• 제목/요약/키워드: Carbon/carbon-based materials

검색결과 1,325건 처리시간 0.026초

FT-IR과 탄소동위원소 분석을 통한 연어유의 구분에 관한 연구 (A Study of Salmon Oil Type Analysis by FT-IR and Carbon Isotopes Ratio)

  • 조은아;차윤환;이영상
    • 한국식품영양학회지
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    • 제25권4호
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    • pp.968-973
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    • 2012
  • This study analyzes the structure types of salmon oil to evaluate the purity of salmon oil products based on the 38 different types of imported salmon oil products distributed in the Republic of Korea. The major types of omega-3 foods in the salmon oil are ethyl ester (EE) and triglyceride (TG). If the salmon oil contained potential contaminants and was processed in order to remove it, EE type omega-3 fatty acids are found in concentration. This provides a good guide in assessing if products were made with EE type ingredients or re-esterified contaminated materials. The results of the FT-IR analysis showed significant difference in the C=O, C-O band positions in TG and EE. There were 19 TG type products and 19 EE type products. The analysis of carbon isotope ratio was performed on the types of TG and EE. There were different properties in the 19 TG type products. In one product, the carbon isotope ratio was -25.15 and the other 18 products showed -22.15~-23.96. The carbon isotope ratio of all 19 EE type products showed -21.91~-23.74. The results of the TLC analysis showed similar results with FR-IR. The re-esterified TG form was not detected in the TG type products, confirming that the TG type products contained natural salmon oil. This study aimed to provide the basic material in classifying the types of natural salmon oil and re-esterified salmon oil, by analyzing the pattern and proportion of FT-IR spectrum, carbon isotope ratio, and TLC.

탄소섬유의 양극산화가 탄소섬유 강화 복합재료의 기계적 계면 특성에 미치는 영향 (Effect of Anodized Carbon Fiber Surfaces on Mechanical Interfacial Properties of Carbon Fibers-reinforced Composites)

  • 박수진;오진석;이재락
    • Composites Research
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    • 제15권6호
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    • pp.16-23
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    • 2002
  • 본 연구에서는 양극산화 처리에 따른 고강도 PAN계 탄소섬유의 표면 특성 변화가 기계적 계면 물성에 미치는 영향을 조사하였다. 탄소섬유의 표면성질은 산.염기도, SEM, XPS, 그리고 접촉각 측정을 통하여 알아보았으며, 복합재료의 기계적 계면 특성은 ILSS와 $K_{IC}$를 통하여 고찰하였다. 탄소섬유 표면의 산도와 $O_{ls}/C_{IC}$가 증가하였는데, 이는 산소관능기의 발달에 기인하고, 양극산화된 탄소섬유의 표면자유에너지의 증가는 극성요소의 증가에 기인하는 것으로 사료된다. ILSS와 $K_{IC}$ 같은 기계적 계면 성질은 양극산화로 향상되어졌는데, 이러한 결과는 좋은 젖음성이 최종 복합재료의 섬유와 에폭시 수지 매트릭스 사이의 계면결합력을 증가시기는 중요한 역할을 하기 때문으로 사료된다.

1.9wt%C 초고탄소 워크롤 단조 공정 : Part II - 기공압착 및 확산접합 (Forging of 1.9wt%C Ultrahigh Carbon Workroll : Part II - Void Closure and Diffusion Bonding)

  • 강성훈;임형철;이호원
    • 소성∙가공
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    • 제22권8호
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    • pp.463-469
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    • 2013
  • In the previous work, a new forging process design, which included incremental upsetting, diffusion bonding and cogging, was suggested as a method to manufacture 1.9wt%C ultrahigh carbon workrolls. The previous study showed that incremental upsetting and diffusion bonding are effective in closing voids and healing of the closed void. In addition, compression tests of the 1.9wt%C ultrahigh carbon steel revealed that new microvoids form within the blocky cementite at temperatures of less than $900^{\circ}C$ and that local melting can occur at temperatures over $1120^{\circ}C$. Thus, the forging temperature should be controlled between 900 and $1120^{\circ}C$. Based on these results, incremental upsetting and diffusion bonding were used to check whether they are effective in closing and healing voids in a 1.9wt%C ultrahigh carbon steel. The incremental upsetting and diffusion bonding were performed using sub-sized specimens of 1.9wt%C ultrahigh carbon steel. The specimen was deformed only in the radial direction during the incremental upsetting until the reduction ratio reached about 45~50%. After deformation the specimens were kept at $1100^{\circ}C$ for the 1 hour in order to obtain a high bonding strength for the closed void. Finally, microstructural observations and tensile tests were conducted to investigate void closure behavior and bonding strength.

