• Title/Summary/Keyword: Carbon corrosion

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An Effects of Radiation Dose Assessment for Radiation Workers and the Member of Public from Main Radionuclides at Nuclear Power Plants (원전에서 발생하는 주요 방사성핵종들이 방사선작업종사자와 원전 주변주민의 피폭방사선량 평가에 미치는 영향)

  • Kim, Hee-Geun;Kong, Tae-Young;Jeong, Woo-Tae;Kim, Seok-Tae
    • Journal of Radiation Protection and Research
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    • v.35 no.1
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    • pp.12-20
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    • 2010
  • In a primary system at nuclear power plants (NPPs), various radionuclides including fission products and corrosion products are generated due to the complex water conditions. Particularly, $^3H,\;^{14}C,\;^{58}Co,\;^{60}Co,\;^{137}Cs,\;and^{131}I$ are important radionuclides in respect of dose assessment for radiation workers and management of radioactive effluents. In this paper, the dominant contributors of radiation exposure for radiation workers and the member of public adjacent to NPPs were reviewed and the process of dose assessment attributable to those contributors were introduced. Furthermore, the analysis for some examples of radiation exposure to radiation workers and the public during the NPP operation was carried out. This analysis included the notable precedents of internal radiation exposure and contamination of demineralized water occurred in Korean NPPs. Particularly, the potential issue about the dose assessment of tritium and carbon-14 was also reviewed in this paper.

δ-Ferrite Behavior of Butt Weld Zone in Clad Steel Plates Depended on Holding Time of PWHT (클래드강 맞대기 용접부의 후열처리 유지시간에 따른 델타 페라이트 거동)

  • Park, Jae-Won;Lee, Chul-Ku
    • Journal of Welding and Joining
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    • v.32 no.2
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    • pp.29-36
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    • 2014
  • Recently, in order to enhance the function and usefulness of products, cladding of dissimilar materials that maximizes the performance of the material is being widely used in all areas of industry as an important process. Clad steel plate, produced by cladding stainless steel plate, an anticorrosive material, on carbon steel plate, is being used to produce pressure vessels. Stainless steel plate has good corrosion resistance, and carbon steel plate has good rigidity and strength; clad steel can satisfy all of these qualities at once. This study aims to find the ${\delta}$-ferrite behavior, mechanical properties, structure change, integrity and reliability of clad steel weld on hot rolled steel plates. For this purpose, multi-layer welding, repair welding and post weld heat treatment were implemented according to welding procedure specifications (WPS). In order to observe the mechanical properties and toughness of clad steel weld zone, post weld heat treatment was carried out according to ASME Sec. VIII Div.1 UW-40 procedure for post weld heat treatment. With heat treatment at $625^{\circ}C$, the hold time was used as the process variable, increased by intervals that were doubled each time, from 80 to 1,280 min. The structure of weld part was typical cast structure; localized primary austenite areas appeared near central vermicular ferrite and fusion line. The heat affected zone showed rough austenite structure created by the weld heat input. Due to annealing effects of heat treatment, the mechanical properties (tensile strength, hardness, impact value) of the heat affected area tended to decrease. From the results of this study, it is possible to conclude the integrity of clad steel welds is not affected much in field welding, repair welding, multi-layer welding, post weld heat treatment, etc.

Evaluation of Liquid Droplet Impingement Erosion through Prediction Model and Experiment (예측모델 및 실험을 통한 액적충돌침식 손상 평가)

  • Yun, Hun;Hwang, Kyeong-Mo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.10
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    • pp.1105-1110
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    • 2011
  • Flow-accelerated corrosion (FAC) is a well-known phenomenon that may occur in piping and components. Most nuclear power plants have carbon-steel-pipe wall-thinning management programs in place to control FAC. However, various other erosion mechanisms may also occur in carbon-steel piping. The most common forms of erosion encountered (cavitation, flashing, Liquid Droplet Impingement Erosion (LDIE), and Solid Particle Erosion (SPE)), have caused wall thinning, leaks, and ruptures, and have resulted in unplanned shutdowns in utilities. In particular, the damage caused by LDIE is difficult to predict, and there has been no effort to protect piping from erosive damage. This paper presents an evaluation method for LDIE. It also includes the calculation results from prediction models, a review of the experimental results, and a comparison between the UT data in the damaged components and the results of the calculations and experiments.

An Estimate of Flexural Strength for Reinforce Concrete Beams Strengthened with CFRP Sheets (탄소섬유쉬트에 의해 휨보강된 RC보의 휨강도 추정)

  • Park Jong-Sup;Jung Woo-Tai;You Young-Jun;Park Young-Hwan
    • Journal of the Korea Concrete Institute
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    • v.17 no.2 s.86
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    • pp.213-220
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    • 2005
  • Carbon fiber reinforced polymer (CFRP) sheets are becoming increasingly popular for strengthening deteriorated concrete bridges due to their excellent strength and stiffness-to-weight ratio, corrosion resistance, and convenience of construction work. The purpose of this study is to compare the performance of CFRP-strengthened reinforced concrete (RC) beams and to develop a new design formula. Simple beams with 3 m span length were tested to investigate the effect of reinforcing steel ratio and CFRP-reinforcing ratio on the flexural behavior of strengthened RC beams. The test results were analyzed with the special emphasis on the failure mode, the maximum load, and the strain distribution in the section. It is shown that the strain of the strengthened beams is not linearly distributed in the section. A new design formula based on the non-linear distribution of the strain has been derived and showed that it has a good agreement with the various domestic and foreign test results.

