• Title/Summary/Keyword: CRITICAL SURFACE TENSION

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Surfactant Aided Air-sparging for Groundwater Remediation (계면촬성제 첨가에 따른 지하수 폭기법의 폭기효율 변화 연구)

  • 소효은;최경민;이승재;김헌기
    • Economic and Environmental Geology
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    • v.35 no.5
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    • pp.421-428
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    • 2002
  • Lab-scale experiments were conducted to evaluate the effect of surface tension reduction on the extension of the influence zone and the VOC removal efficiency of ground water sparging. A glass column packed with coarse sand was used for VOC removal test at two different surface tensions. A glass column without porous media was also used fer control purpose prior to sand-packed column test. A quasi-two-dimensional glass box model, packed with a sand, was used fer sparging zone tests at different water surface tensions. Surface tension of the aquoues solution used in this study was controlled using sodium dodecyl sulfate (SDS). For the glass, sand column experiments, total amount of air filled in the media increased as surface tension decreased. Toluene (used as VOC in this study) removal rate increased slightly with decreased surface tension f3r both free water column and sand-packed column. Air sparging zone extended up to 500% as the surface tension decreased. Combining the results from two different experiments, VOC removal efficiency is expected to increase significantly with surface tension reduction.

Analysis on the free surface flow induced by a pair of source-sink in Stokes flow (스톡스 유동장 내의 한 쌍의 소오스-싱크에 의한 자유표면 유동해석)

  • Jeong, Jae-Tack;Park, Jong-Sun
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.304-307
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    • 2008
  • Two-dimensional Stokes flow due to the line source and line sink of same strength in semi-infinite flow region with free surface is analysed using complex variable theory and conformal mapping. Surface tension effects are included while gravity is neglected. From the results of analysis, flow pattern and free surface shape are obtained and velocity distribution on the free surface is determined with 2 independent parameters Ca (capillary number) and h (non-dimensionalized distance between source and sink). When the location of the sink is above the source, velocity on the free surface converges and a cusp occurs on the free surface for the value of Ca above some critical capillary number.

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Instability Analysis of Marangoni Convection for $NH_3-H_2O$ Absorption Process Accompanied by Heat Transfer (열전달을 수반하는 $NH_3-H_2O$ 흡수과정에서의 Marangoni 대류 불안정성 해석)

  • 김제익;최창균;강용태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.2
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    • pp.126-131
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    • 2003
  • Convective instability driven by surface tension is analyzed in an initially quiescent water absorbing ammonia gas with heat transfer using the linear stability analysis. The propagation theory is adapted to find the critical conditions of the onset of Marangoni convection. In this theory, the solutal penetration depth is chosen as the length scale factor. The results show that the liquid layer becomes more stable with decreasing the Schmidt number and increasing the Lewis number. It is also found that there is a critical Biot number to make the liquid layer be most unstable, and there is a linear relationship between the thor-mal Marangoni number and the solutal Marangoni number.

Synthesis of Non-fluorinated Polystearyl methacrylate Water Repellent and Its Properties on Textile Fibers (비불소계 폴리스테아릴메타크릴레이트 발수제의 합성과 발수특성)

  • Kim, Taekyeong;Kang, Hyejin;Park, Jihoon
    • Textile Coloration and Finishing
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    • v.29 no.2
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    • pp.55-61
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    • 2017
  • A non-fluorinated polystearyl methacrylate water repellent was synthesized by emulsion polymerization. The number and weight averaged molecular weights were obtained at around 137,277 and 237,754g/mole. The melting point was observed at $32^{\circ}C$. The contact angle of water droplet on fabrics treated with the water repellent was $140{\sim}145^{\circ}$ for cotton and polyester, and $125{\sim}130^{\circ}$ for wool and nylon. Since the critical surface tension was estimated at 20.7mN/m, even though relatively not so strong as fluorinated water repellent, it is considered to be used as a good water repellent practically.

Surface Activities of Carboxybetaine Derivatives (카르복시베타인 유도체(誘導體)의 계면활성(界面活性))

  • Shon, Joo-Hwan;Kim, Yu-Ok
    • Journal of the Korean Applied Science and Technology
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    • v.4 no.2
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    • pp.43-48
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    • 1987
  • Isoelectric point and surface tension of twelve of the alkylcarboxy betaines such as 2-(trimethylammonio) dodecanoate, 2-(trimethyammonio) tetradecanoate, 2-(trimethylammonio) hexadecanoate, (dimethyldodecylammonio)ethanoate, (dimethyltetradecylammonio)ethanoate, (dimethylhexadecylammonio) ehtanoate, 2-(dimethylododecylammonio) propanoate, 2-(dimethyltetradecylammonio)proopanoate, 2-(dimethylhexadecylammonio)propanoate, 2-(dimethyltetradecylammonio)-3-phenyl propanoate, 2-(dimethyltetradecylammonio)-3-phenyl propanoate are tested. From the measurement of the isoelectric point, it was found that the isoelectric point were leaned toward the alkaline zone for c-alkylarbrxybetaines, and toward the acidic zone for N-alkylcarboxybetaines. At the range of the carboxybetaine concentration $2\;{\times}\;10^{-2}{\sim}2\;{\times}\;10^{-5}$mole/l, the surface tension of the aqueous solution were decreased to 30-38 dyne/cm, showing the tendency that the ability of lowering the surafce tension was depending on the increase of carbon atom number in the lipophilic alkyl chain. The critical micelle concetration measured by the surface tension and concentration curves have been found at the range of $10^{-2}{\sim}10^{-5}$mole/l.

