• Clean Technology
• /
• v.19 no.1
• /
• pp.44-50
• /
• 2013

Tin-based materials for lithium ion battery have been proposed as new anode candidates owing to their higher specific capacity and relatively high lithium insertion potential. Tin-based materials have been extensively studied as possible replacements for carbon anodes in lithium ion batteries. However, the large volume expansion results in severe particle cracking with loss of electrical contact, giving irreversible capacity losses which prevent the widespread use of tin-based materials in lithium batteries. So remaining studies of tin-based materials are alleviating volume expansion and improving cycle performance. In this work, $SnO_2-SiO_2$ composites were manufactured with sol-gel method to overcome their volume expansion. Carbon was coated with 10 vol% propylene gas. The characteristics of active material and the effect of heat treatment were investigated with TG/DTA, XRD, SEM and FT-IR. Electrochemical characteristics of these composites were measured with CR2032 type coin cells. Carbon coated $SnO_2-SiO_2$at $300^{\circ}C$ heat treatment showed the best electrochemical performance.

• Carbon letters
• /
• v.9 no.2
• /
• pp.121-126
• /
• 2008

High modulus pitch based carbon fibers (HM) were exposed to isothermal oxidation using tube furnace in carbon dioxide gas to study the oxidation kinetics under the temperature of $800-1100^{\circ}C$. The kinetic equation $f=1-{\exp}(-at^b)$ was introduced and the constant b was obtained in the range of 1.02~1.42. The oxidation kinetics were evaluated by the reaction-controlling regime (RCR) depending upon the apparent activation energies with the conversion increasing from 0.2 to 0.8. The activation energies decrease from 24.7 to 21.0 kcal/mole with the conversion increasing from 0.2 to 0.8, respectively. According to the RCR, the reaction was limited by more diffusion controlling regime for the HM fibers with the conversion increasing. Therefore, it seems that the oxidation which is under the diffusion controlling regime takes place continuously from the skin to the core of the fiber.

• Carbon letters
• /
• v.16 no.1
• /
• pp.62-66
• /
• 2015

In this study, carbonized fibers were prepared by using acidically cross-linked LDPE fibers. The surface morphologies of the carbonized fibers were observed by SEM. The effects of cross-linking process temperatures were studied using thermal analyses such as DSC and TGA. The melting and heating enthalpy of the fibers decreased as the cross-linking temperature increased. The cross-linked fibers had a carbonization yield of over 50%. From SEM results the highest yield of carbonized LDPE-based fibers was obtained by cross-linking at a sulfate temperature ($170^{\circ}C$). As a result, carbonation yield of the carbonized fibers was found to depend on the functions of the cross-linking ratio of the LDPE precursors.

• Carbon letters
• /
• v.6 no.1
• /
• pp.1-5
• /
• 2005

Isotropic pitch based carbon fibers were exposed to isothermal oxidation in carbon dioxide gas to study the activation kinetics under the temperature of 800~$1100^{\circ}C$. The kinetic equation $f=1-{\exp}(-at^b)$ was introduced and the constant b was obtained in the range of 0.92~1.25. It was shown that the activated carbon fiber shows the highly specific surface area (SSA) when the constant b comes close to 1. The activation kinetics were evaluated by the reaction-controlling regime (RCR) according to changes of the apparent activation energy with changes of the conversion. It was observed that the activation energies increase from 47.6 to 51.2 kcal/mole with the conversion increasing from 0.2 to 0.8. It was found that the pores of the activated carbon fiber under the chemical reaction were developed well through the fiber.

