• Title/Summary/Keyword: Carbon Supports

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Development of a Cantilevered Patient Table Considering X-ray Transparency (X-선 투과특성을 고려한 외주형 수술용 테이블 개발)

  • Won B.H.;Chun K.J.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.189-190
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    • 2006
  • A patient table considering x-ray transparency, mechanical safety and compact multi-axis moving mechanism has been developed. The goal of medical imaging technology is to keep radiation exposure of patients during x-raying to a minimum. In order to obtain clear pictures at low dose, however, the x-ray table which supports the patient must be sufficiently permeable to radiation to allow good image resolution. The table top is made of low density foam for x-ray transparent effective area and structural aluminum plate to connect moving mechanism under the table, covered with thin carbon fiber. This sandwich construction is very rigid and lightweight, so the table top can handle relatively heavy load comparing to its cantilevered structure which is unavoidable as long as cooperate with C-arm radiography. To verify the design results finite element static analysis and experimental tests have been done. According to the verification the results well satisfy certification guide lines as a medical device.

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The Influence of Support on Gas Mask Cobalt Catalysts for Low Temperature CO Oxidation (방독마스크용 코발트 촉매의 저온 일산화탄소 산화반응에서 지지체의 영향)

  • Kim, Deog-Ki;Kim, Bok-Ie;Shin, Chae-Ho;Shin, Chang-Sub
    • Journal of the Korean Society of Safety
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    • v.21 no.2 s.74
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    • pp.35-45
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    • 2006
  • Cobalt catalysts for gas mask loaded on various supports such as $Al_{2}O_{3},\;TiO_{2}$, AC(activated carbon) and $SiO_{2}$ were used to examine influences of calcination temperatures and reaction temperatures for CO oxidation. $Co(NO_{3})_2{\cdot}6H_{2}O$ was used as cobalt precursor and the catalysts were prepared by incipient wetness impregnation. The catalysts were characterized using XRD, TGA/DTA, TEM, $N_{2}$ sorption, and XPS. For the catalytic activity, support was in the order of ${\gamma}-Al_{2}O_{3}>TiO_{2}>SiO_{2}>AC\;and\;Al_{2}O_{3}$. The catalytic activity at lower temperature than $80^{\circ}C$ showed that with the increase of reaction temperature, cobalt catalysts on ${\gamma}-Al_{2}O_{3},\;TiO_{2},\;AC\$ has the negative activation energy but that of $SiO_{2}$ was positive.

Gas-phase Dehydration of Glycerol over Supported Silicotungstic Acids Catalysts

  • Kim, Yong-Tae;Jung, Kwang-Deog;Park, Eun-Duck
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3283-3290
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    • 2010
  • The gas-phase dehydration of glycerol to acrolein was carried out over 10 wt % HSiW catalysts supported on different supports, viz. $\gamma-Al_2O_3$, $SiO_2-Al_2O_3$, $TiO_2$, $ZrO_2$, $SiO_2$, AC, $CeO_2$ and MgO. The same reaction was also conducted over each support without HSiW for comparison. Several characterization techniques, $N_2$-physisorption, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), the temperature-programmed desorption of ammonia ($NH_3$-TPD), temperature-programmed oxidation (TPO) with mass spectroscopy and CHNS analysis were employed to characterize the catalysts. The glycerol conversion generally increased with increasing amount of acid sites. Ceria showed the highest 1-hydroxyacetone selectivity at $315^{\circ}C$ among the various metal oxides. The supported HSiW catalyst showed superior catalytic activity to that of the corresponding support. Among the supported HSiW catalysts, HSiW/$ZrO_2$ and HSiW/$SiO_2-Al_2O_3$ showed the highest acrolein selectivity. In the case of HSiW/$ZrO_2$, the initial catalytic activity was recovered after the removal of the accumulated carbon species at $550^{\circ}C$ in the presence of oxygen.