Tension-Compression Fatigue Behavior of Carbon Fabric/Epoxy Laminates (Carbon Fabric/Epoxy 적층판의 인장-압축 피로거동)

  • 김진봉;김태욱
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.05a
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    • pp.60-64
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    • 2001
  • In this paper, the tension-compression fatigue test method and the fatigue life characteristics of carbon fabric/epoxy laminate coupon are presented. To avoid the buckling during the compression, a proper design for the test coupons is essential. The critical buckling loads for the coupons are calculated by assuming the coupons as columns under two types of fixed conditions. The first is that both ends of each coupon are perfectly clamped, the second is that both ends of each coupon are simply supported. The strain-load curves are obtained by compressing the representative coupons, on each surface of which a strain gage is attached. The buckling loads obtained from the tests are all between the two calculated critical buckling loads. All the coupons are broken by the compression during the fatigue tests. It is estimated to be the reason that the fatigue load causes delamination before the eventual failure of each coupon, and sequentially the micro-buckling in the delaminated region drives each coupon into fatigue failure during the compression. The S-N curve, the fatigue life characteristics of carbon fabric/epoxy is obtained.

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Characteristic responses of critical current in REBCO coated conductor tapes under tensile/compressive bending strains at 77 K

  • Diaz, Mark Angelo;Shin, Hyung Seop;Lee, Jae-Hun
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.4
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    • pp.31-35
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    • 2018
  • When REBCO coated conductors (CCs) are applied to superconducting devices such as coils and magnets, they are subjected to deformation in various modes such as compression/tension bending, uniaxial/transverse tension and torsion. Despite outstanding performances by REBCO CC tapes, their electromechanical properties have been evaluated primarily under uniaxial tension, therefore data about the critical current ($I_c$) response in the compressive strain region are lacking. In this study, the characteristic responses of $I_c$ in REBCO CC tapes under bending strains in the range from tensile to compressive were evaluated. The springboard bending beam was used, wherein the CC tape sample was soldered onto the surface of the springboard. A Goldacker-type bending test rig, which lacks a support holding the sample during testing, was used as a comparator. Degradation in $I_c$ behaviors, including strain sensitivity, in differently processed REBCO CC tapes were examined based on the test rig used.

Surface Chemical Properties of Surface Active Aminocyclitol Derivatives (계면활성(界面活性) 아미노싸이클리톨 유도체(誘導體)의 계면화학적(界面化學的) 성질(性質))

  • Sohn, Joo-Hwan;Lee, Chang-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.4 no.1
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    • pp.45-52
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    • 1987
  • Surface chemical properties including surface tension, Ross-Miles foaming power, foam stabilities, emulsifying properties, emulsion stabilities, effectiveness of dispersion, dispersion stabilites of the quaternary ammonium salt type deoxyaminoimositol derivatives such as sixteen kinds of dimethylafkyl-deoxyscyllo-inosityl- dimethylalkyl-2-deoxy-2-myo-inosityl-, dimethylakyl-2-deoxy-2-epi-inosityl- and dimethylalkyl-4-deoxy-4-myo-inosityl ammonium chlorides are tested. And critical micelle concentration of these compounds are estimated from the curves of surface tension and concentration. The experimental results show that the members of this class of compounds have necessary surface active properties to make them effective surfactants.

Micro-Gravity Research on the Atomization Mechanism of Near-Critical Mixing Surface Jet

  • Tsukiji, Hiroyuki;Umemura, Akira;Hisida, Manabu
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.774-778
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    • 2004
  • The atomization process of a circular $SF_{6}$ liquid jet issued into an otherwise quiescent, high-pressure $N_2$ gas was observed to explore the breakup mechanism of liquid ligaments involved in turbulent atomization. Both liquid and gas temperatures were fixed at a room temperature but the gas pressure was elevated to more than twice the critical pressure of $SF_{6}$. Therefore, the liquid surface was in a thermodynamic state close to a critical mixing condition with suppressed vaporization. Since the surface tension and the surface gas density approach zero and the surface liquid density, respectively, phenomena equivalent to those which would appear when a very high speed laminar flow of water were injected into the atmospheric-pressure air can be observed by issuing $SF_{6}$ liquid at low speeds in micro-gravity environment which avoid disturbances due to gravity forces. The instability ob near-critical mixing surface jet was quantitatively characterized using a newly developed device, which could issue a very small amount of $SF_{6}$ liquid at small constant velocity into a very high-pressure $N_2$ gas.

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The Effect of Oxidation/Reduction of Sulfide Mineral on Its Recovery by Flotation (산화(酸化)/환원(還元) 조건(條件)에 따른 황화광물(黃化鑛物)의 부유선별(浮游選別)에 의한 회수성(回收性) 변화(變化))

  • Kim, Dong-Su
    • Resources Recycling
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    • v.16 no.2 s.76
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    • pp.12-16
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    • 2007
  • The influence of oxidation on the floatability of sulfide minerals contained in mine failings has been investigated employing chalcopyrite as a target material. The critical surface tension of chalcopyrite was estimated to be about 15.5 dyne/cm based on Zisman plot and the floatability of chalcopyrite was observed to increase with the concentration of collector. The enhanced float-ability of chalcopyrite at its initial stage of oxidation was considered to be due to the transformation of disulfide to elemental sulfur and the decrease in its floatability at further oxidation was presumably caused by the formation of sulfate and/or disulfur trioxide from elemental sulfur. When the oxidized chalcopyrite was reduced, its floatability was increased and the variation of the critical surface tension of chalcopyrite according to tile oxidation/reduction was interpreted by an energy diagram constructed by different bond energies between atoms.