• 제목/요약/키워드: Carbon/carbon-based materials

검색결과 1,325건 처리시간 0.03초

Performance of Magnesia Cement Using MgCO3 and Serpentine

  • Lee, Jong-Kyu;Soh, Jung-Sub
    • 한국세라믹학회지
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    • 제53권1호
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    • pp.116-121
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    • 2016
  • The amount of carbon dioxide ($CO_2$) released while producing building materials is substantial and has been targeted as a leading contributor to global climate change. One of the most typical methods of reducing $CO_2$ in building materials is the addition of slag and fly ash, like pozzolan material another method is to reduce $CO_2$ production by developing carbon negative cement. MgO-based cement from the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. It is also believed that adding reactive MgO to Portland-pozzolan cements can improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, basic research on magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as the main starting materials, as well as blast furnace slag for the mineral admixture, was carried out for industrial waste material recycling. In order to increase the overall hydration activity, $MgCl_2$ was also added. In the case of the addition of $MgCl_2$as accelerating admixture, there was a promoting effect on the compressive strength. This was found to be due to the production of needle-like dense Mg-Cl hydrates. Mgnesia cement has a high viscosity due to its high specific surface area therefore, when the PC-based dispersing agent was added at a level of more than 1.0%, it had the effect of improving fluidity. In particular, the addition of $MgCl_2$ in magnesia cement using $MgCO_3$and magnesium silicate ore (serpentine) as main starting materials led to a lower expansion ratio and an increase in the freeze-thaw resistance finally, the addition of $MgCl_2$ as accelerating admixture led to good overall durability.

재생 및 지속사용 가능 자원 유래 탄소 중립형 접착소재 (Renewable and Sustainable Resource Derived Carbon Neutral Adhesive Materials)

  • 김백진;김상용;조진구;이상협;김현중
    • 접착 및 계면
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    • 제11권2호
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    • pp.76-83
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    • 2010
  • 지난 세기 동안 무분별한 화석자원의 남용과 중국 등 개발도상국에서의 수요급증은 불안정한 유가문제를 야기하였고, 막대한 양의 비가역적 이산화탄소 배출은 지구온난화 문제를 발생시켰다. 이러한 문제를 해결하기 위하여 석유자원을 대체할 수 있는 재생 및 지속사용 가능 자원에 대한 관심이 커지고 있다. 본 논문에서는 재생 및 지속사용 가능 자원으로서 식물성 바이오매스 공급원을 활용하여 석유화학제품 대체하고자 하는 연구개발 동향을 접착소재의 관점에서 고찰하였다.

On static bending of multilayered carbon nanotube-reinforced composite plates

  • Daikh, Ahmed Amine;Bensaid, Ismail;Bachiri, Attia;Houari, Mohamed Sid Ahmed;Tounsi, Abdelouahed;Merzouki, Tarek
    • Computers and Concrete
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    • 제26권2호
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    • pp.137-150
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    • 2020
  • In this paper, the bending behavior of single-walled carbon nanotube-reinforced composite (CNTRC) laminated plates is studied using various shear deformation plate theories. Several types of reinforcement material distributions, a uniform distribution (UD) and three functionally graded distributions (FG), are inspected. A generalized higher-order deformation plate theory is utilized to derive the field equations of the CNTRC laminated plates where an analytical technique based on Navier's series is utilized to solve the static problem for simply-supported boundary conditions. A detailed numerical analysis is carried out to examine the influence of carbon nanotube volume fraction, laminated composite structure, side-to-thickness, and aspect ratios on stresses and deflection of the CNTRC laminated plates.

