• Title/Summary/Keyword: Ca^{2+}$

Search Result 14,522, Processing Time 0.039 seconds

Ettect of Sodium Gluconate on the Hydration of 3CaO.$Al_2O_3$(I)-Adsorption Behavior- (3CaO.$Al_2O_3$의 수화반응에 미치는 글루콘산나트륨읨 영향(I) -흡착거동-)

  • 김창은;이승헌;유종석;최진호
    • Journal of the Korean Ceramic Society
    • /
    • v.23 no.2
    • /
    • pp.38-42
    • /
    • 1986
  • The adsorption behavior of 3CaO.$Al_2O_3$-sodium gluconate-$H_2O$ system by measuring adsorp-tion isotherm DTA and IR sepctra. The adsorbed amount of sodium gluconate on 3CaO.$Al_2O_3$ is exceedingly larger than 3CaO.$SiO_2$ and portland cement. From the DAT experiment the formation of complex is observed by the characteristic exothermic peak of the complex at 45$0^{\circ}C$ It is now strong deduced that the chemical bonding between gluconate anion and 3CaO.$Al_2O_3$ should be coordinative due to the complex formation on the surface 3CaO.$Al_2O_3$ from the IR spectra of sod-ium gluconate only and 3CaO.$Al_2O_3$ -sodium gluconate-$H_2O$.

  • PDF

Sewage sludge solubilization using ultrasonic combined with calcium peroxide (초음파/과산화칼슘(US/CaO2)을 이용한 하수슬러지 가용화)

  • Han, Jun-Hyuk;Nam, Se-Yong
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.29 no.4
    • /
    • pp.41-46
    • /
    • 2021
  • In order to investigate the degree of sewage sludge solubilizaion using ultrasonic(US) combined with calcium peroxide(CaO2), VSS reduction rate, solubilization rate, SCOD/VSS ratio, SCOD increasing rate, LB-EPS(Loosely-Bound EPS) and TB-EPS(Tightly-bound EPS) were measured. US was compared as a control. Solubilization rate increased by 23.4% under US and increased by 50.7% under US/CaO2(0.05 g CaO2/g VSS). and also, at the same conditions, VSS reduction rate increased by 7.1% and 17.7%, respectively. SCOD increasing rate from 10 to 90 minutes was 0.0151 min-1 under US/CaO2(0.02 g CaO2/g VSS). TB-EPS decreased by 36.4% under US and decreased by 59.0% under US/CaO2(0.05 g CaO2/g VSS). TB-EPS decreased during first 10 minutes and then decreased slowly until 90 minutes. There was no significant difference in TB-EPS decrease according to the dosage of calcium peroxide.

A study on the electrolytic properties of $CaF_2$ crystals with $YF_3$ addition ($YF_3 $ 첨가에 따른 $CaF_2 $ 결정의 고체전해질 특성에 관한 연구)

  • Cha, Y.W.;Park, D.C.;Orr, K.K.
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.4 no.1
    • /
    • pp.21-32
    • /
    • 1994
  • $CaF_2$ crystals were grown with various growth rates by Bridgman method, and the electrical properties of these were studied to examine the changes of ionic conductivities with growth rates by AC Impedance Analyzer. As the growth rates were higher, $CaF_2$ crystals were grown to polycrystals from single crystal. And as grain boundaries and various defects were altered, the ionic conductivities were changed dramatically. $YF_3$ added to $CaF_2$ for disorderizing $CaF_2$ structure and improving the number of $F^-$ carriers and vacancies in $CaF_2$ crystals. Then $Ca_{1-x}Y_XF_{2+X}$ crystals were gained. And the ionic conductivities of $Ca_{1-x}Y_XF_{2+X}$ crystals were investigated with $YF_3$ addition. The ionic conductivities of $CaF_2$ and $Ca_{1-x}Y_XF_{2+X}$ crystals with temperatures were compared. In addition, the effects of clusterings and defects on the electrical properties of solid electrolytes were researched.

