are indispensable for predicting changes in the forest ecosystems in the future. Therefore, studies using long-term climate change research facilities, associated with long-term ecological research (LTER) in the fields, will make a considerable contribution to predict and approach the changes in the future.

• Journal of Environmental Health Sciences
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• v.46 no.6
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• pp.627-635
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• 2020

Objectives: Indoor air quality has become more important aspeople spend most of their times indoors. Since students spend most of their times at home or at school, they are more likely to be exposed to indoor air pollutants. Ventilation in school classrooms can affect health and learning performance. In this study, ventilation deficiency was evaluated in school classrooms using Monte Carlo simulation. Methods: This study used sensor-based monitoring for six months to measure carbon dioxide (CO2) concentrations in classrooms in elementary, middle, and high schools. The volume of the classroom and the number of students were investigated, and the students' body surface area was used to calculate the CO2 emission rate. The distribution of ventilation rates was estimated by measured CO2 concentration and a mass-balance model using Monte Carlo simulation. Results: In the elementary, middle, and high schools, the average CO2 concentrations exceeded 1000 ppm, indicating that the ventilation rates were insufficient. The ventilation rates were deficient from July to August and in December, but showed relatively high ventilation rates in October. Forty-three percent of elementary schools, 56% of middle schools, and 62% of high schools showed insufficient ventilation rates. Conclusions: The ventilation rates calculated in elementary, middle and high schools were found to be quite insufficient. Therefore, proper management is needed to overcome the lack of ventilation and improve air quality.

• Atmosphere
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• v.24 no.2
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• pp.197-206
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• 2014

The effects of different averaging operators and atmospheric stability on the turbulent fluxes are investigated using the vertical velocity, air temperature, carbon dioxide concentration, and absolute humidity data measured at 10 Hz by a 3-dimensional sonic anemometer and an open-path $CO_2/H_2O$ infrared gas analyzer installed at a height of 18.5 m on the rooftop of the Jungnang KT building located at a typical residential area in Seoul, Korea. For this purpose, 7 different averaging operators including block average, linear regression, and moving averages during 100 s, 300 s, 600 s, 900 s, and 1800 s are considered and the data quality control procedure such as physical limit check and spike removal is also applied. It is found that as the averaging interval becomes shorter, turbulent fluxes computed by the moving average become smaller and the ratios of turbulent fluxes computed by the 100 s moving average to the fluxes by the 1800 s moving average under unstable stability are smaller than those under neutral stability. The turbulent fluxes computed by the linear regression are 85~92% of those computed by the 1800 s moving average and nearly the same as those computed by 900 s moving average, implying that the adequate selection of an averaging operator and its interval will be very important to estimate more accurate turbulent fluxes at urban area.

• Clean Technology
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• v.17 no.3
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• pp.266-272
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• 2011

Anchovy oil was extracted using supercritical carbon dioxide ($SCO_2$) and organic solvents. Extraction was carried out at temperature range from 40 to $60^{\circ}C$, and pressure range from 15 to 25 MPa. The flow rate of $CO_2$ (22 $gmin^{-1}$) was constant entire the extraction period of 1.5 h. The fatty acid composition of anchovy oil was analyzed by gas chromatography (GC). The main fatty acids of anchovy oil were myristic acid, palmitic acid, stearic acid, palmitoleic acid, EPA (eicosapentaenoic acid), and DHA (docosahexaenoic acid). In addition, the oil obtained by $SCO_2$ extraction contained a higher percentage of polyunsaturated fatty acids especially EPA and DHA comparing to the organic solvent extracted oil. The oxidative stability of oils extracted from Anchovy by $SCO_2$ extraction was compared to those extracted by organic solvents. Results showed that the storage periods of oils obtained by $SCO_2$ extraction were longer than those of organic solvents extraction.

