• Title/Summary/Keyword: Ca addition

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Preparation and Characteristics of Cellulose Acetate Based Nanocomposites Reinforced with Cellulose Nanocrystals (CNCs) (셀룰로오스 나노크리스탈 강화 셀룰로오스 아세테이트 나노복합소재 제조 및 특성)

  • Gwon, Jae-Gyoung;Lee, Dan-Bee;Cho, Hye-Jung;Lee, Sun-Young
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.5
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    • pp.565-576
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    • 2018
  • Cellulose acetate (CA) has been widely utilized for composite materials due to its high transparency and thermal resistance. In this study, CNCs (cellulose nanocrystals) were reinforced in CA nanocomposites for fortifying mechanical properties of the composites. In addition, CA nanocomposites reinforced with CNCs were manufactured by extrusion/injection processes applied with CNC-predispersion method for achieving a high dispersion level of CNCs in the CA matrix. According to the analysis of mechanical properties, the CA nanocomposite with 3 wt% CNCs has the highest tensile and flexural strengths due to the reinforcing effect of CNC nanoparticles. Thermogravimetric analysis (TGA) showed that the addition of acid hydrolyzed CNCs slightly lowered the initial pyrolysis temperature of CA nanocomposite.

Effect of Ca additions on Mechanical Properties of Mg-4Al-2Sn-xCa Die-Casting Alloys (Ca 첨가에 따른 Mg-4Al-2Sn-xCa 다이캐스팅 합금의 기계적특성 연구)

  • Kim, Young-Min;Lee, Young-Cheol;Park, Yong-Ho
    • Journal of Korea Foundry Society
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    • v.31 no.5
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    • pp.293-301
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    • 2011
  • Representative magnesium alloys applied to the die-casting are AZ91, AM60, etc., and the application of these alloys is restricted to components operating at moderate temperatures, due to grain boundary siding of ${\beta}$-phase($Mg_{17}Al_{12}$) at temperatures above $120^{\circ}C$. Heat-resistant magnesium alloys such as AE42, AE44 have been developed, but that have been too burdensome to produce because of the expensive rare earth materials. Research work for the development of low-priced heat-resistant magnesium alloy is actively in progress and positive results are being reported. This study aims to investigate the effect of Ca additions on mechanical properties of Mg-4Al-2Sn heat resistant magnesium alloys. Mg-4Al-2Sn alloys with Ca (0wt.%, 0.3wt.%, 0.7wt.%, 1wt.%) have been produced through the die-casting process for the development of low-priced heat-resistant magnesium alloy, and high temperature tensile tests are performed using the specimens. The results showed that mechanical properties of Mg-4Al-2Sn-xCa increased with the addition of Ca up to 0.7wt.% Ca and further addition of Ca deteriorated the mechanical properties of the alloys. A significant amount of porosity was observed at the sample with 1wt%. Ca and the longer freezing range of the alloy was believed to cause the formation of porosity.

Protective role of caffeic acid in an Aβ25-35-induced Alzheimer's disease model

  • Kim, Ji Hyun;Wang, Qian;Choi, Ji Myung;Lee, Sanghyun;Cho, Eun Ju
    • Nutrition Research and Practice
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    • v.9 no.5
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    • pp.480-488
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    • 2015
  • BACKGROUND/OBJECTIVES: Alzheimer's disease (AD) is characterized by deficits in memory and cognitive functions. The accumulation of amyloid beta peptide ($A{\beta}$) and oxidative stress in the brain are the most common causes of AD. MATERIALS/METHODS: Caffeic acid (CA) is an active phenolic compound that has a variety of pharmacological actions. We studied the protective abilities of CA in an $A{\beta}_{25-35}$-injected AD mouse model. CA was administered at an oral dose of 10 or 50 mg/kg/day for 2 weeks. Behavioral tests including T-maze, object recognition, and Morris water maze were carried out to assess cognitive abilities. In addition, lipid peroxidation and nitric oxide (NO) production in the brain were measured to investigate the protective effect of CA in oxidative stress. RESULTS: In the T-maze and object recognition tests, novel route awareness and novel object recognition were improved by oral administration of CA compared with the $A{\beta}_{25-35}$-injected control group. These results indicate that administration of CA improved spatial cognitive and memory functions. The Morris water maze test showed that memory function was enhanced by administration of CA. In addition, CA inhibited lipid peroxidation and NO formation in the liver, kidney, and brain compared with the $A{\beta}_{25-35}$-injected control group. In particular, CA 50 mg/kg/day showed the stronger protective effect from cognitive impairment than CA 10 mg/kg/day. CONCLUSIONS: The present results suggest that CA improves $A{\beta}_{25-35}$-induced memory deficits and cognitive impairment through inhibition of lipid peroxidation and NO production.