  • PDF

The Influence of Heat Treatment and Ca contents on the Electrochemical Characteristics of Mg-Ca Alloys (Mg-Ca 합금의 전기화학적 특성에 미치는 Ca 첨가량 및 열처리의 영향)

  • Lee, S.H.;Chung, Dong-Seok;Park, B.O.;Kim, Y.G.;Jeong, Ha-Guk;Kim, Hye-Sung
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.17 no.3
    • /
    • pp.173-179
    • /
    • 2004
  • In this study, the influence of heat treatment and Ca contents on the electrochemical behavior was investigated. Mg-Ca alloys, i.e., Mg-0.22wt%Ca, Mg-0.56wt%Ca, Mg-1.31wt%Ca are prepared by ingot metallurgy. As-cast Mg-Ca alloys exhibited better electrochemical properties than pure Mg. Especially, Mg-0.22wt%Ca alloy improves its anode efficiency up to 62% and lowers the OCP up to -1.72VSCE. Microstructure and XRD patterns of Mg-Ca alloys show that additive Ca element is mainly solid-solutioned. While, the others show the microstructure and XRD pattern with large $Mg_2Ca$ at grain boundary. To assess the effect of heat treatment on the as-cast Mg-alloy, the specimens were heat treated at $200^{\circ}C$ for 2 hours under $CO_2$ gas atmosphere. Although corrosion properties of Mg-Ca alloys are somewhat deteriorated by heat treatment at $200^{\circ}C$ Mg-0.22wt%Ca alloy with uniformly distributed nano-sized $Mg_2Ca$ phase in ${\alpha}$-Mg matrix show still better corrosion properties than pure Mg specimen.

Ginsenoside Rg1 attenuates mechanical stress-induced cardiac injury via calcium sensing receptor-related pathway

  • Lu, Mei-Li;Wang, Jing;Sun, Yang;Li, Cong;Sun, Tai-Ran;Hou, Xu-Wei;Wang, Hong-Xin
    • Journal of Ginseng Research
    • /
    • v.45 no.6
    • /
    • pp.683-694
    • /
    • 2021
  • Background: Ginsenoside Rg1 (Rg1) has been well documented to be effective against various cardiovascular disease. The aim of this study is to evaluate the effect of Rg1 on mechanical stress-induced cardiac injury and its possible mechanism with a focus on the calcium sensing receptor (CaSR) signaling pathway. Methods: Mechanical stress was implemented on rats through abdominal aortic constriction (AAC) procedure and on cardiomyocytes and cardiac fibroblasts by mechanical stretching with Bioflex Collagen I plates. The effects of Rg1 on cell hypertrophy, fibrosis, cardiac function, [Ca2+]i, and the expression of CaSR and calcineurin (CaN) were assayed both on rat and cellular level. Results: Rg1 alleviated cardiac hypertrophy and fibrosis, and improved cardiac decompensation induced by AAC in rat myocardial tissue and cultured cardiomyocytes and cardiac fibroblasts. Importantly, Rg1 treatment inhibited CaSR expression and increase of [Ca2+]i, which similar to the CaSR inhibitor NPS2143. In addition, Rg1 treatment inhibited CaN and TGF-b1 pathways activation. Mechanistic analysis showed that the CaSR agonist GdCl3 could not further increase the [Ca2+]i and CaN pathway related protein expression induced by mechanical stretching in cultured cardiomyocytes. CsA, an inhibitor of CaN, inhibited cardiac hypertrophy, cardiac fibrosis, [Ca2+]i and CaN signaling but had no effect on CaSR expression. Conclusion: The activation of CaN pathway and the increase of [Ca2+]i mediated by CaSR are involved in cardiac hypertrophy and fibrosis, that may be the target of cardioprotection of Rg1 against myocardial injury.

