DOI QR코드

DOI QR Code

Removal Characteristics of Strontium and Cesium tons by Zeolite Synthesized from Fly Ash

석탄회로 합성한 제올라이트에 의한 Sr(II) 및 Cs(I) 이온의 제거 특성

  • Published : 2003.10.01

Abstract

The adsorption behaviors of strontium and cesium ions on fly ash, natural zeolites, and zeolites synthesized from fly ash were investigated. The zeolites synthesized from fly ash had greater adsorption capabilities for strontium and cesium ions than the original fly ash and natural zeolites. The maximum adsorption capacity of synthetic zeolite for strontium and cesium ions was 100 and 154 mg/g, respectively, It was found that the Freundlich isotherm model could fit the adsorption isotherm. The distribution coefficients (K$\_$d/) for strontium and cesium ions were also calculated from the adsorption isotherm data, The distribution coefficients decreased with increasing equilibrium concentration of strontium and cesium ions in solution. By studying the removal of cesium and strontium ions in the presence of calcium, magnesium, sodium, potassium, sulfate, nitrate, nitrite, and EDTA (in the range of 0.01 - 5 mM) it was found that these coexistence ions competed for the same adsorption sites with strontium and cesium ions.

Keywords

References

  1. Nollet, H., P. Lutgen and W. Verstraete, 2002, Chemical removal of PCBs from water samples under ambient conditions, J Chem. Technol. Biotechnol., 77, 517-524 https://doi.org/10.1002/jctb.608
  2. Bayat, B., 2002, Comparative study of adsorption properties of Turkish fly ashes: I. The case of nickel(II), copper(II) and zinc(II), J. of Hazard. Mat., 95(3), 251-273 https://doi.org/10.1016/S0304-3894(02)00140-1
  3. Ricou-Hoer, P., I. Lecuyer and P. Le Cloirec, 2001, Experimental design methodology applied to adsorption of metallic ions onto fly ash, Water Res. 35, 965-976 https://doi.org/10.1016/S0043-1354(00)00341-9
  4. Kao, P. C., J. H. Tzeng and T. L. Huang, 2000, Removal of chlorophenols from aqueous solution by fly ash, J. Hazard. Mat., 79, 237-249
  5. Gupta, G. and N. Torres, 1998, Use of fly ash in reducing toxicity of and heavy metals in wastewater effluent, J. of Hazard. Mat., 57, 243-248 https://doi.org/10.1016/S0304-3894(97)00093-9
  6. Albanis, T. A, T. G. Danis and M. G. Kourgia, 1998, Adsorption-desorption studies of selected chlorophenols and herbicides and metal release in soil mixtures with fly ash, Environ. Technol., 19, 25-34 https://doi.org/10.1080/09593331908616652
  7. Ayala, J. F., B. Garcia, P. Rodriguez and J. Sancho, 1998, Asturian fly ash as a heavy metals removal material, Fuel., 77(11), 1147-1154 https://doi.org/10.1016/S0016-2361(98)00027-1
  8. Akgerman, A. and M. Zardkoohi, 1996, Adsorption of phenolic compounds on fly ash, J. Chem. Eng. Data 41, 185-187
  9. Banerjee, K., P. N. Cheremisino and S. L. Cheng, 1995, Sorption of organic contaminants by fly ash in a single solute system, Environ. Sci. Technol., 29, 2243-2251 https://doi.org/10.1021/es00009a014
  10. Querol, X., N. Moreno, J. C. Umana, A. Alastuey, E. Hernandez, A Lopez-Soler and F. Plana, 2002, Synthesis of zeolites from fly ash: an overview, Int. Jour. of Coal Geology, 50, 413-423 https://doi.org/10.1016/S0166-5162(02)00124-6
  11. Amrhein, C. A, G. H. Hagnia, T. S. Kim, P. A. Mosher, R. C. Gagajena, T. Amanios and L. de la Torre, 1996, Synthesis and properties of zeolites from coal fly ash, Environ. Sci. and Technol., 30, 735-742 https://doi.org/10.1021/es940482c
  12. Steenbruggen, G. and G. G. Hollman, 1998, The synthesis of zeolites from fly ash and the properties of the zeolite products, J. of Geochem. Explor., 62, 305-309 https://doi.org/10.1016/S0375-6742(97)00066-6
  13. Querol, X., F. Plana, A. Alastuey and A. Lopez-Soler, 1997, Synthesis of Na-zeolites from fly ash, Fuel., 76(8), 793-799 https://doi.org/10.1016/S0016-2361(96)00188-3
  14. Okada, Y., 1991, Synthesis of zeolite using fly ash on closed system, Jpn. J. Soil Sci. Plant Nutri., 62, 1-10
  15. Henmi, T., 1987, Increase in cation exchange capacity of coal fly ash by alkali treatment, Clay Sci., 6, 277-282
  16. Lee, M. G., G. Yi, B. J. Ahn and F. Roddick, 2000, Conversion of coal fly ash into zeolite and heavy metal removal characteristics of the products, Kor. J. Chem. Eng., 17(3), 325-331 https://doi.org/10.1007/BF02699048
  17. Kim, W. B., S. H. Jung and B. J. Ahn, 1997, Synthesis of Na-Pl zeolite from coal fly ash, J. Ind. Eng. Chem., 3(3), 185-190