Comparison of Mechanical Properties between Carbon/PEEK Composites and Ti Stem for Optimal Design

  • Yoon, Sung-Won;Kim, Yun-Hae;Jung, Min-Kyo;Murakami, Ri-Ichi
    • International Journal of Ocean System Engineering
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    • 제3권3호
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    • pp.152-157
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    • 2013
  • This study, a new concept design of the stem and aims to determine the suitability of various carbon/PEEK composite designs for artificial hip joints. Shear stress tested with alternative materials of the Ti-based stem for artificial hip joints. In addition, FEA is conducted according to the fiber ply orientation and the load condition for carbon/PEEK composites. The stem shape of two types was designed through the shape normal of the femur. Multidirectional load cases were used for each FEA model. In the case of general shape, the results show that the stress of ply orientation case II was lower than for cases I and III. On the other hand, in the case of the curved shape, ply orientation case I was lowest. In the case of the Ti stem, the stress of the curved shape was 18% lower than the general shape.

Partially Carbonized Poly (Acrylic Acid) Grafted to Carboxymethyl Cellulose as an Advanced Binder for Si Anode in Li-ion Batteries

  • Cho, Hyunwoo;Kim, Kyungsu;Park, Cheol-Min;Jeong, Goojin
    • Journal of Electrochemical Science and Technology
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    • 제10권2호
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    • pp.131-138
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    • 2019
  • To improve the performance of Si anodes in advanced Li-ion batteries, the design of the electrode plays a critical role, especially due to the large volumetric expansion in the Si anode during Li insertion. In our study, we used a simple fabrication method to prepare Si-based electrodes by grafting polyacrylic acid (PAA) to a carboxymethyl cellulose (CMC) binder (CMC-g-PAA). The procedure consists of first mixing nano-sized Si and the binders (CMC and PAA), and then coating the slurry on a Cu foil. The carbon network was formed via carbonization of the binders i.e., by a simple heat treatment of the electrode. The carbon network in the electrode is mechanically and electrically robust, which leads to higher electrical conductivity and better mechanical property. This explains its long cycle performance without the addition of a conducting agent (for example, carbon). Therefore, the partially carbonized CMC-g-PAA binder presented in this study represents a new feasible approach to produce Si anodes for use in advanced Li-ion batteries.

활성백토를 흡착재로 활용한 경화체의 실내 공기 개선 평가 (Evaluation of Indoor Air Improvement of Matrix Using Activated clay as Adsorption Material)

  • 정현수;김연호;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 봄 학술논문 발표대회
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    • pp.189-190
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    • 2020
  • The importance of indoor air quality management has recently been highlighted due to environmental problems such as indoor air pollution. Among indoor air pollutants, carbon dioxide occurs in cooking, heating, burning, and causes forgetfulness, dementia and amnesia. Radon, which occurs in building materials, soil and ground, is a type 1 carcinogen that causes lung cancer in the body through breathing. These substances can be released from the room through ventilation, but there is a limit to reducing the amount of indoor activity due to reduced ventilation conditions due to increased indoor activity time. However, these substances can be removed from the gas by adsorption. The purpose of this study was to identify the properties of granular active and powdered active white soil and mix them to make cement-based active white soil adsorbent matrix for carbon dioxide, fine dust and radon gas adsorption, and to evaluate indoor air improvements according to the mixing scale. The results of the experiment showed that active carbon dioxide adsorption performance increased for carbon dioxide and radon as the exchange rate increased through physical adsorption. In particular, the higher the replacement rate of the granular active bag, the better adsorption performance was shown.

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탄소섬유/에폭시 복합재료의 층간파괴인성에 미치는 균열진전각도의 영향 (Effect of Crack Propagation Directions on the Interlaminar Fracture Toughness of Carbon/Epoxy Composite Materials)

  • 황진호;황운봉
    • 대한기계학회논문집A
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    • 제23권6호
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    • pp.1026-1038
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    • 1999
  • Interlaminar fracture toughness of carbon/epoxy composite materials has been studied under tensile and flexural loading by the use of width tapered double cantilever beam(WTDCB) and end notched flexure(ENF) specimens. This study has significantly examined the effect of various interfacial ply orientation, ${\alpha}(0^{\circ},\;45^{\circ}\;and\;90^{\circ})$ and crack propagation direction, ${\theta}(0^{\circ},\;15^{\circ},\;30^{\circ}\;and\;45^{\circ})$ in terms of critical strain energy release rate through experiments. Twelve differently layered laminates were investigated. The data reduction for evaluating the fracture energy is based on compliance method and beam theory. Beam theory is used to analyze the effect of crack propagation direction. The geometry and lay-up sequence of specimens are considered various conditions such as skewness parameter, beam volume, and so on. The results show that the fiber bridging occurred due to the non-midplane crack propagation and causes the difference of fracture energy evaluated by both methods. For safer and more reliable composite structures, we obtain the optimal stacking sequence from initial fracture energy in each mode.

