• 한국신재생에너지학회:학술대회논문집
• /
• 2006.11a
• /
• pp.316-319
• /
• 2006

There is a worldwide interest in the development and commercialization of Polymer Electrolyte Membrane Fuel Cells (PEMFCs) for vehicular and stationary applications. One of the major objectives is the reduction of loaded electrode materials, which is comprise of the Pt-based noble metals. In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the deposition of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled active materials were formed on the surface of carbon-supported Au nanoparticles. The structural and electrochemical analyses indicate that the active materials were deposited on the surface of Au nanoparticles selectively and that an at toying process occurred during the successive reducing process The carbon-supported & surface-alloys showed the higher electrocatalytic activity than those of the particle-alloys and commercial one (Johnson-Matthey) for the reaction of methanol and formic acid oxidation. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

• Journal of the Korean Ceramic Society
• /
• v.42 no.7 s.278
• /
• pp.469-474
• /
• 2005

Activated Carbon Fibers (ACFs) are widely used as adsorbents in technologies related to pollution abatement due to their highly porous structure and large adsorption capacity. The porous structure and surface area of ACFs depends strongly on both the activation processes arid the nature .of the precursors. The chemical activation with hydroxides has recently been, of great interest as it permits the preparation of activated carbon fibers with highly developed porosity. In this work, OXI-PAN fiber used as precursor for the preparation of activated carbon fibers by chemical activation with KOH and NaOH. The affects of several activation conditions on the surface properties, pore size distribution and adsorption capacity of Ag ion and Iodine ion on ACFs studied.

• New & Renewable Energy
• /
• v.2 no.4 s.8
• /
• pp.64-69
• /
• 2006

There is a worldwide interest in the development and commercialization of polymer electrolyte membrane fuel cells [PEMFCs] for vehicular and stationary applications. One of the major objectives is the reduction of loaded electrode materials, which is comprise of the Pt-based noble metals. In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the supporting of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled active materials were formed on the surface of carbon-supported Au nanoparticles. The structural and electrochemical analyses indicate that the active materials were deposited on the surface of Au nanoparticles selectively and that an alloying process occurred during the successive reducing process. The carbon-supported & surface-alloys showed the higher electrocatalytic activity than those of the particle-alloys and commercial one [Johnson-Matthey] for the reaction of methanol and formic acid oxidation. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

• Journal of Electrochemical Science and Technology
• /
• v.9 no.4
• /
• pp.251-259
• /
• 2018

In general, the charge storage characteristics and overall performance of electrochemical energy devices (such as lithiumion batteries and supercapacitors) significantly depends on the structural and geometrical factors of the electrodes' active materials. The most widely used active materials of electrochemical energy storage devices are based on carbons of various forms. Each carbon type has drawbacks and advantages when used as the electrode material. Studies have been recently carried out to combine different types of carbons, in particular nanostructured carbons, in order to overcome the structure-originated limitations and thus enhance the overall electrochemical performances. In this feature article, we report the recent progress on the development of this novel class of materials (multidimensional nanocarbons), and their applications for supercapacitors. Multidimensional nanocarbons include graphenes/carbon nanotubes (CNTs), CNTs/carbon films, CNTs/fullerenes, and ternary carbon nanostructures. Various applications using these multidimensional nanocarbons have been proposed and demonstrated in the literature. Owing to the recent extensive studies on electrochemical energy storage devices and considering that carbons are their most fundamental electrode materials, the number of reports on nanocarbons employed as electrodes of the electrochemical energy storage devices is rapidly increasing. Recently, numerous multidimensional nanocarbons have been designed, prepared, and utilized as electrodes of electrochemical capacitors or supercapacitors, which are considered next-generation energy devices owing to their unique merits compared to the conventional structures. In this review, we summarize the basic motivations, preparation methods, and resultant supercapacitor performances of each class of multidimensional nanocarbons published in the literature, focusing on recent reports.

• Proceedings of the KIEE Conference
• /
• 1997.07d
• /
• pp.1606-1608
• /
• 1997

We have synthesized PPP from benzen by chemical reaction. And then disordered carbon materials were obtained by heating-treating PPP in a nitrogen atmosphere for 1, 4, 8 and 12 hour at $700^{\circ}C$. The carbon prepared by heat treatment showed a broad x-ray diffraction peak around $2{\theta}=20^{\circ}$ having a property of disordered carbon. Carbon electrodes were charged and discharged at a current density of $0.25mA/cm^2$. In the result, PPP-based carbon obtained at $700^{\circ}C$ for 8h showed 605mAh/g of first discharge capacity and had a small hysteresis characteristic.

