• Title/Summary/Keyword: Carbon/carbon-based materials

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Biodegradation of Endosulfan by Klebsiella oxytoca KE-8 Immobilized on Activated Carbon

  • Jo, Min-Sub;Lee, Jung-Bok;Kim, Jang-Eok;Sohn, Ho-Yong;Jeon, Chun-Pyo;Choi, Chung-Sig;Kwon, Gi-Seok
    • Korean Journal of Environmental Agriculture
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    • v.29 no.2
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    • pp.176-183
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    • 2010
  • Endosulfan degrading ability of Klebsiella oxytoca KE-8 immobilized by entrapment with activated carbon was examined. Endosulfan degradation by the immobilized bacterial strains on several different activated carbon based support materials was investigated. Based on results, activated carbon ($8\times30$ mesh) was chosen as a support material. The immobilized Klebsiella oxytoca KE-8 with the cell density of 4 mg $g^{-1}$ (dry weight) degraded 22.18 ug $ml^{-1}$ endosulfan within 5 days at pH 7.0, $30^{\circ}C$ in batch shake flask cultures. Also, we an experimented recycle packed bed column mode and continuous packed bed column mode for endosulfan degradation. Under optimum operation condition, the immobilized cells in a laboratory scale pack bed column with support beads were able to degrade endosulfan completely in defined minimal salt medium at a maximum rate of 129.6 ug $ml^{-1}$ per day. Moreover, the endosulfan degradation activity could be demonstrated at $4^{\circ}C$ for one month without significant decrease in activity. Results of this study suggest that immobilized cells of Klebsiella oxytoca KE-8 might be applicable to endosulfan contaminated site.

Free-standing Three Dimensional Graphene Incorporated with Gold Nanoparticles as Novel Binder-free Electrochemical Sensor for Enhanced Glucose Detection

  • Bui, Quoc Bao;Nguyen, Dang Mao;Nguyen, Thi Mai Loan;Lee, Ku Kwac;Kim, Hong Gun;Ko, Sang Cheol;Jeong, Hun
    • Journal of Electrochemical Science and Technology
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    • v.9 no.3
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    • pp.229-237
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    • 2018
  • The electrochemical sensing performance of metal-graphene hybrid based sensor may be significantly decreased due to the dissolution and aggregation of metal catalyst during operation. For the first time, we developed a novel large-area high quality three dimensional graphene foam-incorporated gold nanoparticles (3D-GF@Au) via chemical vapor deposition method and employed as free-standing electrocatalysis for non-enzymatic electrochemical glucose detection. 3D-GF@Au based sensor is capable to detect glucose with a wide linear detection range of $2.5{\mu}M$ to 11.6 mM, remarkable low detection limit of $1{\mu}M$, high selectivity, and good stability. This was resulted from enhanced electrochemical active sites and charge transfer possibility due to the stable and uniform distribution of Au NPs along with the enhanced interactions between Au and GF. The obtained results indicated that 3D-GF@Au hybrid can be expected as a high quality candidate for non-enzymatic glucose sensor application.

Mechanical buckling of FG-CNTs reinforced composite plate with parabolic distribution using Hamilton's energy principle

  • Tayeb, Tayeb Si;Zidour, Mohamed;Bensattalah, Tayeb;Heireche, Houari;Benahmed, Abdelillah;Bedia, E.A. Adda
    • Advances in nano research
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    • v.8 no.2
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    • pp.135-148
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    • 2020
  • The incorporation of carbon nanotubes in a polymer matrix makes it possible to obtain nanocomposite materials with exceptional properties. It's in this scientific background that this work was based. There are several theories that deal with the behavior of plates, in this research based on the Mindlin-Reissner theory that takes into account the transversal shear effect, for analysis of the critical buckling load of a reinforced polymer plate with parabolic distribution of carbon nanotubes. The equations of the model are derived and the critical loads of linear and parabolic distribution of carbon nanotubes are obtained. With different disposition of nanotubes of carbon in the polymer matrix, the effects of different parameters such as the volume fractions, the plate geometric ratios and the number of modes on the critical load buckling are analysed and discussed. The results show that the critical buckling load of parabolic distribution is larger than the linear distribution. This variation is attributed to the concentration of reinforcement (CNTs) at the top and bottom faces for the X-CNT type which make the plate more rigid against buckling.

Resistance and Structural Safety of a 3M Carbon Fibier-based Kayak (3미터급 카본 카약의 저항성능 및 구조 안전성 연구)

  • Seo, Kwang-Cheol;Lee, Gyeong-Woo;Park, Joo-Shin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.4
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    • pp.482-488
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    • 2019
  • Leisure and business facilities have been steadily developing in Korea. Among waterborne leisure vessels and equipment, the distribution and sale of kayaks and canoes have significantly increased. Previously, (FRP) materials were primarily employed for constructing kayaks. However, owing to global warming and depletion of natural resources, the demand for non-polluting renewable energy is rapidly increasing, which has increased the demand for carbon fibers. To meet the requirements of changing social consciousness, a carbon fiber-based commercial kayak was designed in this study. Resistance analysis and structural safety were conducted by employing software tool for verifying the reliability of the proposed kayak. The pressure resistance and frictional resistance were examined in a wide range of speed. Obtained results indicate that at speeds greater than 2.6 m/s, the pressure resistance significantly increases and the total resistance also increases. Furthermore, the results corroborate that the proposed kayak structure has a adequate safety with respect to the design loads that are considered during operating conditions.

