• Title/Summary/Keyword: Ca-형

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Preparation of pyroelectric BSCT thick films by screen-printing (스크린 프린팅을 이용한 초전형 BSCT 후막의 제작)

  • Noh, Hyun-Ji;Lee, Sung-Gap;Nam, Sung-Pill;Lee, Young-Hie
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.165-166
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    • 2008
  • $(Ba_{0.6},Sr_{0.3},Ca_{0.1})TiO_3$ powders, which were prepared by sol-gel method using a solution of Ba-acetate, Sr-acetate and Ca-acetate and Ti iso-propoxide, were mixed with organic vehicle and the BSCT thick films were fabricated by the screen-printing techniques on high purity alumina substrates. The structural and dielectirc properties were investigated for various $Pr_2O_3$ and $Y_2O_3$doping contents. As a result of thermal analysis of $(Ba_{0.6},Sr_{0.3},Ca_{0.1})TiO_3$ powders, the exothermic peak was observed at around $670^{\circ}C$ due to the formation of the polycrystalline perovskite phase. All BSCT thick films, sintered at $1420^{\circ}C$ for 2h, showed the typical XRD patterns of perovskite polycrystalline structure. The average grain size of the specimens decreased with amount of $Pr_2O_3$ and $Y_2O_3$ contents.

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Development of a Low-cost Automatic Water Quality Diagnosis System for Cooling Towers (저가형 냉각탑 자동 수질 진단 시스템 개발)

  • Kim, Jung Hwan;Park, Han-Bin;Kang, Taesam;Park, Jungkeun
    • Journal of Sensor Science and Technology
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    • v.23 no.1
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    • pp.58-65
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    • 2014
  • We developed a low-cost automatic diagnosis system for water quality in cooling towers to measure the concentrations of key ingredients such as $Ca^{2+}$, $Cl^-$, $PO{_4}^{3-}$, and $Fe^{2+}$. $Ca^{2+}$, and $Cl^-$ are the main factors that cause the generation of scale, corrosion, and sludge in water pipes. $PO{_4}^{3-}$ prevents corrosion, sludge and scale by inhibiting the ions (i.e., $Ca^{2+}$, $Cl^-$) from sticking to the pipes. $Fe^{2+}$ is an indicator of pipe corrosion. The proposed system consists of a microprocessor, a specimen container and heater, a precision pump, relays and valves, LED optical sources, and photo detectors. It automatically collects water samples and carries out pretreatment for determining the concentration of each chemical, and then estimates the concentration of each ion using low-cost LED optical sources and detectors. Experimental results showed that the accuracy of the proposed system is sufficiently high for water quality diagnosis and management of cooling towers, demonstrating the possibility of the proposed system's wide usage in real environments.

AN ANALYSIS OF THE LIGHT AND RADIAL VELOCITY CURVES OF DO CAS (식쌍성 DO Cas의 광도곡선과 시선속도곡선의 분석)

  • 안영숙;김호일;이우백
    • Journal of Astronomy and Space Sciences
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    • v.17 no.2
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    • pp.181-188
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    • 2000
  • DO Cas is a short period (P=0.68day) eclipsing binary star and is classified as a near-contact binary by Shaw(1990). There is no published radial velocity curve for this short period binary after Mannino(1958). Hill(1991) suspected that Mannino's radial velocity curve had some serious mistake. So, we scanned the original plates used by Mannino with PDS and the spectra were employed to IRAF packages to estimate the radial velocities. The radial velocity curve and the BVR light curves made by us in 1998 were analyzed simultaneously with Wilson-Devinney code. We found that DO Cas is a contact or near-contact binary which the primary component fills its Roche lobe and we also estimated the absolute dimensions of each components of this system.

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Thermal and Mineralogical Characterization of Ca-Montmorillonite from Gampo Area (감포지역(甘浦地域) Ca-몬모릴로나이트의 열적(熱的) 및 광물학적(鑛物學的) 특성(特性))

  • Moon, Hi-Soo;Choi, Sun Kyung;Kim, Moon Young
    • Economic and Environmental Geology
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    • v.21 no.2
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    • pp.175-184
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    • 1988
  • Ten under 2 micron size fractions of the montmorillonite from Yongdongri area, Gyeongsangbug-Do were studied using X-ray powder diffraction, cation exchange measurement, differential thermal analysis, thermogravimetric analysis, differential thermal scanning calorimetry and chemical analysis. Montmorillonites occurring at same deposit show limited variation in chemical composition whereas in thermal properties they do not. Their dehydroxylation endothermic peaks are "abnormal" type with a small range of variation of peak temperature reflecting tetrahedral substitution of Al for Si. Data from DSC show that divalent-cation saturated montmorillonite has relatively a higher endothermic heat capacity than monovalent-cation saturated montmorillonite, indicating that cations with higher electronegativity hold more water molecules.