  18. Roy, K., D. K. Pal, S. Basu, D. Nayak and S. Lahiri, 2002, Synthesis of a new ion exchanger, zirconium vanadate, and its application to the separation of barium and cesium radionuclides at tracer levels, Applied Radiation and Isotopes, 57(4), 471-474 https://doi.org/10.1016/S0969-8043(02)00136-7
  19. Moller, T., R. Harjula and J. Lehto, 2002, Ion exchange of $^{85}Sr$, $^{134}Cs$ and $^{57}Co$ in sodium titanosilicate and the effect of crystallinity on selectivity, Separation and Purification Technol., 28(1), 13-23 https://doi.org/10.1016/S1383-5866(02)00004-7
  20. Marageh, M. G., S. W. Husain and A. R. Khanchi, 1999, Selective sorption of radioactive cesium and strontium on stannic molybdophosphate ion exchanger, Applied Radiation and Isotopes, 50(3), 459-465 https://doi.org/10.1016/S0969-8043(98)00082-7
  21. Harjula, R. and J. Lehto, 1994, Industrial scale removal of cesium with hexacyanoferrate exchanger-process development, Nuclear Technol., 107, 271-278
  22. Mimura, H., F. Tachibana and K. Akiba, 1992, Ion-exchange selectivity for cesium in ferrierites, J. of Nuclear Sci. and Technol., 29(2), 184-186 https://doi.org/10.3327/jnst.29.184
  23. Abusafa, A. and H. Yucel, 2002, Removal of 137Cs from aqueous solutions using different cationic forms of a natural zeolite: clinoptilolite, Sepa. and Purif. Technol., 28(2), 103-116 https://doi.org/10.1016/S1383-5866(02)00042-4
  24. Faghihian, H., M. G. Marageh and H. Kazemian, 1999, The use of clinoptilolite and its sodium form for removal of radioactive cesium, and strontium from nuclear wastewater and $Pb^{2+}$, $Ni^{2+}$, $Cd^{2+}$, $Ba^{2+}$ from municipal wastewater, Applied Radiation and Isotopes, 50(4), 655-660 https://doi.org/10.1016/S0969-8043(98)00134-1
  25. Apak, R., G. Atun, K. Guclu, E. Tutem and G. Keskin, 1995, Sorptive removal of cesium-137 and strontium-90 from water by unconventional sorbents, I. Usage of bauxite wastes (red muds), J. of Nuclear Sci. and Technol., 32(0), 1008-1017 https://doi.org/10.3327/jnst.32.1008
  26. Nishi, T., M. Matsuda, K. Chino and M. Kikuchi, 1992, Reduction of cesium leachability from cementitous resin forms using natural acid clay and zeolite, Cement and Concrete Research, 22, 387-392 https://doi.org/10.1016/0008-8846(92)90080-F
  27. Mimura, H. and T. Kanno, 1985, Distribution and fixation of cesium and strontium in zeolite A and chabazite, J. of Nuclear Sci. and Technol., 22(4), 284-291 https://doi.org/10.3327/jnst.22.284
  28. Park, C. K., S. I. Woo, T. Tanaka and H. Kamiyama, 1992, Sorption and desorption behavior of $^{60}Co$, $^{85}Sr$, and $^{137}Cs$ in a porous tuff, J. of Nuclear Sci. and Technol., 29(2), 1181-1193
  29. Apak, R., G. Atun, K. Guclu and E. Tutem, 1996, Sorptive removal of cesium-137 and strontium-90 from water by unconventional sorbents, II. Usage of coal fly ash, J. of Nuclear Sci. and Technol., 33(5), 396-402 https://doi.org/10.3327/jnst.33.396
  30. Chang, H. L. and W. H. Shih, 1998, A general method for the conversion of fly ash into zeolite as ion exchangers for cesium, Ind. Eng. Chem. Res., 37, 71-78 https://doi.org/10.1021/ie970362o
  31. Kim, D. S. and J. W. Park, 1993, Removal of $Cs^+$ and $Sr^{2+}$ ions by natural zeolites, J. of Environ. Sci. Soc. 2(4), 347-356
  32. Lee, E. H., J. H. Yoo and H. S. Park, 1993, Ion exchange kinetics for Cs and Sr in a batch zeolite system, J. of Kor. Ind. and Eng. Chem., 4(4), 739-745
  33. Kam, S. K, D. S. Kim and M. G. Lee, 1999, Comparison of divalent heavy metal removal performances by domestic natural zeolites, J of Kor. Environ. Sci. Soc., 8(3), 399-409
  34. Al-Duri, B., Y. Khader and G. Mckay, 1992, Prediction of binary component isotherms for adsorption on heterogeneous surfaces, J. Chem. Technol. Biotechnol., 53, 345-352 https://doi.org/10.1002/jctb.280530405
  35. Freeze, R. A. and J. A. Cherry, 1979, Groundwater, Prentice-Hall, 133pp
  36. Parsons, R., 1959, Handbook of electrochemical constants, Butterworths, London, 26-27pp
  37. Kawamura, F. and K. Motojima, 1982, Using copper hexacyanoferrate(II) impregnated zeolite for cesium removal from radioactive liquid waste, Nuclear Technol., 58, 242-247 https://doi.org/10.13182/NT82-A32935
  38. Ebner, A. D., J. A. Ritter and J. D. Navratil, 2001, Adsorption of cesium, strontium, and cobalt ions on magnetite and a magnetite silica composite, Ind. Eng. Chem Res., 40, 1615-1623 https://doi.org/10.1021/ie000695c

Cited by

  1. Removal of Sr and Cs ions by SAN-Zeolite Beads Prepared by Immobilization of Zeolite with SAN vol.24, pp.11, 2015, https://doi.org/10.5322/JESI.2015.24.11.1331