Dissociative adsorption and self-assembly of $CaF_2$ on the Si(001)-$4^{\circ}$ off surface

  • Kim, Hui-Dong;Dugerjav, Otgonbayar;Arvishataar, Amarmunkh;Motlak, Moaaed;Seo, Jae-Myeong
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.02a
    • /
    • pp.132-132
    • /
    • 2012
  • Depositing $CaF_2$[0.6% lattice-mismatch] on the Si(001)-$4^{\circ}$ off surface [composed of a single (001) domain with regularly-arrayed double-layer DB steps and located between (1 1 19) and (1 1 21)] held at $700^{\circ}C$, $CaF_2$ molecules are preferentially adsorbed on the dimers and dissociated to Ca and F atoms. Dissociated Ca atoms form a silicide layer of a $2{\times}3$ structure on the (001) terrace, while F atoms are desorbed from the surface. Once the terrace is covered with a calcium silicide layer, CaF starts to be adsorbed selectively on the steps, as shown in Fig. (a). With $CaF_2$ deposition exceeding 1 ML, the (1 1 17) surface having 1-D $CaF_2$ nanodots are formed as shown in Fig. (b). By the present STM study, it has been clearly disclosed that the calcium silicide interfacial layer is preformed prior to adsorption of $CaF_2$ on vicinal Si(001) surface.

  • PDF

Asn-Linked Glycosylation Contributes to Surface Expression and Voltage-Dependent Gating of Cav1.2 Ca2+ Channel

  • Park, Hyun-Jee;Min, Se-Hong;Won, Yu-Jin;Lee, Jung-Ha
    • Journal of Microbiology and Biotechnology
    • /
    • v.25 no.8
    • /
    • pp.1371-1379
    • /
    • 2015
  • The Cav1.2 Ca2+ channel is essential for cardiac and smooth muscle contractility and many physiological functions. We mutated single, double, and quadruple sites of the four potential Asn (N)-glycosylation sites in the rabbit Cav1.2 into Gln (Q) to explore the effects of Nglycosylation. When a single mutant (N124Q, N299Q, N1359Q, or N1410Q) or Cav1.2/WT was expressed in Xenopus oocytes, the biophysical properties of single mutants were not significantly different from Cav1.2/WT. In comparison, the double mutant N124,299Q showed a positive shift in voltage-dependent gating. Furthermore, the quadruple mutant (QM; N124,299,1359,1410Q) showed a positive shift in voltage-dependent gating as well as a reduction of current. We tagged EGFP to the QM, double mutants, and Cav1.2/WT to chase the mechanisms underlying the reduced currents of QM. The surface fluorescence intensity of QM was weaker than that of Cav1.2/WT, suggesting that the reduced current of QM arises from its lower surface expression than Cav1.2/WT. Tunicamycin treatment of oocytes expressing Cav1.2/WT mimicked the effects of the quadruple mutations. These findings suggest that Nglycosylation contributes to the surface expression and voltage-dependent gating of Cav1.2.

Low Temperature Sintering and Dielectric Properties of CaCO3-Al2O3 Mixture and Compound with CAS-based Glass (CAS계 유리가 첨가된 CaCO3-Al2O3 혼합물 및 화합물의 저온 소결 및 유전 특성)

  • Yoon, Sang-Ok;Kim, Myung-Soo;Kim, Kwan-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.22 no.5
    • /
    • pp.397-404
    • /
    • 2009
  • Effects of ceramic filler types and dose on the low temperature sintering and dielectric properties of ceramic/$CaO-Al_2O_3-SiO_2$ (CAS) glass composites were investigated. All of the specimens were sintered at $850{\sim}900^{\circ}C$ for 2 h, which conditions are required by the low-temperature co-firing ceramic (LTCC) technology. Ceramic fillers of $CaCO_3$, $Al_2O_3$, $CaCO_3-Al_2O_3$ mixture, and $CaCO_3-Al_2O_3$ compound ($CaAl_2O_4$), respectively, were used. The addition of $Al_2O_3$ yielded the crystalline phase of alumina, which was associated with the inhibition of sintering, while, $CaCO_3$ resulted in no apparent crystalline phase but the swelling was significant. The additions of $CaCO_3-Al_2O_3$ mixture and $CaAl_2O_4$, respectively, yielded the crystalline phases of alumina and anorthite, and the sintering properties of both composites increased with the increase of filler addition and the sintering temperature. In addition, the $CaAl_2O_4$/CAS glass composite, sintered at $900^{\circ}C$, demonstrated good microwave dielectric properties. In overall, all the investigated fillers of 10 wt% addition, except $CaCO_3$, yielded reasonable sintering (relative density, over 93 %) and low dielectric constant (less than 5.5), demonstrating the feasibility of the investigated composites for the application of the LTCC substrate materials.

