• Title/Summary/Keyword: Calcium sulfate

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The Effects of Desulfurization by Screen using Ca-based Absorbent in a Solid Waste Fluidized-bed Combustor (유동층연소로에서 제지공장 폐기물을 이용한 황산화물 제어시 스크린에 의한 탈황효과)

  • 조상원;이재홍;조기철;장상용;오광중
    • Journal of Environmental Science International
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    • v.7 no.6
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    • pp.783-791
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    • 1998
  • The objectives of this study were to investigate the characteristics of desulfurization under different experimental conditions and the effects of desulfurization bed fluidized bed combuster installed with the screen. The experimental results were as follows ; First, as the height of fluidized bed combustor becomes higher, the concentrations of $SO_2$ mainly increased and sulfur retion of paper sludge was higher than that of natural limestone. Second, the desulfurzation by natural limestone occurred at in-bed and the desulfurization by paper sludge occurred in the whole of fluidized bed combuster. In addition, we identified calcium sulfate by the analysis of SEM and XRD. Third, screen at splash region increased sulfur retention 2~5%, air velocity and anthracite fraction had a little effect on the sulfur retention.

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Characterization of Individual Atmospheric Particles, Collected in Susan, Korea, Using Low-Z Electron Probe X-ray Microanalysis (Low-Z Electron Probe X-ray Microanalysis 분석법을 이용한 해안인근 지역의 대기입자 분석)

  • 김혜경;노철언
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.5
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    • pp.503-513
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    • 2003
  • A single particle analytical technique, called low-Z electron probe X-ray microanalysis (low-Z EPMA) was applied to characterize atmospheric particles collected in Busan, Korea, over a daytime period in Dec. 2001. The ability to quantitatively analyze the low-Z elements, such as C, N, and 0, in microscopic volume enables the low-Z EPMA to specify the chemical composition of individual atmospheric particle. Various types of atmospheric particles such as organics, carbon-rich, aluminosilicates, silicon oxide, calcium carbonate, iron oxide, sodium chloride, sodium nitrate, ammonium sulfate, and titanium oxide were identified. In the sample collected in Busan, sodium nitrate particles produced as a result of the reaction between sea salt and nitrogen oxides in the atmosphere were most abundantly encountered both in the coarse and fine fractions. On the contrary, original sea salt particles were rarely observed. The fact that most of the carbonaceous particles were distributed in the fine fraction implies that their origin is anthropogenic.

Synthesis and Characteristics of Magnesium Hydroxide Group Flame Retardant for Polymer Addtives (고분자 첨가제인 난연제로서의 수산화마그네슘계 물질의 합성과 특성)

  • Lee, Dong-Kyu;Kang, Kuk-Hyoun;Lee, Jin-Hwa
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.4
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    • pp.385-393
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    • 2009
  • Different types magnesium hydroxide groups have been obtained using the hydrothermal precipitation technique from magnesium sulfate and calcium carbonate solution. The Mg atom coordinated around O atom of ${SO_4}^{2-}$ in another layer to form a multi-layer structure crystal. The influence of synthesis parameters on the morphological characteristics and size of magnesium hydroxide groups precipitated in aqueous were investigated such as different of additive and pH. Magnesium hydroxide groups were decomposed gradually and converted finally to MgO particles after heated in air temperature up to $1050^{\circ}C$. The particle size and it's distribution morphology, crystal phase and thermal behavior of the samples were characterized through XRD, SEM, EDS, and TG/DTA.

Studies on $\beta$-Amylase of Radish (Radish $\beta$-amylase에 관한 연구)

  • 우원식
    • YAKHAK HOEJI
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    • v.6 no.2
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    • pp.18-22
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    • 1962
  • Purified preparation of .betha.-amylase is obtained from radish root by the means of fractional precipitation with ammonium sulfate. Purified preparation saccharifies the starch, .betha.-maltose being formed. Dextrinization in the true sense does not take place. Hydrolysis ceases when approximately 50% of the theoretical yield of maltose is obtained and there remains a substance (to be .betha.-limit dextrin) which gives a blue-violet with iodine, no glucose being formed. Stability of preparation is optimal at pH 4-9 and more completely inactivated at 65.deg. in fifteen minutes. .betha.-Amylase of radish exhibits optimal activity at and near pH 5.0, which varied depending upon the buffer. Calcium and chloride ions do not effect the activities of enzyme. The results of experiments with oxidizing, alkylating and mercaptide-forming reagents which have been reported to be specific for sulfhydryl groups confirm that free sulfhydryl groups are essential to the activity of .betha.-amylase from radish.

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Effect of Salt on the Formation of $\alpha$-Calcium Sulfate Hemihydrate from by-Product Gypsum of Phosphoric Acid Process in Aqueous Salt Solution at Atmospheric Pressure (상압수용액중에서 인산석고로부터 $\alpha$형 반수석고의 생성에 미치는 염류의 영향)

  • 이구종;최상흘
    • Journal of the Korean Ceramic Society
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    • v.25 no.1
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    • pp.66-72
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    • 1988
  • The effect of salts on the formation of ${\alpha}$-hemihydrated gypsum at boiling temperature under atmospheric pressure was studied by the solubility measurement method, and the formation of ${\alpha}$-hemihydrated gypsum from by-product gypsum of phosphoric acid process in the salts solution were investigated. The order of catalytic effect of salt on the formation of ${\alpha}$-hemihydrated gypsum are as follows: NH4Cl>NaCl>NaNO3. In the salts solution of sodium nitrate, sodium chloride, and ammonium chloride, prismatic ${\alpha}$-hemihydrated gypsum was obtained and the crystal form was converted to needle form in complex solution with sulfuric acid. The P2O5 content in gypsum was largely decreased in this atmosphoric solution process.

