• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.3
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• pp.72-83
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• 2022

This paper studied the effect on the microstructure, electrical properties, and compressive strength of cement mortar containing carbon fiber (CF) and steel fiber (SF), which are conductive materials. The resistivity of conductive fiber-reinforced cement mortar (FRCM) was measured using the 4-probe method, and the compressive strength was measured based on the compression test. Their performance was compared and reviewed with plain mortar (PM). Furthermore, the surface shape and composition of the fracture surface of the conductive FRCM were analyzed using a scanning electron microscope (SEM) and an energy disperse X-ray spectrometer (EDS). The results showed that the resistivity gradually increased as the curing time increased in all specimens, whereas the resistivity decreased significantly as the fiber volume fraction increased. Adding steel fibers up to 1.25% did not affect the resistivity of cement mortar considerably. On the contrast, the resistivity of carbon fiber was somewhat decreased even at low contents (ie, 0.1 to 0.3%), and thereafter, it was significantly decreased. The percolation threshold of the conductive CFRCM containing CF used in this experiment was 0.4%, and it is judged to be the optimum carbon fiber dosage to maximize the conductive effect while maintaining the compressive strength performance as much as possible. For the surface shape and composition analysis of conductive FRCM, the fracture surface was observed through SEM-EDS. These results are considered to be very useful in establishing the microstructure mechanism of reinforcing fibers in cement mortars.

• ETRI Journal
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• v.35 no.4
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• pp.734-737
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• 2013

Nonvolatile ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) memory based on an organic thin-film transistor with inkjet-printed dodecyl-substituted thienylenevinylene-thiophene copolymer (PC12TV12T) as the active layer is developed. The memory window is 4.5 V with a gate voltage sweep of -12.5 V to 12.5 V. The field effect mobility, on/off ratio, and gate leakage current are 0.1 $cm^2/Vs$, $10^5$, and $10^{-10}$ A, respectively. Although the retention behaviors should be improved and optimized, the obtained characteristics are very promising for future flexible electronics.

• Applied Microscopy
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• v.42 no.4
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• pp.223-227
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• 2012

Focused Ion Beam (FIB) systems have incorporated versatile nanomanipulators with inherent sophisticated machining capability to characterize the electrical properties of highly miniature components of electronic devices. Carbon fibers were chosen as a model system to test the applicability of nanomanipulators to microscale electronic materials, with special emphasis on the direct current current-voltage characterizations in terms of electrode configuration. The presence of contact resistance affects the electrical characterization. This resistance originates from either i) the so-called "spreading resistance" due to the geometrical constriction near the electrode - material interface or ii) resistive surface layers. An appropriate electrode strategy is proposed herein for the use of FIB-based manipulators.

• Analytical Science and Technology
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• v.21 no.1
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• pp.25-33
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• 2008

Organic disulfide compounds are having higher theoretical capacity than the conventional cathode material and are considered as the important storage material. Here, we are reporting the preparation of poly (2,2'-dithiodianiline) PDDA/multiwall carbon nanotubes, (MWCNTs) composites under different experimental conditions. Amine functionalized and unfunctionalized MWCNTs were independently used for the preparation of composites. Composites were prepared in the presence of cetyl trimethyl bromide (CTAB), a cationic surfactant, and also in the absence of CTAB. A physical mixture of PDTDA and MWCNTs was formed with unfunctionalized MWCNTs. Grafting of PDDA onto MWCNTs was performed by chemical oxidative polymerization of 2, 2'-dithiodianiline in the presence of amine functionalized MWCNTs. The composites of MWCNTs and PDTDA were characterized for structure, morphology and thermal properties through Fourier transform infrared spectroscopy, Fourier transform Raman spectroscopy, scanning electron microscopy and UV-visible spectroscopy. The composite materials prepared by this method are expected to find applications as electrode materials for lithium batteries.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.422.1-422.1
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• 2016

Graphene quantum dots (GQDs), a new kind of carbon-based photo luminescent nanomaterial from chemically modified graphene oxide (CMGO) or chemically modified graphene (CMG), has attracted extensive research attention in the last few years due to its outstanding chemical, optical and electrical properties. To further extended its potential applications as optoelectronic devices, solar cells, bio and bio-sensors and so on, intensive research efforts have been devoted to the CMG. However, the CMG, a suspension of aqueous, have problematic since they are prone to agglomeration after drying a solvent. In this study, we synthesized the GQDs from graphite and deposited on silicon substrate by kinetic spray. The photo luminescent properties of deposited GQD films were analyzed and compared with initial GQDs suspension. In addition, its carbon properties were investigated with GQDs solution properties. The properties of deposited GQD films by kinetic spray were similar to that of the GQDs suspension in water. We could provide a pathway for silicon-based silicon based device applications. Finally, the well-adjusted GQD films with photo luminescence effects will show Energy-Down-Shift layer effects on silicon solar cells. The GQD layers deposited at nozzle scan speeds of 40, 30, 20, and 10 mm/s were evaluated after they were used to fabricate crystalline-silicon solar cells; the results indicate that GQDs play an important role in increasing the optical absorptivity of the cells. The short-circuit current density (Jsc) was enhanced by about 2.94 % (0.9 mA/cm2) at 30 mm/s. Compared to a reference device without a GQD energy-down-shift layer, the PCE of p-type silicon solar cells was improved by 2.7% (0.4 percentage points).