Selective Removal of Al(III) from Rare Earth Solutions Using Peas-based Activated Carbon

  • An, Fu-Qiang;Wu, Rui-Yan;Li, Min;Yuan, Zhi-Guo;Hu, Tuo-Ping;Gao, Jian-Feng
    • 대한화학회지
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    • 제61권5호
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    • pp.231-237
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    • 2017
  • Efficiently removing Al(III) from rare earth is very significant because even trace amount of Al(III) can cause serious harm to the rare earth materials. In this paper, a nitrogen-containing activated carbon, AC-P700, was synthesized using peas as raw materials. The AC-P700 was characterized by surface area analyzer, FT-IR, and XPS methods. The adsorption and recognition properties of AC-P700 towards Al(III) were investigated, and the recognition mechanism was also analyzed. The BET special surface area of AC-P700 was $1277.1m^2{\cdot}g^{-1}$, and the average pore diameter was 1.90 nm. The AC-P700 possesses strong adsorption affinity and excellent recognition selectivity towards Al(III). The adsorption capacity for Al(III) could reach to $0.53mmol{\cdot}g^{-1}$, and relative selectivity coefficients relative to La(III) and Ce(III) is 9.6 and 8.7, respectively. Besides, AC-P700 possesses better regeneration ability and reusability.

카드뮴 셀레나이드 양자점과 단일벽 탄소나노튜브로 구성된 이종 나노 소재를 기반으로 한 광전소자의 제작 및 특성평가 (Fabrication and characterization of optoelectronic device using CdSe nanocrystal quantum dots/single-walled carbon nanotubes)

  • 심형철;정소희;한창수;김수현
    • 센서학회지
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    • 제19권2호
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    • pp.160-167
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    • 2010
  • In this paper, we fabricated the optoelectronic device based on Cadmium selenide(CdSe) nanocrystal quantum dots (NQDs)/single-walled carbon nanotubes(SWNTs) heterostructure using dieletrophoretic force. The efficient charge transfer phenomena from CdSe to SWNT make CdSe-Pyridine(py)-SWNT unique heterostructures for novel optoelectronic device. The conductivity of CdSe-py-SWNT was increased when it was exposed at ultra violet(UV) lamp, and varied as a function of wavelength of incident light.

수평형 CVD 장치에서 기판 위치에 따른 단일벽 탄소나노튜브의 합성 수율 및 직경 분포 고찰 (Investigation of Synthesis Yield and Diameter Distribution of Single-Walled Carbon Nanotubes Grown at Different Positions in a Horizontal CVD Chamber)

  • 조성일;정구환
    • 한국표면공학회지
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    • 제52권6호
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    • pp.357-363
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    • 2019
  • We investigated a synthesis yield and diameter distribution of single-walled carbon nanotubes (SWNTs) with respect to the growth position in a horizontal chemical vapor deposition (CVD) chamber. Thin films and line-patterned Fe films (0.1 nm thickness) were prepared onto ST-cut quartz substrates as catalyst to compare the growth behavior. The line-patterned samples showed higher growth density and parallel alignment than those of the thin film catalyst samples. In addition, line density of the aligned SWNTs at central region of the chamber was 7.7 tubes/㎛ and increased to 13.9 tubes/㎛ at rear region of the CVD chamber. We expect that the enhanced amount of thermally decomposed feedstock gas may contribute to the growth yield enhancement at the rear region. In addition, the lamina flow in the chamber also contribute to the perfect alignment of the SWNTs based on the value of gas velocity, Reynold number, and Knudsen coefficient we employed.