Basic Design of High-Speed Riverine Craft Made of Carbon Fiber Reinforced Polymer

  • Han, Zhiqiang;Choi, Jung-kyu;Hwang, Inhyuck;Kim, Jinyoung;Oh, Daekyun
    • 대한조선학회논문집
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    • 제57권4호
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    • pp.241-253
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    • 2020
  • The Small-Unit Riverine Craft (SURC) is a small high-speed vessel used by navies and marine corps in relatively shallow waterway environments, such as riverine areas or littoral coasts. In the past, SURCs have primarily been rigid-hulled inflatable boats constructed using composite materials such as glass fiber reinforced plastics. More recently, single-hull SURCs have been manufactured using aluminum for weight reduction. In this study, a Carbon Fiber Reinforced Polymer (CFRP) material was applied instead to examine its feasibility in the basic design of an SURC with a hull length of 10 m. The CFRP structural design was obtained using the properties of a marine CFRP laminate, determined in a previous study. Next, the designed CFRP SURC was modeled to confirm its functionality, then compared with existing aluminum SURCs, indicating that the CFRP SURC was 41.49 % lighter, reduced fuel consumption by 30 %, and could sail 50 NM further for every hour of engine operation. A method for reducing the high cost of carbon fiber was also proposed based on the adjustment of the carbon fiber content to provide the optimum strength where required. The data developed in this study can be used as a basis for further design of CFRP craft.

Hydro-thermo-mechanical biaxial buckling analysis of sandwich micro-plate with isotropic/orthotropic cores and piezoelectric/polymeric nanocomposite face sheets based on FSDT on elastic foundations

  • Rajabi, Javad;Mohammadimehr, Mehdi
    • Steel and Composite Structures
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    • 제33권4호
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    • pp.509-523
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    • 2019
  • In the present work, the buckling analysis of micro sandwich plate with an isotropic/orthotropic cores and piezoelectric/polymeric nanocomposite face sheets is studied. In this research, two cases for core of micro sandwich plate is considered that involve five isotropic Devineycell materials (H30, H45, H60, H100 and H200) and an orthotropic material also two cases for facesheets of micro sandwich plate is illustrated that include piezoelectric layers reinforced by carbon and boron-nitride nanotubes and polymeric matrix reinforced by carbon nanotubes under temperature-dependent and hydro material properties on the elastic foundations. The first order shear deformation theory (FSDT) is adopted to model micro sandwich plate and to apply size dependent effects from modified strain gradient theory. The governing equations are derived using the minimum total potential energy principle and then solved by analytical method. Also, the effects of different parameters such as size dependent, side ratio, volume fraction, various material properties for cores and facesheets and temperature and humidity changes on the dimensionless critical buckling load are investigated. It is shown from the results that the dimensionless critical buckling load for boron nitride nanotube is lower than that of for carbon nanotube. It is illustrated that the dimensionless critical buckling load for Devineycell H200 is highest and lowest for H30. Also, the obtained results for micro sandwich plate with piezoelectric facesheets reinforced by carbon nanotubes (case b) is higher than other states (cases a and c).The results of this research can be used in aircraft, automotive, shipbuilding industries and biomedicine.

지속가능 섬유 소재 추적성과 저탄소화 공정 (Low Carbonization Technology & Traceability for Sustainable Textile Materials)

  • 최민기;김원준;심명희
    • 한국의류산업학회지
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    • 제25권6호
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    • pp.673-689
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    • 2023
  • To realize the traceability of sustainable textile products, this study presents a low-carbon process through energy savings in the textile material manufacturing process. Traceability is becoming an important element of Life Cycle Assessment (LCA), which confirms the eco-friendliness of textile products as well as supply chain information. Textile products with complex manufacturing processes require traceability of each step of the process to calculate carbon emissions and power usage. Additionally, an understanding of the characteristics of the product planning-manufacturing-distribution process and an overall understanding of carbon emissions sources are required. Energy use in the textile material manufacturing stage produces the largest amount of carbon dioxide, and the amount of carbon emitted from processes such as dyeing, weaving and knitting can be calculated. Energy saving methods include efficiency improvement and energy recycling, and carbon dioxide emissions can be reduced through waste heat recovery, sensor-based smart systems, and replacement of old facilities. In the dyeing process, which uses a considerable amount of heat energy, LNG, steam can be saved by using "heat exchangers," "condensate management traps," and "tenter exhaust fan controllers." In weaving and knitting processes, which use a considerable amount of electrical energy, about 10- 20% of energy can be saved by using old compressors and motors.

단일벽 탄소나노튜브를 이용한 리튬이온전지용 실리콘-흑연 기반 복합전극 설계 (Design of silicon-graphite based composite electrode for lithium-ion batteries using single-walled carbon nanotubes)

  • 최진영;최정민;이승효;강준;김대욱;김혜민
    • 한국표면공학회지
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    • 제57권3호
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    • pp.214-220
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    • 2024
  • In this study, three-dimensional (3D) networks structure using single-walled carbon nanotubes (SWCNTs) for Si-graphite composite electrode was developed and studied about effects on the electrochemical performances. To investigate the effect of SWCNTs on forming a conductive 3D network structure electrode, zero-dimensional (0D) carbon black and different SWCNTs composition electrode were compared. It was found that SWCNTs formed a conductive network between nano-Si and graphite particles over the entire area without aggregation. The formation of 3D network structure enabled to effective access for lithium ions leading to improve the c-rate performance, and provided cycle stability by alleviating the Si volume expansion from flexibility and buffer space. The results of this study are expected to be applicable to the electrode design for high-capacity lithium-ion batteries.

