• Environmental Engineering Research
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• 제21권3호
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• pp.297-303
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• 2016

Global warming due to greenhouse gases is an issue of great concern today. Fossil fuel power plants, especially coal-fired thermal power plants, are a major source of carbon dioxide emission. In this work, carbon capture and utilization using sodium hydroxide was studied experimentally. Application for flue gas of a coal-fired power plant is considered. Carbon dioxide, reacting with an aqueous solution of sodium hydroxide, could be converted to sodium bicarbonate ($NaHCO_3$). A bench-scale unit of a reactor system was designed for this experiment. The capture scale of the reactor system was 2 kg of carbon dioxide per day. The detailed operational condition could be determined. The purity of produced sodium bicarbonate was above 97% and the absorption rate of $CO_2$ was above 95% through the experiment using this reactor system. The results obtained in this experiment contain useful information for the construction and operation of a commercial-scale plant. Through this experiment, the possibility of carbon capture for coal power plants using sodium hydroxide could be confirmed.

• 소성∙가공
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• 제33권4호
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• pp.261-269
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• 2024

This study aimed to optimize the MIL-53 metal-organic framework coatings for enhanced durability in carbon dioxide capture applications. We synthesized MIL-53 powders using a hydrothermal method and deposited them on stainless-steel substrates by spin coating at various speeds, ranging from 300 to 2,000 rpm. The microstructure, surface properties, and tribological characteristics of the coatings were analyzed systematically. The results indicated that the spin speed significantly impacted the coating uniformity and defect formation. Coatings prepared at moderate speeds of 500 to 1,000 rpm exhibited optimal thickness and density, resulting in superior wear resistance. The tribological tests revealed that the coatings prepared at 700 to 1000 rpm had the lowest wear rates. These findings offer valuable insights for the development of durable MOF-based coatings for carbon dioxide capture and other applications requiring long-term stability under mechanical stress.

• Korean Chemical Engineering Research
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• 제47권5호
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• pp.531-537
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• 2009

무분별한 화석연료 사용에 따른 온실가스 배출의 영향으로 지구 온난화 현상과 이와 연계된 환경 재해들이 발생하고 있다. 대표적 온실가스인 이산화탄소를 방출하지 않고 포집하여 저장하는데 관련된 일련의 기술들을 CCS(carbon dioxide capture and storage)라 하여 최근 매우 큰 주목을 받고 있다. CCS 기술 중에서 화학 흡수법(chemical absorption)은 대규모 처리가 가능하다는 측면에서 그 중에서 가장 많이 상용화된 기술이다. 하지만 발생하는 이산화탄소를 경제적으로 처리할 수 있기까지는 아직도 많은 부분들을 개선할 필요가 있다. 본 논문에서는 공정 시스템 공학 측면에서 화학 흡수법에 대하여 최근 연구 동향을 살펴보고 향후 연구 방향에 대해 살펴 보고자 한다.

• 환경영향평가
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• 제21권3호
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• pp.469-481
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• 2012

CCS(Carbon Dioxide Capture and Storage) is considered as the most effective counterplan in the mitigation of climate change. Even though the risk of leakage of $CO_2$ stored in the geologic formation is very low, the public is expected to disagree with the initiation of a CCS project without proper management plans ensuring the safety. In this study, recognition of laypeople were surveyed about CCS, climate change, characteristics of carbon dioxide, storage concepts, ground pressure, the impact of carbon dioxide, and carbon dioxide for leakage. Thereafter the factors that could affect to recognition of CCS were analyzed by regression analysis. A survey was carried out to find out the public understanding and awareness about climate change and CCS. It is the purpose of this study to propose appropriate risk management strategies based on the findings from the survey.

• KEPCO Journal on Electric Power and Energy
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• 제6권3호
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• pp.297-303
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• 2020

The reaction of carbon dioxide with the amine-based absorbents which have various substituents in the molecule was described. In the case of MEA which is a representative primary amine, the absorption reaction was proceeded very fast while the regeneration reaction was took place slowly due to the strong bond strength between the absorbent and carbon dioxide. The more substituents on N atom of the absorbent, the slower the absorption reaction between carbon dioxide and the absorbent, which in turn causes faster the regeneration rate from the reaction intermediate, carbamate.

• 한국수소및신에너지학회논문집
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• 제28권1호
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• pp.30-39
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• 2017

Interests in fuel cell based power generation systems are on the steady rise owing to various advantages such as high efficiency, ultra low emission, and potential to achieve a very high efficiency by a synergistic combination with conventional heat engines. In this study, the performance of a hybrid system which combined a molten carbonate fuel cell (MCFC) and an indirectly fired micro gas turbine adopting carbon dioxide capture technologies was predicted. Commercialized 2.5 MW class MCFC system was used as the based system so that the result of this study could reflect practicality. Three types of ambient pressure hybrid systems were devised: one adopting post-combustion capture and two adopting oxy-combustion capture. One of the oxy-combustion based system is configured as a semi-closed type, while the other is an open cycle type. The post-combustion based system exhibited higher net power output and efficiency than the oxy-combustion based systems. However, the semi-closed system using oxy-combustion has the advantage of capturing almost all carbon dioxide.