Finite element modelling of back-to-back built-up cold-formed stainless-steel lipped channels under axial compression

  • Roy, Krishanu;Lau, Hieng Ho;Lim, James B.P.
    • Steel and Composite Structures
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    • v.33 no.1
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    • pp.37-66
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    • 2019
  • In cold-formed steel structures, such as trusses, wall frames and portal frames, the use of back-to-back built-up cold-formed stainless-steel lipped channels as compression members are becoming increasingly popular. The advantages of using stainless-steel as structural members are corrosion resistance and durability, compared with carbon steel. The AISI/ASCE Standard, SEI/ASCE-8-02 and AS/NZS do not include the design of stainless-steel built-up channels and very few experimental tests or finite element analyses have been reported in the literature for such back-to back cold-formed stainless-steel channels. Current guidance by the American Iron and Steel Institute (AISI) and the Australian and New Zealand (gAS/NZS) standards for built-up carbon steel sections only describe a modified slenderness approach, to consider the spacing of the intermediate fasteners. Thus, this paper presents a numerical investigation on the behavior of back-to-back cold-formed stainless-steel built-up lipped channels. Three different grades of stainless steel i.e., duplex EN1.4462, ferritic EN1.4003 and austenitic EN1.4404 have been considered. Effect of screw spacing on the axial strength of such built-up channels was investigated. As expected, most of the short and intermediate columns failed by either local-global or local-distortional buckling interactions, whereas the long columns, failed by global buckling. All three grades of stainless-steel stub columns failed by local buckling. A comprehensive parametric study was then carried out covering a wide range of slenderness and different cross-sectional geometries to assess the performance of the current design guidelines by AISI and AS/NZS. In total, 647 finite element models were analyzed. From the results of the parametric study, it was found that the AISI & AS/NZS are conservative by around 10 to 20% for cold-formed stainless-steel built-up lipped channels failed through overall buckling, irrespective of the stainless-steel grades. However, the AISI and AS/NZS can be un-conservative by around 6% for all three grades of stainless-steel built-up channels, which failed by local buckling.

Evaluation of Tribological Characteristics of Diamond-Like Carbon (DLC) Coated Plastic Gear (플라스틱 기어의 트라이볼로지적 특성 향상을 위한 DLC 코팅 적용)

  • Bae, Su-Min;Khadem, Mahdi;Seo, Kuk-Jin;Kim, Dae-Eun
    • Tribology and Lubricants
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    • v.35 no.1
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    • pp.1-8
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    • 2019
  • Demand for plastic gears are increasing in many industries due to their low production cost, light weight, applicability without lubricant, corrosion resistance and high resilience. Despite these benefits, utilizing plastic gears is limited due to their poor material properties. In this work, DLC coating was applied to improve the tribological properties of polyamide66 gear. 0 V, 40 V, and 70 V of negative bias voltages were selected as a deposition parameter in DC magnetron sputtering system. Pin-on-disk experiment was performed in order to investigate the wear characteristics of the gears. The results of the pin-on-disk experiment showed that DLC coated polyamide66 with 40 V of negative bias voltage had the lowest friction coefficient value (0.134) and DLC coated PA66 with 0 V of negative bias voltage showed the best wear resistance ($9.83{\times}10^{-10}mm^3/N{\cdot}mm$) among all the specimens. Based on these results, durability tests were conducted for DLC coated polyamide66 gears with 0 V of negative bias voltage. The tests showed that the temperature of the uncoated polyamide66 gear increased to about $37^{\circ}C$ while the DLC coated gear saturated at about $25^{\circ}C$. Also, the power transmission efficiency of the DLC coated gear increased by about 6% compared to those without coating. Weight loss of the polyamide66 gears were reduced by about 73%.

Development of GDL-carbon Composite Bipolar Plate Assemblies for PEMFC (PEM 연료전지용 가스확산층-탄소 복합재료 분리판 조합체 개발)

  • Lim, Jun Woo
    • Composites Research
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    • v.34 no.6
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    • pp.406-411
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    • 2021
  • PEM (proton exchange membrane) fuel cells generate only water as a by-product, and thus are in the spotlight as an eco-friendly energy source. Among the various components composing the stack of the fuel cell, research on the bipolar plate that determines the efficiency of the fuel cell is being actively conducted. The composite bipolar plate has high strength, rigidity and corrosion resistance, but has the disadvantage of having a relatively low electrical conductivity. In this study, to overcome these shortcomings, a gas diffusion layer (GDL)-composite bipolar plate assembly was developed and its performance was experimentally verified. The graphite foil coating method developed in the previous study was applied to reduce the contact resistance between the bipolar plate and the GDL. In addition, in order to improve electron path in the stack and minimize the contact resistance between the GDL and the bipolar plate, a GDL-bipolar plate assembly was fabricated using a thin metal foil. As a result of the experiment, it was confirmed that the developed GDL-bipolar plate assembly had 98% lower electrical resistance compared to the conventional composite bipolar plate.