Catalytic Detoxication of Coal Combustion Gases (연탄 연소가스의 촉매제독에 관한 연구)

  • Tuwon Chang;Young Sun Uh;Youn Soo Sohn
    • Journal of the Korean Chemical Society
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    • v.29 no.6
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    • pp.656-663
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    • 1985
  • A catalytic conversion of carbon monoxide has been studied in a coal combustion system. Three different catalysts were prepared by impregnating 0.2% platinum on three different types of supports, ${\gamma}-Al_2O_3$ pellets, ceramic foam and honeycomb. These catalysts have shown an excellent initial activities in the coal combustion system, but they were rapidly deactivated in repeated uses. Among these catalysts ceramic foam has shown to be better than others both in activities and durabilities. The main cause of deactivation seems to be ascribed to poisoning by zinc metal and sulfur compounds and to decrease in platinum surface area by sintering.

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Production of L(+)-Lactic Acid by Rhizopus oryzae after Immobilization in Polymer Supports with Gamma-ray Induced Polymerization (방사선중합체로 고정화된 Rhizopus oryzae의 유산생성)

  • 양재승;타마다
    • KSBB Journal
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    • v.6 no.4
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    • pp.403-406
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    • 1991
  • Lactic acid production yield was examined for commercial use by immobilizing Rhizopus oryzae with radiation induced polymer. The supporting material was synthesized by the low temperature radiation polymerization method, in which the microorganism was entrapped physically by contacting together in culture broth shaking for 24 hours. Support polymers with 5∼10vol-% monomers were able to increase their catalytic activities, consuming 65g/1 of glucose, producing 56g/1 of lactic acid, thus yielding 88% of product in general. But in free culture, the microorganism consumed almost all carbon sources and produced lactic acid only 60% even after 96 hours. The yield of the experiment under discussion was significantly high compared with conventional immobilization procedure.

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Cloning and Characterization of a Gene Cluster for Cyclohexanone Oxidation in Rhodococcus sp. TK6

  • Choi Jun-Ho;Kim Tae-Kang;Kim Young-Mog;Kim Won-Chan;Park Kunbawui;Rhee In-Koo
    • Journal of Microbiology and Biotechnology
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    • v.16 no.4
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    • pp.511-518
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    • 2006
  • A gene cluster for cyclohexanone oxidation was cloned from Rhodococcus sp. TK6, which is capable of growth on cyclohexanone as the sole carbon source. The 9,185-bp DNA sequence analysis revealed seven potential open reading frames (ORFs), designated as ssd-chnR-chnD-chnC-chnB-chnE-partial pcd. The chnBCDE genes encode enzymes for the four-step conversion of cyclohexanone to adipic acid, catalyzed by cyclohexanone monooxygenase (ChnB), $\varepsilon-caprolactone$ hydrolase (ChnC), 6-hydroxyhexanoate dehydrogenase (ChnD), and 6-oxohexanoate dehydrogenase (ChnE). Furthermore, the presence of a regulatory element in the downstream region of the chnD gene supports the notion that chnR is a putative regulatory gene. Among them, the activity of ChnB was confirmed and characterized, following their expression and purification in Escherichia coli harboring the modified chnB gene (chnB gene with 6 successive codons for His at the 3' terminus).

Dimethyl Carbonate Synthesis by Methanol Oxidative Carbonylation (메탄올 산화 카르보닐화에 의한 디메틸카보네이트 합성)

  • Nam, Jeong-Kwang;Cho, Deug-Hee;Suh, Jeong-Kwon;Kim, Seong-Bo
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.530-534
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    • 2011
  • The synthesis of dimethyl carbonate by liquid phase oxidative carbonylation of methanol was studied under batch reaction system. Reaction factors such as effect on various metals, anion containing in copper catalyst, temperature, carbon monoxide and oxygen molar ratio and copper content were investigated. In particular $CuCl_2{\cdot}2H_2O$ showed the excellent of the methanol conversion 65.2%, DMC selectivity 96.6% reaction condition under 1.0 g, $150^{\circ}C$, MeOH/CO/$O_2$=0.2/0.215/0.05 (molar ratio). $CuCl_2$ led to corrosion of the reactor. Thus, a new catalyst system using supports was investigated to resolve these corrosion problem. Influence on various supports were examined and copper catalyst supported on zeolite Y showed the most excellent activity on the formation of dimethyl carbonate. The amount of Fe dissolved during the reaction using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometer) was compared with catalysts, calcined Cu/zeolite Y showed the lower value below 5% than $CuCl_2-2H_2O$.