A study of glass and carbon fibers in FRAC utilizing machine learning approach

  • Ankita Upadhya;M. S. Thakur;Nitisha Sharma;Fadi H. Almohammed;Parveen Sihag
    • Advances in materials Research
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    • v.13 no.1
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    • pp.63-86
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    • 2024
  • Asphalt concrete (AC), is a mixture of bitumen and aggregates, which is very sensitive in the design of flexible pavement. In this study, the Marshall stability of the glass and carbon fiber bituminous concrete was predicted by using Artificial Neural Network (ANN), Support Vector Machine (SVM), Random Forest (RF), and M5P Tree machine learning algorithms. To predict the Marshall stability, nine inputs parameters i.e., Bitumen, Glass and Carbon fibers mixed in 100:0, 75:25, 50:50, 25:75, 0:100 percentage (designated as 100GF:0CF, 75GF:25CF, 50GF:50 CF, 25GF:75CF, 0GF:100CF), Bitumen grade (VG), Fiber length (FL), and Fiber diameter (FD) were utilized from the experimental and literary data. Seven statistical indices i.e., coefficient of correlation (CC), mean absolute error (MAE), root mean squared error (RMSE), relative absolute error (RAE), root relative squared error (RRSE), Scattering index (SI), and BIAS were applied to assess the effectiveness of the developed models. According to the performance evaluation results, Artificial neural network (ANN) was outperforming among other models with CC values as 0.9147 and 0.8648, MAE values as 1.3757 and 1.978, RMSE values as 1.843 and 2.6951, RAE values as 39.88 and 49.31, RRSE values as 40.62 and 50.50, SI values as 0.1379 and 0.2027 and BIAS value as -0.1 290 and -0.2357 in training and testing stage respectively. The Taylor diagram (testing stage) also confirmed that the ANN-based model outperforms the other models. Results of sensitivity analysis showed that the fiber length is the most influential in all nine input parameters whereas the fiber combination of 25GF:75CF was the most effective among all the fiber mixes in Marshall stability.

Performance Evaluation for Repair of Composite Maintenance Robot Using Carbon Fiber Spray Method (탄소섬유 분사형 복합재 유지보수 로봇의 보수성능평가)

  • Geun-Su Song;Dae-Ham Cheon;Jae-Youl Lee;Kwang-Bok Shin
    • Composites Research
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    • v.37 no.2
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    • pp.76-85
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    • 2024
  • In this paper, a composite maintenance robot using carbon fiber spray method was developed that automatically sprays mixture was created for repair to damaged areas to repair them. To develop a robot, a repair process was developed in which a mixture of milled carbon fiber, epoxy resin, and hardener is sprayed and consolidated on the damaged area. To automate the repair process, an EOAT based on a collaborative robot was developed that can automatically suction and spray the mixture onto the damaged area. To evaluate the repair performance of the robot, 0° and 90° unidirectional specimens were manufactured and tested in accordance with ASTM D3039. Tests were performed on undamaged specimen, damaged specimen, and repaired specimen by a robot after damaged. As a result of the specimen test, the tensile strength of the 0° and 90° specimens was recovered by 10% and 90% after repair. Based on the test results, the repair performance of the developed composite maintenance robot was verified.

Mechanical Properties of Cement Grout Including Conductive Materials (전도성 재료를 포함한 시멘트 그라우트의 역학적 특성)

  • Choi, Hyojun;Cho, Wanjei;Hwang, Bumsik;Yune, Chanyoung
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.12
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    • pp.35-41
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    • 2020
  • Recently, underground spaces have been developed variously due to the concentration of the building structure in downtown area and reconstruction of the apartment. However, various problems such as differential settlement are occurring in the waterproof and reinforcement construction. In grouting method, which is frequently used for the ground reinforcement, quality control was performed by measuring the injection quantity of grouting materials and performing laboratory tests using boring samples, but it is difficult to determine whether the ground reinforcement has been performed properly during the construction stage. In order to solve this problem, a research is needed to carry out quality control by measuring electric resistivity after grouting is performed using grouting materials mixed with conductive materials. In this research, as a basic study of the new grouting method using conductive materials, uniaxial compression tests were performed using cement specimen with 0, 3, 5, 7% of carbon fiber to evaluate the effect of conductive material on the performance of grouting material. Based on the test results, the uniaxial compressive strength is increased with the mixed proportion of the carbon fiber increase. Furthermore, the carbon fiber can also affect on the early-strength of the grouting materials.

Fatigue Life Analysis of Composite Materials (복합재료의 피로수명 해석)

  • 이창수;황운봉;박현철;한경섭
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.268-271
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    • 1999
  • Fatigue life Prediction is investigated analytically based on the fatigue modulus concept. Fatigue modulus degradation rate at any fatigue cycle was assumed as a power function of number of fatigue cycles. New stress function describing the relation of initial fatigue modulus and elastic modulus was used to account for material non-linearity at the first cycle. It was assumed that fatigue modulus at failure is proportional to applied stress level. A new fatigue life prediction equation as a function of applied stress is proposed. The prediction was verified experimentally using cross-ply carbon/epoxy laminate (CFRP) tube.

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