• Carbon letters
• /
• v.26
• /
• pp.1-10
• /
• 2018

Biochar obtained from the thermal conversion of biomass has high potential as a substitute material for activated carbon and other carbon-based materials because it is economical, environmentally friendly, and carbon-neutral. The physicochemical properties of biochar can also be controlled by a range of activation methods such as physical, chemical, and hydrothermal treatments. Activated biochar can be used as a catalyst for the catalytic pyrolysis of a biomass and as an absorbent for the removal of heavy metal ions and atmospheric pollutants. The applications of biochar are also expanding not only as a key component in producing energy storage materials, such as supercapacitors, lithium ion batteries, and fuel cells, but also in carbon capture and storage. This paper reviews the recent progress on the activation of biochar and its diverse present and future applications.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2005.04a
• /
• pp.90-93
• /
• 2005

A thermal model of carbon spun yarn and its composite is presented. Based on voxelization method, the unit cells of spun carbon yam and its composite are divided into a number of volume elements and the local material properties have been given to each element. By using Finite Difference Method, temperature distribution in the unit cell can be obtained. Effective thermal conductivity of unit cell is calculated using the temperature distribution and thermal conductivities of local elements.

• Carbon letters
• /
• v.4 no.3
• /
• pp.140-145
• /
• 2003

Antibacterial behaviors of PAN-based activated carbon fibers (ACFs) containing silver metal were investigated. The effects of surface and pore structures of the ACFs were studied by $N_2$/77 K adsorption and D-R plot as a function of silver loading content. The antibacterial activities were investigated by a dilution test against Staphylococcus aureus (S. aureus; gram positive) and Klebsiella pnemoniae (K. pnumoniae; gram negative). As experimental results, the ACFs showed some decreases in specific surface areas, micropore volumes, and total pore volume with an increase of silver content. However, the antibacterial activities of the ACFs were strongly increased against S. aureus as well as K. pnumoniae, which could be attributed to the presence of antibacterial metal in the ACFs system.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.20 no.5
• /
• pp.436-442
• /
• 2007

Physical properties and impedance-humidity characteristics of carbon nitride films were investigated for micro-humidity-sensors. Carbon nitride films were deposited in low temperature and low power for application of semiconductor fabrication process, and empirical equation was proposed for thickness evaluation. Deposited films had an uniform and compact surface comparing with previously reported results, which was expected a good candidate for humidity sensing materials. Carbon nitride humidity sensors based on Si substrate revealed good humidity-impedance characteristics with a wide range of relative humidity and showed low hysteresis.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.02a
• /
• pp.529-529
• /
• 2012

Dispersion of carbon nanotubes in biocompatible media are of particular interest for diverse biomedical and nanomedicine applications. Various biomolecules and biopolymers such as DNA, proteins, poly L-lysine, starch, gelatin, steroid biosurfactants, and chitosan have shown capability for the effective dispersion of carbon nanotubes in water. Chitosan has demonstrated capacity for effective dispersion of single-walled carbon nanotubes (SWCNTs) in acidic medium and it also showed tendency to preferentially disperse smaller diameter nanotubes. Chemical functionalizations of chitosan enable its solubility in neutral pH water by reducing the intra and inter molecular hydrogen bonding. Herein, we present a neutral pH water soluble chitosan derivative, chitosan-hydroxyphenyl acetamide (CHPA), obtained by functionalizing the amino groups of chitosan with 4-hydroxyphenyl acetic acid, as an efficient biocompatible dispersant for debundling and solubilization of SWNTs in neutral aqueous solutions. Various process conditions for individual dispersion of SWCNTs are analyzed based on optical absorption and Raman spectroscopy.

• Applied Microscopy
• /
• v.50
• /
• pp.4.1-4.10
• /
• 2020

Metallic matrix composites reinforced with carbon nanomaterials continue to attract interest because of their excellent mechanical, thermal, and electrical properties. However, two critical issues have limited their commercialization. Uniform distribution of carbon nanomaterials in metallic matrices is difficult, and the interfaces between the nanomaterials and matrices are weak. Microscope-based analysis was recently used to quantitatively examine these microstructural features and investigate their contributions to the composites' mechanical, thermal, and electrical properties. The impacts of the microstructure on these properties are discussed in the first section of this review. In the second section, the various microscopic techniques used to study the distribution of carbon nanomaterials in metallic matrices and their interfaces are described.