Effects of Dietary Ca Levels and Kinds of Lipids on the Lipid Metabolism in the Rats (식이내 Ca 수준과 지방 종류를 달리하였을 때 흰쥐의 체내 지방대사에 미치는 영향)

  • 권오란
    • Journal of Nutrition and Health
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    • v.21 no.5
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    • pp.324-332
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    • 1988
  • Effects of a change in dietary Ca content and an alteration in dietary lipid type on lipid metabolism have been investigated in male Sprague-Dawley rats. The results obtained were summarized as follows ; 1) There was no comparable changes in food consumption and body weight gain among all 9 groups. 2) Serum total lipids and cholesterol were lowest when high Ca-corn all diet was fed, and highest when low Ca-butter diet was fed. 3) The contents of total lipids and cholesterol per g liver and total liver showed no consistent tendency with the dietary treatment. 4) Addition of Ca to the diet caused the significant increase in the dry fecal matter and fecal Ca. And fecal total lipids and fecal cholesterol were much greater if the high-Ca diet was fed than if control and low-Ca diet were fed. It is concluded that Ca and polyunsaturated acids have tendency of hypocholesterolemic effect.

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Luminescence of CaS:Bi

  • 김창홍;편종홍;최 한;김성진
    • Bulletin of the Korean Chemical Society
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    • v.20 no.3
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    • pp.337-340
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    • 1999
  • Luminescence of bismuth activated CaS, CaS:Bi, prepared in sodium polysulfide is studied. Excitation spectrum of CaS:Bi shows a band at 350 nm due to the recombination process between holes in Na+Ca2+ and electrons in conduction bands, in addition to bands at 260 nm from band gap of CaS, and at 320 nm (1S0→1P1) and at 420 nm (1S0→3P1) from electronic energy transitions of Bi. Emission band at 450 nm is from 3P1→1S0 transition of Bi3+, bands at 500 nm and 580 nm correspond to recombinations of electron donors (Bi3+Ca2+ and VS2-) with acceptors (VCa2+ and Na+Ca2+). Emission band of 3P1→1S0 transition is shifted to longer wavelength from CaS:Bi to BaS:Bi, due to the increase of the Stokes shift by the decrease of the crystal field parameter from CaS:Bi to BaS:Bi.

An Effect of $Al_{2}O_{3}$ on the Reaction between Molten Converter Slag and CaO pellet (용융전로(熔融轉爐)슬래그와 CaO펠렛의 상호반응(相互反應)에 미치는 $Al_{2}O_{3}$의 영향(影響))

  • Kim, Young-Hwan;Ko, In-Yong
    • Resources Recycling
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    • v.15 no.2 s.70
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    • pp.3-9
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    • 2006
  • As a basic study on the conversion of molten converter slag to the ordinary portland cement, the effects of $Al_{2}O_{3}$ addition on the interface reaction between solid CaO and molten converter slag has been studied. Alumina added converter slag whose basicity was controlled to 1 and 2 was melted and hold for 30 minutes in MgO crucible at $1500^{\circ}C$. Then sintered CaO pellet heated at the same temperature was dipped into the molten slag and held for 30minutes. After the reaction, the crucible was cooled in air and the specimen was cut off to the horizontal direction of the crucible. The dissolution rate of CaO pellet with the addition of $Al_{2}O_{3}$ was measured by the change of the radius or sintered CaO pellet and the interface layer was observed by SEM/EDX. As a result. At the basicity 2 slag, thickness of created $C_{3}S$ layer increased 3.5 times and quantity of $C_{6}AF_{2}\;or\;C_{4}AF$ phase increase 2 times than baisicy 1 slag.

Effect of Fluid Pressure on L-type $Ca^{2+}$ Current in Rat Ventricular Myocytes (백서 심실 근세포 L형 $Ca^{2+}$ 전류에 대한 유체압력의 효과)

  • Lee Sun-Woo;Woo Sun-Hee
    • YAKHAK HOEJI
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    • v.50 no.2
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    • pp.111-117
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    • 2006
  • Cardiac chambers serve as mechanosensory systems during the haemodynamic or mechanical disturbances. To examine a possible role of fluid pressure (FP) in the regulatien of atrial $Ca^{2+}$ signaling we investigated the effect of FP on L-type $Ca^{2+}$ current $(I_{Ca})$ in rat ventricular myocytes using whole-cell patch-clamp technique. FP $(\sim40cm\;H_2O)$ was applied to whole area of single myocytes with electronically controlled micro-jet system. FP suppressed the magnitude of peak $I_{Ca}$ by $\cong25\%$ at 0 mV without changing voltage dependence of the current-voltage relationship. FP significantly accelerated slow component in inactivation of $I_{Ca}$, but not its fast component. Analysis of steady-state inactivation curve revealed a reduction of the number of $Ca^{2+}$ channels available for activity in the presence of FP. Dialysis of myocytes with high concentration of immobile $Ca^{2+}$ buffer partially attenuated the FP-induced suppression of $I_{Ca}$. In addition, the intracellular $Ca^{2+}$ buttering abolished the FP-induced acceleration of slow component in $I_{Ca}$ inactivation. These results indicate that FP sup-presses $Ca^{2+}$ currents, in part, by increasing cytosolic $Ca^{2+}$ concentration.