• Advances in nano research
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• 제13권1호
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• pp.1-12
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• 2022

The existence of active material in the environment causes the small-scale systems to be sensitive to the actual environment. Carbon dioxide is one of the active materials that exists a lot in the air conditions of the living environment. However, in some applications, the carbon dioxide-coated is used to improve the performance of systems against the destructive factors such as the corrosion; nevertheless, in the current research, the stability analysis of a carbon dioxide capture mechanism-coated beam is investigated according to the mathematical simulation of a rectangular composite beam utilizing the modified couple stress theory. The composite mechanism of carbon dioxide trapping is made of a polyacrylonitrile substrate that supports a cross-link polydimethylsiloxane gutter layer as the carbon dioxide mechanism trapping. Three novel types of carbon dioxide trapping mechanism involving methacrylate, poly (ethylene glycol) methyl ether methacrylate, and three pedant methacrylates are considered, which were introduced by Fu et al. (2016). Finally, according to introducing the methodology of carbon dioxide (CO₂) trapping, the impact of various effective parameters on the stability of composite beams will be analyzed in detail.

• 한국콘텐츠학회논문지
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• 제16권12호
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• pp.373-382
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• 2016

이산화탄소 포집 및 저장 / 격리 (CCS) 기술은 많은 이산화탄소 저감 방법 중 이상적인 방법으로 주목 받고 있다. 이산화탄소를 포집해서 파이프라인을 통해 저장소까지 수송할 때, 저장소가 가까운 경우 직접 수송할 수도 있지만, 중간 저장의 역할을 하는 허브를 거쳐 수송할 수도 있다. 허브의 수와 위치를 결정하는 것은 중요한 문제이다. 다목적 의사 결정을 위한 수학 모델은 많은 제약식과 목적식을 수반하는데, 문제의 계산 복잡도가 증가하지만 항상 최적을 보장하지 않는다. 본 연구에서는, 이산화탄소 수송망에서 중간 저장 허브의 위치와 수를 결정하는 알고리즘을 제안하고, 이를 활용하여 이산화탄소 발생지의 연결 네트워크 시뮬레이터를 개발한다. 시뮬레이터에서는 또한 이산화탄소의 수송 경로를 제공한다. 사례 연구로 한국에 모델을 적용한다.

• 한국도로학회논문집
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• 제17권2호
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• pp.99-105
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• 2015

PURPOSES: In this study, alkali-activated blast-furnace slag (AABFS) was investigated to determine its capacity to absorb carbon dioxide and to demonstrate the feasibility of its use as an alternative to ordinary Portland cement (OPC). In addition, this study was performed to evaluate the influence of the alkali-activator concentration on the absorption capacity and physicochemical characteristics. METHODS: To determine the characteristics of the AABFS as a function of the activator concentration, blast-furnace slag was activated by using calcium hydroxide at mass ratios ranging from 6 to 24%. The AABFS pastes were used to evaluate the carbon dioxide absorption capacity and rate, while the OPC paste was tested under the same conditions for comparison. The changes in the surface morphology and chemical composition before and after the carbon dioxide absorption were analyzed by using SEM and XRF. RESULTS: At an activator concentration of 24%, the AABFS absorbed approximately 42g of carbon dioxide per mass of paste. Meanwhile, the amount of carbon dioxide absorbed onto the OPC was minimal at the same activator concentration, indicating that the AABFS actively absorbed carbon dioxide as a result of the carbonation reaction on its surface. However, the carbon dioxide absorption capacity and rate decreased as the activator concentration increased, because a high concentration of the activator promoted a hydration reaction and formed a dense internal structure, which was confirmed by SEM analysis. The results of the XRF analyses showed that the CaO ratio increased after the carbon dioxide absorption. CONCLUSIONS : The experimental results confirmed that the AABFS was capable of absorbing large amounts of carbon dioxide, suggesting that it can be used as a dry absorbent for carbon capture and sequestration and as a feasible alternative to OPC. In the formation of AABFS, the activator concentration affected the hydration reaction and changed the surface and internal structure, resulting in changes to the carbon dioxide absorption capacity and rate. Accordingly, the activator ratio should be carefully selected to enhance not only the carbon capture capacity but also the physicochemical characteristics of the geopolymer.

• 청정기술
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• 제18권3호
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• pp.229-249
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• 2012

산업 발달로 화석 연료 사용이 급증하고 이에 따른 지구 온난화 문제와 자원 고갈 문제가 대두되어 지속 성장을 위협하고 있다. 따라서 지속 성장을 위해서 두 문제를 모두 해결하여야 한다. 현재 이산화탄소의 처리 방법으로 인식되고 있는 이산화탄소 포집 및 저장 기술(carbon capture and sequestration, CCS)의 환경 논란으로 인해 사후 처리 기술의 필요성이 커지고 있다. 이에 해결책중 하나로 부각되고 있는 이산화탄소 포집 및 재활용 기술(carbon capture and utilization, CCU)에 대해서 알아보았다. 이산화탄소 전환 기술은 이산화탄소 배출량 감소에 따른 지구 온난화 문제의 해결 뿐 아니라 탄소원의 재활용이란 측면에서 자원고갈 문제의 해결책으로 제시될 수 있겠다. 이산화탄소 전환 기술은 기상 전환과 액상 전환으로 나눌 수 있으며 기상 전환의 경우 필요 에너지 공급원과 온화한 반응조건에서 전환이 이뤄져야 하고 저에너지 소비 생성물 분리 정제 기술의 개발이 필요하다. 액상 전환의 경우, 반응 속도를 높일 수 있는 촉매 및 광감응제 개발과 함께 촉매, 빛, 전기의 혼성 시스템의 개발이 요구되어진다. 이산화탄소 전환 기술은 신재생 에너지 및 바이오산업의 경쟁력 향상을 위한 연결 기술로 그 가치가 매우 크다.