• Tribology and Lubricants
• /
• v.33 no.6
• /
• pp.245-250
• /
• 2017

In this work, we examine pure water and water with nanoparticles to investigate water lubrication characteristics and the effect of nanoparticles as lubricant additives for different substrates. We test carbon-based coatings and metals such as high-speed steel and stainless steel in pure deionized (DI) water and DI water with nanoparticles. We investigate water lubrication characteristics and the effect of nanoparticles based on the friction coefficient and wear rate for different substrates. The investigation reveals that nanoparticles enhance the friction and wear properties of high-speed steel and stainless steel. The friction coefficient and wear rate of both high-speed steel and stainless steel decreases in DI water with nanoparticles compared with the results in pure DI water. The presence of nanoparticles in water show good lubricating effect at the contact area for both high-speed steel and stainless steel. However, for carbon-based coatings, nanoparticles do not improve friction and wear properties. Rather, the friction coefficient and wear rate increases with an increase in the concentration of nanoparticles in case of water lubrication. Because carbon-based coatings already have good tribological properties in a water environment, nanoparticles in water do not contribute toward improving the friction and wear properties of carbon-based coatings.

• Journal of Powder Materials
• /
• v.29 no.4
• /
• pp.297-302
• /
• 2022

This study compares the characteristics of a compact TiO₂ (c-TiO₂) powdery film, which is used as the electron transport layer (ETL) of perovskite solar cells, based on the manufacturing method. Additionally, its efficiency is measured by applying it to a carbon electrode solar cell. Spin-coating and spray methods are compared, and spray-based c-TiO₂ exhibits superior optical properties. Furthermore, surface analysis by scanning electron microscopy (SEM) and atomic force microscopy (AFM) exhibits the excellent surface properties of spray-based TiO₂. The photoelectric conversion efficiency (PCE) is 14.31% when applied to planar perovskite solar cells based on metal electrodes. Finally, carbon nanotube (CNT) film electrode-based solar cells exhibits a 76% PCE compared with that of metal electrode-based solar cells, providing the possibility of commercialization.

• Journal of Powder Materials
• /
• v.23 no.4
• /
• pp.317-324
• /
• 2016

Tin is one of the most promising anode materials for next-generation lithium-ion batteries with a high energy density. However, the commercialization of tin-based anodes is still hindered due to the large volume change (over 260%) upon lithiation/delithiation cycling. To solve the problem, many efforts have been focused on enhancing structural stability of tin particles in electrodes. In this work, we synthesize tin nano-powders with an amorphous carbon layer on the surface and surroundings of the powder by electrical wire explosion in alcohol-based liquid media at room temperature. The morphology and microstructures of the powders are characterized by scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and transmission electron microscopy. The electrochemical properties of the powder for use as an anode material for lithium-ion battery are evaluated by cyclic voltammetry and a galvanometric discharge-charge method. It is shown that the carbon-coated tin nano-powders prepared in hexanol media exhibit a high initial charge specific capacity of 902 mAh/g and a high capacity retention of 89% after 50 cycles.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2009.05a
• /
• pp.5.2-5.2
• /
• 2009

Carbon based nanoelctronic materials such as buckyball, CNT, and graphene have been active field of research because of their superior electronic prperties and potential application to flexible electronics. Still the difficulty of fabrication and spatial control prevent them from practical applications. Here I introduce a novel growth method of CNTs, known as surface assisted growth, that can answer the challenge. Various device examples from as-grown CNTs will prove the importance of this method for future nanoelectronics.

• Advances in nano research
• /
• v.14 no.5
• /
• pp.443-450
• /
• 2023

Carbon nanotubes (CNTs) have received increased interest in reinforcing research for polymer matrix composites due to their exceptional mechanical characteristics. Its high surface area/volume ratio and aspect ratio enable polymer-based composites to make the most of its features. This study focuses on the experimental tensile testing and fabrication of carbon nanotube reinforced composite (CNTRC) beams, exploring various micromechanical models. By examining the performance of these models alongside experimental results, the research aims to better understand and optimize the mechanical properties of CNTRC materials. Tensile properties of neat epoxy and 0.3%; 0.4% and 0.5% by CNT reinforced laminated single layer (0°/90°) carbon fiber composite beams were investigated. The composite plates were produced in accordance with ASTM D7264 standard. The tensile test was performed in order to see the mechanical properties of the composite beams. The results showed that the optimum amount of CNT was 0.3% based on the tensile capacity. The capacity was significantly reduced when 0.4% CNT was utilized. Moreover, the experimental results are compared with Finite Element Models using ABAQUS. Hashin Failure Criteria was utilized to predict the tensile capacity. Good conformance was observed between experimental and numerical models. More importantly is that Young' Moduli of the specimens is compared with the prediction Halpin-Tsai and Mixture-Rule. Although Halpin-Tsai can accurately predict the Young's Moduli of the specimens, the accuracy of Mixture-Rule was significantly low.