Study of the Effects of Potassium Chloride and Calcium Chloride on the Development of Drosophila melanogaster (염화칼륨과 염화칼슘의 초파리 발생에 미치는 영향에 대하여)

  • Kang, Moon-Ju;Chung, Yong-Jai
    • The Korean Journal of Zoology
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    • v.17 no.1
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    • pp.5-16
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    • 1974
  • In order to see the single effect and interaction of potassium chloride(KCI) and calcium the chloride ($CaCl_2$) on the development of Drosophila melanogaster, the emergence rates of the five strains of the flies were examined from the media containing 0.0M, 0.5M, 0.1M, 0.2M, of $CaCl_2$ or KCI plus various concentrations of KCI or $CaCl_2$, and the results are presented as follows: 1. The emergence rate of D. melanogaster is not significantly different among strains but strikingly different among concentrations of KCI or $CaCl_2$; the emergence rate decreases as concentration of KCI or $CaCl_2$ increases. 2. The inhibitory effect of $CaCl_2$ on the emergence rates is greater than that of KCI, implying that the resistibility of the flies to KCI is greater than to $CaCl_2$. 3. The addition of small amount of $CaCl_2$ or KCI to KCI or $CaCl_2$ media counteracts the inhibitory effect of KCI or $CaCl_2$, but the addition of a little greater amounts of $CaCl_2$ or KCI to the KCI or $CaCl_2$ media enhance the inhibitory effect of the salts. 4. Thus, there may be some interaction of $K^+$ and $Ca^++$ ions in the inhibitory effect on the development(emergence rates) of Drosophila melanogaster.

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Effects of CellCaSi and Inorganic Additives on Phosphorus Removal in Water (규산질다공체와 무기첨가물의 수중 인 제거 효과)

  • Park, Myung-Hwan;Han, Myung-Soo;Lee, Seog-June;Ahn, Chi-Yong;Yoon, Byung-Dae;Oh, Hee-Mock
    • Korean Journal of Ecology and Environment
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    • v.35 no.3 s.99
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    • pp.213-219
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    • 2002
  • The CellCaSi, a porous silicate material, was tested for the removal of phosphorus (P as phosphate) in water. The effect of the CellCaSi was investigated on the basis of both particle size (under 1,2, and 4 mm) and added amount (0, 1, 2.5, 5, and 10 g/1) of the CellCaSi. The removal efficiency of phosphorus was highest with a particle size of under 1 mm and also increased with an increasing amount of the CellCaSi. The pH change showed little effect on the phosphorus removal of the CellCaSi. The calcium ion was eluted from the CellCaSi into the water, while the aluminium and iron were not. The eluted calcium ion was combined with dissolved phosphorus and then precipitated. The highest removal efficiency of phosphorus was obtained by the combined addition of the CellCaSi, calcium chloride, and ferric chloride. That is, the phosphorus concentrations of 0.10 and 1.0 mg/1 decreased to 0.03 and 0.47 mg/l by the addition of the CellCaSi (1 g/l), calcium ion (30 mg/l), and ferric ion (1 mg/l) at day 8 after treatment. The water qualities at the end of the experiment were as follows: pH was 8.1 and conductivity was 318 ${\mu}$S/cm (a registered maximum conductivity of 500${\mu}$S/cm for raw and potable wafers).

Effect of Strontium on the Uptake and Distribution of Calcium and Magnesium in Sugar beet (스티론티움에 의한 사탕무의 Ca과 Mg 흡수 및 분포)

  • Kim, Tae Wan;Hwang, Seon-Woong;Lee, Young-Hwan;Um, Myung-Ho;Heinrich, Georg
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.4
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    • pp.333-343
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    • 1999
  • To investigate the relationship between the translocation and distribution the monovalent K and Na and the divalent Sr and Ca, the natrophile and calcitrophic plant sugar beet (Beta vulgaris L.) was used. Strontium uptake and distribution are concentration and growth stage dependent. The highest Ca content occurred in the treatment of 4 : 1 mM ratio of Ca to Sr, while the highest Sr content in old leaves in the presence of 1 mM Ca and 4 mM Sr. The addition of low concentration of Sr stimulates Ca-uptake. Reversely. Sr-uptake is highest in the presence of 1 mM Ca. This result may be an antagonistic effect between Ca and Sr. The ratios of Mg to Ca and Sr are satisfactorily presented by the regression analysis. The sum of Sr and Ca contents are most significant linear to the ratio of Mg to one, showing a negative correlation. This result implies that the absorption of Mg and Ca or Sr is antagonistic. In the presence of only 5 mM Sr, K and Na-uptakes increases, while Sr in the presence of Ca does not affect the change in the K and Na assimilation and their ratios. The ratios of K to Na is also not changed. A little addition of Sr could more effectively retain the chlorophyll loss while only in the presence of Sr, the chlorophyll levels are considerably reduced.

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