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Decline of Trees by Acid Rain - Especially Cation - (산성 강우에 의한 수목의 쇠퇴현상(II) - 양이온을 중심으로 -)

  • Lee, Chong-Kyu;Hwang, Jin-Hyoung;Kim, Jong-Gap
    • The Korean Journal of Ecology
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    • v.28 no.6
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    • pp.383-387
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    • 2005
  • In order to clarify the causal of free decline, which observed around the industrial complex, we analyzed pH, electrical conductivity (EC), and cation in rainfall and throughfall cations concentration in the air in tree areas, suburban and rural area. pH of both rainfall and throughfall was lower in the industrial area than the suburban and rural areas. Among the abiotic and biotic factors analyzed in this study, relations between decline degree of Pinus thunbergii and ingredients of rainfall, pH and $Ca^{2+}$ showed negative and positive correlations, respectively.

Dielectric Properties of Liquid Crystalline Polymers and $CaTiO_3-LaAlO_3$ Composites for Embedded Matching Capacitors (내장형 capacitor를 위한 LCP와 $CaTiO_3-LaAlO_3$ 복합재의 유전특성)

  • Kim, Jin-Cheol;Oh, Jun-Rok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.232-233
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    • 2007
  • We manufactured Liquid Crystal Polymer (LCP) and (1-x)CaTiO3-xLaAlO3 (CT-LA) ceramic composites and investigated dielectric properties to use as embedded capacitor in printed circuit boards and replace LTCC substrate. The dielectric properties of these composites are varied with volume fraction of CT-LA and ratios of CT/LA. Dielectric constants are in the range of 3~15. In addition, we could get low TCC and High Q value that could not achieve in other ceramic-polymer composites. Especially, in composite with x=0.01 and 30 vol% CT-LA, the dieletric constant and Q-value are 10 and 200, respectively. And more TCC is $-28{\sim}300ppm/^{\circ}C$ in the temperature range of $-55{\sim}125^{\circ}C$. We think that this composites can be used high-Q substrate material like LTCC and embedded temperature compensation capacitor in printed circuit boards.

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Production of Vaterite Type Calcium Carbonate by using Oyster Shell Waste with Lysine (라이신 첨가에 의한 폐 굴껍질 이용 vaterite형 탄산칼슘 제조)

  • Bak, Young-Cheol
    • Korean Chemical Engineering Research
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    • v.59 no.1
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    • pp.118-126
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    • 2021
  • The experiments to produce the vaterite type calcium carbonate were conducted for using the waste oyster shell as the recycling resources. Firstly, the oyster shell were calcinated at 800 ℃ for 24 h. Calcinated oyster shell were reacted with the nitric acid solution, and were diluted to 0.1 M Ca(NO3)2 solution. This solution was mixed with 0.1 M Na2CO3 contained 0.1 mol lysine/1 mol CaO at 20 ℃ and 600 rpm mixing condition for 1 h. The reaction products were identified to vaterite type calcium carbonate (84.5% vaterite, 15.5% calcite) by XRD and SEM analysis. Mean particle diameter was 6.87 ㎛, and the lysine content in calcium carbonate was analyzed to 0.1%.

The vortex dynamics in $Bi_2$$Sr_2$Ca$Cu_2$$O_8$single crystals unirradiated and with low-density columnar defect (저밀도 원통형 결함이 $Bi_2Sr_2CaCu_2O_8$ 단결정의 볼텍스 동역학에 미치는 영향)

  • Lee, T.W.;Lee, C.W.;Shim, S.Y.;Ha, D.H.;Kim, D.H.
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.36-40
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    • 2001
  • We have studied vortex dynamics in$ Bi_2$$Sr_2$$CaCu_2$O$_{8}$single crystals of unirradiated and irradiated samples by using 100 $\times$ $100\mu\textrm{m}^2$Hall sensor. Doses equivalent magnetic fields are 20 G, 100 G and 1 kG. In the magnetization measurement, a second magnetization peak (SMP) was observed in unirradiated, 20 G dose and 100 G dose samples in contrast to 1 kG dose sample. In the unirradiated sample, the SMP was observed in the range of 18 K ~ 35 K and the amplitude of the SMP decreased with increasing temperature. With increase of the irradiation dose, temperature region and sharpness of the SMP were reduced. In the magnetic relaxation measurement, we observed that the normalized relaxation rate S decreased with increasing the irradiation dose. Our results suggest that the vortex dynamics is not greatly affected by low-density columnar defects.s.