Flexural bearing capacity and stiffness research on CFRP sheet strengthened existing reinforced concrete poles with corroded connectors

  • Chen, Zongping;Song, Chunmei;Li, Shengxin;Zhou, Ji
    • Structural Monitoring and Maintenance
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    • v.9 no.1
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    • pp.29-42
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    • 2022
  • In mountainous areas of China, concrete poles with connectors are widely employed in power transmission due to its convenience of manufacture and transportation. The bearing capacity of the poles must have degenerated over time, and most of the steel connectors have been corroded. Carbon fiber reinforced polymer (CFRP) offers a durable, light-weight alternative in strengthening those poles that have served for many years. In this paper, the bearing capacity and failure mechanism of CFRP sheet strengthened existing reinforced concrete poles with corrosion steel connectors were investigated. Four poles were selected to conduct flexural capacity test. Two poles were strengthened by single-layer longitudinal CFRP sheet, one pole was strengthened by double-layer longitudinal CFRP sheets and the last specimen was not strengthened. Results indicate that the failure is mainly bond failure between concrete and the external CFRP sheet, and the specimens fail in a brittle pattern. The cross-sectional strains of specimens approximately follow the plane section assumption in the early stage of loading, but the strain in the tensile zone no longer conforms to this assumption when the load approaches the failure load. Also, bearing capacity and stiffness of the strengthened specimens are much larger than those without CFRP sheet. The bearing capacity, initial stiffness and elastic-plastic stiffness of specimen strengthened by double-layer CFRP are larger than those strengthened by single-layer CFRP. Weighting the cost-effective effect, it is more economical and reasonable to strengthen with single-layer CFRP sheet. The results can provide a reference to the same type of poles for strengthening design.

Interaction study of molten uranium with multilayer SiC/Y2O3 and Mo/Y2O3 coated graphite

  • S.K. Sharma;M.T. Saify;Sanjib Majumdar;Palash K. Mollick
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1855-1862
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    • 2023
  • Graphite crucibles are used for melting uranium and its alloys in VIM furnace. Various coating materials namely Al2O3, ZrO2, MgO etc. are applied on the inner surface of the crucibles using paint brush or thermal spray technique to mitigate U-C interaction. These leads to significant amount of carbon pick-up in uranium. In this study, the attempts are made to develop multilayer coatings comprising of SiC/Y2O3 and Mo/Y2O3 on graphite to study the feasibility of minimizing U-C interaction. The parameters are optimized to prepare SiC coating of about 70㎛ thickness using CVD technique on graphite coupons and subsequently Y2O3 coating of about 250㎛ thickness using plasma spray technique. Molybdenum and Y2O3 layers were deposited using plasma spray technique with 70㎛ and 250㎛ thickness, respectively. Interaction studies of the coated graphite with molten uranium at 1450℃ for 20 min revealed that Y2O3 coating with SiC interlayer provides physical barrier for uranium-graphite interaction, however, this led to the physical separation of coating layer. Y2O3 coating with Mo interlayer provided superior barrier effect showing no degradation and the coatings remained intact after interaction tests. Therefore, the Mo/Y2O3 coating was found to be a promising solution for minimizing carbon pick-up during uranium/uranium alloy melting.

Study of the corrosion effect of CO2 stream with SO2 and NO2 on a phosphate coated steel tube (SO2 및 NO2 포함 고압 CO2 스트림이 인산염 코팅 CO2 수송관 부식에 미치는 영향)

  • Cho, Meang-Ik;Kang, Seong-Gil;Huh, Cheol;Baek, Jong-Hwa
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.12
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    • pp.6973-6979
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    • 2014
  • To mitigate global warming and climate change, many countries are investing massively on the development of CCS technology, which is assumed to be the key technology to reduce $CO_2$ emissions. CCS technology is comprised of the capture, transport, and storage processes. During the capture process, impurities other than $CO_2$ are inevitably flowed into the $CO_2$ stream. In the present study, corrosion characteristics of a phosphate coated tube for $CO_2$ transportation was investigated with a $CO_2$ stream composed of $CO_2$, $H_2O$, $SO_2$, and $NO_2$. The test specimen was a phosphate coated steel tube, which was filled with $CO_2$ stream with the impurities mentioned above. SEM-EDS analysis is conducted to investigate the corrosion behavior. The results showed that although the H2O concentration did not exceed the solubility limit, corrosion occurred in the specimen, which has an inflow of $SO_2$ or $NO_2$. This suggests that the $SO_2$, $NO_2$ and $H_2O$ concentration should be strictly controlled. These results suggest that the $SO_2$ and $NO_2$ concentration should be controlled below 175ppm and 65ppm, respectively.