• Journal of the Korean Ceramic Society
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• v.40 no.5
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• pp.481-487
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• 2003

A technique for determination of proportions of char, coal ana coke is needed in order to monitor pulverized coal injection performance in operating blast furnace. Quantitative X-ray powder diffraction analysis can be applied to the problem providing that structural information on carbonaceous materials, coal, char, coke and their mixture are known. Chars were prepared from a coal at different temperatures (1000∼1400$^{\circ}C$) and were characterised by X-Ray powder Diffraction (XRD). The XRD result gave crystallite size (height Lc and diameter, La), aromaticity, number of (002) plane in carbon, and d-spacing. As a result, with increasing heat treat temperature of char, Lc$_{(002)}$, La$_{(10)}$ and number of (002) plane in carbon were increased, and d-spacing and FWHM(Full With Half Maximum) were decreased. Result of prediction of amount of char from the mixtures (char, coke and ore) based on the Lc$_{(002)}$ information of two mixtures (coke and char) showed very close values expected.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.6
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• pp.1908-1918
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• 1991

Fatigue tests have been carried out to measure the degradation of the residual strength and the fatigue life in carbon/epoxy (0/45/90/-45)$_{2s}$ composite materials. Theoretical predictions of residual strength and fatigue life were compared with experimental results. Distribution characteristics were studied using the probability of failure based on the cumulative distribution function and median rand. The static ultimate strength of carbon/epoxy composites used herein is observed to be relatively higher than that of existing similar composites ; while fatigue life is shorter due to the brittleness of matrix. The fatigue life obtained in these experiments is shorter than that estimated by residual strength degradation model when the stress level above 0.6 For the stress level of 0.6, the experimental value was abruptly increased. The cumulative distribution function for the static ultimate strength is well correlated to that for the strength converted from the measured fatigue life. Also, the predicted distribution of residual strength shows good agreement with the experimental results. Therefore, it is proven that the residual strength degradation model is reasonable.e.

• 대한공업교육학회지
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• v.35 no.2
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• pp.224-237
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• 2010

When the underwater structure sails high speed, noise and vibration propagate to the sensor in the nose of the dome. In this paper, to avoid this kind of noise and vibration CRP(Carbon Reinforced Plastic) material and SNORE ring(Self-NOise REduction Ring) are attached at the curved structure and simulates its isolation characteristics using commercial software. Vibration displacement and stress are calculated at the planar sensor array. The material of the curved structure is aluminum and maximum outer diameter is 53Omm, 215mm in length, 270mm in planar diameter, respectively. Based on the simulation results, reduction ratio of the received normal stress at the sensor is above 95% at the frequency of 12kHz and 15kHz. At the mid point of the planar sensor the normal stress is higher than 20mm and 40mm apart. This results can be used to increase the sensitivity of the acoustic sensor as a basic data.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.10
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• pp.639-647
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• 2017

This basic study is focused on the physically removal method of carbon dioxide from the decomposition of ammonium carbarmate to prevent the recombination of ammonium salts. A basic visual experimental set-up was designed and constructed to observe the recombination phenomena from the proper composition of ammonia gas, carbon dioxide gas, and compressed air dilution gas. To quantify the recombination phenomena, a simple device was designed to measure the weight change under severe cases for three different tube sizes. The temperature and pressure in the visual tube and the volumetric flow rates of the nitrogen dilution gas were studied and the conditions to avoid recombination were analyzed according to mean free path theory. Diffusivity values based on the Chapman-Enskog theory were calculated from the experimental data. These value may serve as an index for the prevention of recombination.

• Composites Research
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• v.28 no.2
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• pp.70-74
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• 2015

In this paper, carbon nanotubes (CNTs) and micro glass bubbles (GBs) have been incorporated into a polyamide6 (PA6) matrix to impart thermoelectric properties. The spaces created in the matrix by GBs allows the formation of "segregated" CNT network. The tightly bound CNT network, if controlled properly, can serve as a conductive path for electron transport, while prohibiting phonon transport, which would provide an ideal configuration for thermoelectric applications. The CNTs and GBs were dispersed in a nylon-formic acid solution using horn sonication followed by coagulation in deionized water, and nanocomposite panels were fabricated using a hot press. The performance of nanocomposite panels was evaluated from thermal and electrical conductivities and Seebeck coefficient, and a thermoelectric figure of merit as high as 0.016 was achieved.