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Removal Characteristics of Strontium and Cesium tons by Zeolite Synthesized from Fly Ash (석탄회로 합성한 제올라이트에 의한 Sr(II) 및 Cs(I) 이온의 제거 특성)

  • 감상규;이동환;문명준;이민규
    • Journal of Environmental Science International
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    • v.12 no.10
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    • pp.1061-1069
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    • 2003
  • The adsorption behaviors of strontium and cesium ions on fly ash, natural zeolites, and zeolites synthesized from fly ash were investigated. The zeolites synthesized from fly ash had greater adsorption capabilities for strontium and cesium ions than the original fly ash and natural zeolites. The maximum adsorption capacity of synthetic zeolite for strontium and cesium ions was 100 and 154 mg/g, respectively, It was found that the Freundlich isotherm model could fit the adsorption isotherm. The distribution coefficients (K$\_$d/) for strontium and cesium ions were also calculated from the adsorption isotherm data, The distribution coefficients decreased with increasing equilibrium concentration of strontium and cesium ions in solution. By studying the removal of cesium and strontium ions in the presence of calcium, magnesium, sodium, potassium, sulfate, nitrate, nitrite, and EDTA (in the range of 0.01 - 5 mM) it was found that these coexistence ions competed for the same adsorption sites with strontium and cesium ions.

Clinical application and classification of bone graft material according to component (임상가를 위한 특집 2 - 구성성분별 골이식재의 분류와 임상적용)

  • Kim, Young-Kyun
    • The Journal of the Korean dental association
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    • v.48 no.4
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    • pp.263-274
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    • 2010
  • I classified the bone graft material according to the component. Most bone graft material is composed of inorganic and organic constituent. Organic component such DBM is associated with osteoinduction. Inorganic components such as hydroxyapatite, $\beta$-TCP, calcium sulfate, bioactive glass, polymer are associated with osteoconduction. Autogenous bone graft is ideal material. We can select any biocompatible material for the restoration of small filling defect with intact bony wall. However, we should select first osteogenetic and osteoinductive material to regenerate the viable bone tissue.

IMPLANTATION OF TOOTHASH COMBINED WITH PLASTER OF PARIS;CLINICAL APPLICATIONS (치아회분말과 치과용 연석고의 혼합매식술;임상적 적용)

  • Kim, Young-Kyun;Yeo, Hwan-Ho
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.16 no.2
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    • pp.130-136
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    • 1994
  • Toothash and plaster of Paris (Calcium sulfate) have been studied for bone substitute through experimental studies and clinical studies. Toothash is like resorbable hydroxyapatite. Plaster of Paris is resorbable and biocompatible. The toothash combined with plaster of Paris has the advantages of individual characteristics. The authors used this composite material in the jaw defect filling. In operation, we could manage this implant material easily and remove the dead space. During the followup period, this composite material was resorbed gradually and substituted as new-forming bone from the surrounding tissue. Complications were minor and treated completely without problems.

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Characterization of BmaI endonuclease from bacillus macerans ATCC 8244 (Bacillus macerans의 BmaI endonuclease의 특성에 대한 연구)

  • 권용태;전희숙;노현모
    • Korean Journal of Microbiology
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    • v.26 no.1
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    • pp.1-5
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    • 1988
  • The esolation and characterization of a new type II restriction endounclease, BamI, from Bacellus macerans ATCC 8244 were described. BmaI endonuclease was partially purified by procedures of ammonium sulfate fractionation, DEAE-cellulose and phosphocellulose chromatographies. This enzume recognized one site on pBR322 DNA, two sites on Bluescribe DNA, three sites on $\lambda$DNA and no site on SV 40 DNA. The same cleavage patterns for vareius DNAs as PvuI indicated that BamI is an isoschisomer of PvuI whose recognition sequence is 5'-CGATCG-3'. The optimal pH for the BmaI endonuclease activity was about 7.0 and optimal NaCl concentration was about 100mM. Manganese ion could partially replace magnesium as a cofactor, but calcium could not at all.

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Characterization of a Thermostable Protease from Thermophilic Bacillus amyloliquefaciens NS 15-4 (고온성 Bacillus amyloliquefaciens NS 15-4가 생산하는 내열성 Protease의 특성)

  • Kim, Hyung-Kwoun;Kim, Kee-Hyun;Lee, Jung-Kee;Kim, Young-Ok;Nam, Hee-Sop;Oh, Tae Kwang
    • Microbiology and Biotechnology Letters
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    • v.23 no.3
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    • pp.322-328
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    • 1995
  • A thermophilic bacteria showing proteolytic activity against defatted soybean was isolated from soil. It was identified as Bacillus amyloliquefaciens based on its morphological and physiological characteristics. The Bacillus amyloliquefaciens NS 15-4 was cultivated at 50$\circ$C by rotary shaking in a medium containing defatted soybean. An extracellular protease from this strain was purified to homogeneity by ammonium sulfate precipitation, ion exchange, and hydrophobic interaction chromatographies. The molecular weight of the enzyme was estimated to be approximately 30,000 by SDS-PAGE and the N-terminal amino acid sequence of the enzyme was turned out to be AQSVPYGISQIKAPA. The optimum temperature and pH for the enzyme reaction were 60$\circ$C and 11, respectively, and its thermostability was increased by the addition of calcium ion. The enzyme was inactivated by phenylmethylsulfonylfluoride, suggesting it be a serine protease. Comparing with other commercial proteases, the enzyme showed relatively high proteolytic activity against defatted soybean, a water-insoluble protein substrate.

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