CO2 Capture Performance of Dry Sorbents Manufactured by Coal Fly Ash (석탄 화력발전소의 비산재를 이용한 건식 CO2 흡수제 제조 및 특성 연구)

  • Lee, Jae Hee;Wee, Jung-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.8
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    • pp.547-553
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    • 2013
  • This paper investigates the effect of coal-fired fly ash on dry $CO_2$ sorbents as the supports and additives. For this purpose, various kinds of dry sorbent were manufactured by mixing fly-ash, the primary $CO_2$ absorption components (NaOH and CaO) and water with their different combination. Thereafter, their $CO_2$ absorption performance and the property were analyzed. As a result, variation of absorption efficiency and temperature as well as $CO_2$ desorption of the sorbents are confirmed, which may be primarily ascribed to fly-ash addition to the sorbents. Particularly, fly-ash effect is strongly measured in the sorbent manufactured by mixing all four components (named WNCF sorbents). Absorption efficiency of WNCF sorbents at $550^{\circ}C$ is 35.6% higher than that of flyash free sorbent and desorption is solely observed in WNCF sorbents. Fly-ash in WNCF sorbents leads to increase the dispersity of $CO_2$ absorption components and decrease their particle size in the sorbents. In addition, fly-ash is used as the supports and pozzolanic reaction is hindered by NaOH in WNCF sorbent. Furthermore, $CO_2$ desorption from the sorbents may be due to fly-ash. The interaction between fly-ash and $CO_2$ absorption components substantially attenuate the strength between captured $CO_2$ in CaO and NaOH.

Aluminum Solubility of Andisols in Jeju Island, Korea (제주도 Andisol 토양의 Al-용해도 특성)

  • Lee, Gyoo-Ho;Song, Yun-Goo;Moon, Ji-Won;Moon, Hi-Soo
    • Economic and Environmental Geology
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    • v.45 no.2
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    • pp.89-104
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    • 2012
  • The solubility of aluminum for two Andisol profiles formed on pyroclastic materials and basaltic rocks from Jeju Island, Korea was investigated. It is found that high organic carbon content and $Al_{pyrophosphate}/Al_{oxalate}$ ratios in the A horizons, suggesting the substantial amounts of reactive Al are associated with organic matter, whereas the low organic carbon content and the $Al_{pyrophosphate}/Al_{oxalate}$ ratios in the Bo horizons indicate that a major part of the reactive Al should be bound inorganically. The differential FT-IR spectra following acid-oxalate dissolution and heating up to 150 and $350^{\circ}C$, and transmission electron microscope (TEM) observation confirm that imogolite is in the Bo horizon. Our results of equilibration experiments demonstrate that the Al solubility in the Bo horizon for Andisols can be clarified by the congruent dissolution model for imogolite-type material (ITM), rather than by the simultaneous equilibrium with both ITM and Al hydroxy-interlayered aluminosilicate. With results from dialysis and aging procedures, it is noted that the formation of a proto imogolite sol showing its transformation to imogolite, which supports the congruent dissolution of ITM primarily controlling the Al solubility of Andisols in Jeju Island, Korea.

A Study on the Green Growth Policy and Government Support -Focusing on the Green Logistics- (녹색성장 정책과 정부 지원에 관한 연구 -녹색물류를 중심으로-)

  • Kim, Tae-Hwan;Ryu, Seong-Kyun
    • International Commerce and Information Review
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    • v.14 no.1
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    • pp.315-344
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    • 2012
  • Each country has set low-carbon green growth to a new growth drive for the future while making various efforts. Accordingly, our country also set green growth to our policy task in top priority throughout our country while initiating various policies. Our country has focused on initiating a few policies in green growth. Our country has focused on the development of green industries to secure our national competitiveness while generating added values in green growth. It is necessary to have studies in initiating policies in balance when we consider that green growth should be initiated through the shift over the whole lifestyle. On the other hand, policies led and driven by the central government have been emphasized. Although the planning and establishment of policies might be said to fall under the central government's main areas, green growth policies can be realized regionally in the end. Considering these circumstances, the coordination in a proper way between the central government and each municipality can also be seen as major characteristics only in our country, which can be hardly seen in other countries. This study aims at developing the initiative strategies in our country's green logistics while analyzing the characteristics of green growth and situations of green logistics initiative, studying the government's policies to support green logistics, reviewing the government's policies for supports, and suggesting alternatives for them.

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