에폭시 수지 적용 아라미드 및 탄소섬유 복합재료의 물성연구 (Property Evaluation of Epoxy Resin based Aramid and Carbon Fiber Composite Materials)

  • 서대경;하나라;이장훈;박현규;배진석
    • 한국염색가공학회지
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    • 제27권1호
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    • pp.11-17
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    • 2015
  • Recently, super fiber reinforced composite materials are widely used in many industries due to high mechanical properties. In this study, 2 different types of composite materials were manufactured in order to compare their mechanical properties. Carbon and Aramid fibers were used for reinforcement materials and Bisphenol-A type epoxy resin was for matrix. Two kinds of fiber-reinforced materials were manufactured by RIM(Resin Injection Molding) method. Before manufacturing composite materials, the optimal manufacturing and curing process condition were established and the ratio of reinforcement to epoxy resin was discussed. FT-IR analysis was conducted to clarify the structure of epoxy resin. Thermal and mechanical property test were also carried out. The cross-section of composite materials was observed using a scanning electron microscope(SEM).

경제성을 고려한 새로운 PAC 선정방법의 적용 (Application of Newly PAC Selection Method Based on Economic Efficiency)

  • 김영일;배병욱
    • 대한환경공학회지
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    • 제28권11호
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    • pp.1141-1147
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    • 2006
  • 경제성을 고려한 새로운 PAC 선정방법을 적용하고자 상수원수 내 MIB와 유기물 제거를 위한 PAC 흡착실험을 수행하였다. PAC 투입량이 증가함에 따라 MIB 제거율은 증가하는 경향을 보였으며, 석탄계 PAC가 목탄계 PAC에 비해 MIB 제거율이 우수한 것으로 나타났다. DOC 및 $UV_{254}$의 제거율은 PAC와 원수 종류에 따라 큰 차이를 보이지는 않았으나, MIB 제거율에 비해 떨어지는 결과를 보였다. MIB, DOC, 그리고 $UV_{254}$ 제거율은 실험에 사용한 PAC들 중에서 P-1000 PAC가 가장 좋았다. EEM 결과에 의하면 모든 시료에 존재하는 대부분의 유기물은 Fulvic산과 유사한 물질인 것으로 판명되었다. 특히, PAC 접촉 이후 대상 시료에 존재하는 유기물 중에서 Fulvic산과 유사한 유기물, Humic과 유사한 유기물, 그리고 SMP와 유사한 유기물 등이 줄어드는 경향을 보였다. 경제성을 고려한 PAC 선정방법에 의해 MCI 값이 가장 낮은 P-1000이 가장 적합한 PAC로 선정되었다. 최종적으로 선정하기에 앞서 PAC의 효율성 및 취급용이성, PAC의 입자크기 및 분포, 그리고 DOC 농도에 따른 PAC 투입비용 등도 고려해야 할 것으로 판단된다.

폴리이미드 기판에 극저온 Catalytic-CVD로 제조된 니켈실리사이드와 실리콘 나노박막 (Nano-thick Nickel Silicide and Polycrystalline Silicon on Polyimide Substrate with Extremely Low Temperature Catalytic CVD)

  • 송오성;최용윤;한정조;김건일
    • 대한금속재료학회지
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    • 제49권4호
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    • pp.321-328
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    • 2011
  • The 30 nm-thick Ni layers was deposited on a flexible polyimide substrate with an e-beam evaporation. Subsequently, we deposited a Si layer using a catalytic CVD (Cat-CVD) in a hydride amorphous silicon (${\alpha}$-Si:H) process of $T_{s}=180^{\circ}C$ with varying thicknesses of 55, 75, 145, and 220 nm. The sheet resistance, phase, degree of the crystallization, microstructure, composition, and surface roughness were measured by a four-point probe, HRXRD, micro-Raman spectroscopy, FE-SEM, TEM, AES, and SPM. We confirmed that our newly proposed Cat-CVD process simultaneously formed both NiSi and crystallized Si without additional annealing. The NiSi showed low sheet resistance of < $13{\Omega}$□, while carbon (C) diffused from the substrate led the resistance fluctuation with silicon deposition thickness. HRXRD and micro-Raman analysis also supported the existence of NiSi and crystallized (>66%) Si layers. TEM analysis showed uniform NiSi and silicon layers, and the thickness of the NiSi increased as Si deposition time increased. Based on the AES depth profiling, we confirmed that the carbon from the polyimide substrate diffused into the NiSi and Si layers during the Cat-CVD, which caused a pile-up of C at the interface. This carbon diffusion might lessen NiSi formation and increase the resistance of the NiSi.