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Molecular Epidemiology and Antimicrobial Resistance of Methicillin-resistant Staphylococcus aureus Isolated from Nasal Swab at Intensive Care Unit (중환자실 입원 환자의 비강 도말에서 메티실린 내성 황색포도알균의 분자역학, 항생제 내성 연구)

  • Kwak, Om Sub;Kwon, Mee Hye;Jeong, Ji Hyun;Kang, Mi-il;Cheun, Ji Young;Lee, Go Eun;Kim, Young Keun;Choi, Eu Gene;Na, Moon Jun;Kwon, Hee Uk;Son, Ji Woong
    • Tuberculosis and Respiratory Diseases
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    • v.65 no.2
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    • pp.91-98
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    • 2008
  • Background: Methicillin-resistant Staphylococcus aureus (MRSA) is the most common organism associated with nosocomial infections. MRSA infections are becoming increasing important because they have emerged no only as healthcare-associated (HA) infections but also as community-associated (CA) ones. This study examined the moleculo-epidemiology of MRSA, which was isolated from nasal swabs in the intensive care unit (ICU) at Konyang University Hospital. MRSA are classified into HA-MRSA and CA-MRSA. Methods: From June to September 2006, 353 patients who were admitted to the ICU in Konyang University Hospital were enrolled in this study. Single nasal swabs were obtained for culture in the ICU on the 1st day. Pulsed-field gel electrophoresis and the antimicrobial resistant patterns were analyzed between HA- and CA-MRSA. An antimicrobial sensitivity test was also performed. Results: Forty two strains of MRSA were isolated from 353 patients (11.9%). Among the 42 isolates, HA-MRSA and CA-MRSA were found in 33 (78.6%), and 9 (21.4%), respectively. Eleven different PFGE types (type A to K) were identified. Types A (n=9) and B (n=7) were the most common for HA-MRSA, and types A (n=2) and B (n=2) were identified in CA-MRSA. The proportion of types A and B in CA-MRSA (44.4%) was similar to that in HA-MRSA (48.5%). The rates of resistance rates to erythromycin and ciprofloxacin were higher in HA-MRSA than in CA-MRSA. Conclusion: The rate of isolation of MRSA in an ICU setting was 11.9%. HA-MRSA was isolated more frequently than CA-MRSA. The rate of resistance of HA-MRSA to erythromycin and ciprofloxacin was higher than that of CA-MRSA. Despite the small number of subjects, the main isolates (type A and B) of CA-MRSA were similar to those of HA-MRSA.

Synthesis of Fe­Garnet for tile Immobilization of High Level Radioactive Waste (고준위 방사성폐기물의 고정화를 위한 Fe­석류석 합성 연구)

  • ;;;Yudintsev, S. V.
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.4
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    • pp.307-320
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    • 2003
  • Garnet has been considered as a possible matrix for the immobilization of radioactive actinides. It is expected that Fe­based garnet be able to have the high substitution ability of actinide elements because ionic radius of Fe in tetrahedral site is larger than that of Si of Si­based garnet. Accordingly, we synthesized Fe­garnet with the batch composition of $Ca_{2,5}$C $e_{0.5}$Z $r_2$F $e_3$ $O_{12}$ and $Ca_2$CeZrFeF $e_3$ $O_{12}$ and studied their phase relations and properties. Mixed samples were fabricated in pellet forms under the pressure of 400 kg/$\textrm{cm}^2$ and were sintered in the temperature range of 1100∼140$0^{\circ}C$ in atmospheric conditions. Phase identification and chemical composition of synthesized samples were analyzed by XRD and SEM/EDS. In results, where the compounds were sintered at 130$0^{\circ}C$, we optimally obtained Fe­garnets as the main phase, even though some minor phases like perovskite were included. The compositions of Fe­garnets synthesized from the batch compositions of $Ca_{2,5}$C $e_{0.5}$Z $r_2$F $e_3$ $O_{12}$ and $Ca_2$CeZrFeF $e_3$ $O_{12}$, are $Ca_{2.5­3.2}$C $e_{0.3­0.7}$Z $r_{1.8­2.8}$F $e_{1.9­3.2}$ $O_{12}$ and $Ca_{2.2­2.5}$C $e_{0.8­1.0}$Z $r_{1.3­1.6}$ F $e_{0.4­.07}$ F $e_{3­3.2}$ $O_{12}$, respectively. Ca contents were exceeded and Ce contents were exceeded or depleted in 8­coodinated site, comparing to the initial batch composition. These results were caused by the compensation of the difference of ionic radius between Ca and Ce.