Protease-Activated Receptor 2 Activation Inhibits N-Type Ca2+ Currents in Rat Peripheral Sympathetic Neurons

  • Kim, Young-Hwan;Ahn, Duck-Sun;Kim, Myeong Ok;Joeng, Ji-Hyun;Chung, Seungsoo
    • Molecules and Cells
    • /
    • v.37 no.11
    • /
    • pp.804-811
    • /
    • 2014
  • The protease-activated receptor (PAR)-2 is highly expressed in endothelial cells and vascular smooth muscle cells. It plays a crucial role in regulating blood pressure via the modulation of peripheral vascular tone. Although several mechanisms have been suggested to explain PAR-2-induced hypotension, the precise mechanism remains to be elucidated. To investigate this possibility, we investigated the effects of PAR-2 activation on N-type $Ca^{2+}$ currents ($I_{Ca-N}$) in isolated neurons of the celiac ganglion (CG), which is involved in the sympathetic regulation of mesenteric artery vascular tone. PAR-2 agonists irreversibly diminished voltage-gated $Ca^{2+}$ currents ($I_{Ca}$), measured using the patch-clamp method, in rat CG neurons, whereas thrombin had little effect on $I_{Ca}$. This PAR-2-induced inhibition was almost completely prevented by ${\omega}$-CgTx, a potent N-type $Ca^{2+}$ channel blocker, suggesting the involvement of N-type $Ca^{2+}$ channels in PAR-2-induced inhibition. In addition, PAR-2 agonists inhibited $I_{Ca-N}$ in a voltage-independent manner in rat CG neurons. Moreover, PAR-2 agonists reduced action potential (AP) firing frequency as measured using the current-clamp method in rat CG neurons. This inhibition of AP firing induced by PAR-2 agonists was almost completely prevented by ${\omega}$-CgTx, indicating that PAR-2 activation may regulate the membrane excitability of peripheral sympathetic neurons through modulation of N-type $Ca^{2+}$ channels. In conclusion, the present findings demonstrate that the activation of PAR-2 suppresses peripheral sympathetic outflow by modulating N-type $Ca^{2+}$ channel activity, which appears to be involved in PAR-2-induced hypotension, in peripheral sympathetic nerve terminals.

Postharvest Quality of Satsuma Mandarin Fruit Affected by Controlled Atmosphere (CA 저장이 온주밀감의 수확 후 품질에 미치는 효과)

  • Yang, Yong-Joon
    • Horticultural Science & Technology
    • /
    • v.19 no.2
    • /
    • pp.145-148
    • /
    • 2001
  • This research was conducted to find out whether controlled atmosphere(CA) can maintain Satsuma Mandarin fruit fresh longer compared to cold storage. Fruit harvested in Nov. 1998 at Jeju Province were stored in three different CA condition including cold storage. The CA treatments consisted of combinations of 3%, 5% and 10.9% $CO_2$ with 1% and 3-3.9% $O_2$, respectively. Weight and firmness were maintained higher in static CA chambers than in the cold storage. Soluble solid content in fruit of cold storage increased until 2 months of storage and thereafter sharply decreased, whereas that of CA-stored fruit increased slowly throughout the storage period of 120 days. Citric acid decreased obviously in all the treatments with a partially longer retention in CA chambers during storage. Sensory evaluation clearly showed that CA could extend market period of Satsuma Mandarin fruit.

  • PDF