• Transactions of the Korean Society of Automotive Engineers
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• v.5 no.4
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• pp.93-99
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• 1997

The re quest to develop the engines that are able to run without air or with very little oxygen condition is raised with the interest of ocean science or the mines. This research had already be gun before the world war II, but had been stagnant owing to the appearance of nuclear power. Recycle diesel engines have ability to run under the above mentioned condition the recycle diesel engine recirculates exhaust gases into intake port and consumes additional oxygen supplied by oxygen tank. Carbon dioxide is controlled by the absorber. The combustion and emission characteristics of recycle diesel engines are quite different with conventional one because the working fluids of recycle diesel engines consist of Ar, $CO_2$ and $O_2$ as well as $N_2$. Recycle diesel engine is therefore different with general diesel engine from the viewpoint of intake air composition. It is required to investigate the effect of intake composition in the combustion and emission to know recycle diesel engine. In this study, NOx concentration, smoke and cylinder pressure are measured with the variation of Ar and $CO_2$ Reduces show that the addition of Ar reduces NOx but increases smoke. Otherwise $CO_2$ reduces smoke and NOX simultaneously. Only $CO_2$ increases the ignition delay and both gases increase fuel consumption Ar addition is superior to $CO_2$ addition for the performance of recycle diesel engine system but $CO_2$ has the avantage with respect to emission.

• Korean journal of applied entomology
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• v.42 no.2
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• pp.139-144
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• 2003

The effect of $CO_2$-treatment on interrupting diapause of Bombus ignitus was examined to provide a means for year-round rearing of the bumblebee. When mated young queens were exposed to 65% or 99% $CO_2$ for 30 min daily during two consecutive days, oviposition rate increased to 75% and 77%, respectively, comparing 50% in $CO_2$-untreated queens. At the same time, the days needed to first oviposition shortened to 17-18 days in $CO_2$-treated queens, comparing to 30 days in $CO_2$-untreated queens. $CO_2$-treatment at the second day after mating was appropriate to the oviposition and colony development. $CO_2$-treatment showed a positive effect on the oviposition and colony development, but less than them of overwintered queen in numbers of produced progeny. It can be concluded that $CO_2$-treatment to B. ignitus is insufficient to produce commercial grade bumblebee colony in spite of its capability for promoting oviposition, because the treatment failed to form a big colony.

• Journal of the Korean Institute of Gas
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• v.14 no.3
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• pp.41-45
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• 2010

The physical properties of DME(Dimethyl Ether) are very similar to LPG and well-mixed. As cetane number of DME is similar to diesel fuel that can replace diesel fuel and alternative energy. DME is a clean energy source that can be manufactured from various raw materials such as natural gas, CBM(Coal Bed Methane) and biomass. DME has no carbon-carbon bond in its molecular structure and its combustion essentially generates no soot as well as no SOx. The development of DME process in KOGAS have 4 section. First, syngas section can be manufactured various syngas ratio. This completes the tri-reforming process for the synthesis gas ratio of approximately 4.0 to 1.0 range can be adjusted. Second, $CO_2$ is removed from the $CO_2$ removal section of about 92~99%, so the maximum concentration of $CO_2$ entering the DME synthesis reactor should not exceed 8%. Third, in the DME synthesis section, if the temperature of DME reactor increases, the activity of DME catalyst increased. but for the long-term activity is desirable to maintain the proper temperature. Finally, the purity of DME in the DME purification section is over 99.6%.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.1
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• pp.121-126
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• 2008

The cooling heat transfer coefficient of $CO_2$ (R-744) in a horizontal and helically coiled tube was investigated experimentally. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater, evaporator and gas cooler (test section). The test section consists of a horizontal stainless steel tube and hellically coiled copper tube of 4.57 and 7.75 mm. The experiments were conducted at saturation temperature of 100 to $20^{\circ}C$, and mass flux of 200 to $500kg/m^2s$. The test results showed the variation of the heat transfer coefficient tended to decrease as cooling pressure of $CO_2$ increased. The heat transfer coefficient with respect to mass flux increased as mass flux increased. The experimental results were also compared with the existing correlations for the supercritical heat transfer coefficient, which generally underpredicted the measured data. However, the experimental data showed a relatively good agreement with the correlations of Pitla et al. except for the pseudo critical temperature.