• Bulletin of the Korean Chemical Society
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• v.27 no.5
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• pp.687-693
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• 2006

Chromium(III) complexes, cis-[Cr([14]-decane)$(HOC _6H _4COO) _2$]$ClO _4$ I and cis-[Cr([14]-decane)(OH) $(OC _6H _4NO _2)$]$ClO _4{\cdot}H _2O$ II ([14]-decane = rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-teraazacyclotetradecane) are synthesized and structurally characterized by a combination of elemental analysis, conductivity, IR and VIS spectroscopy, and X-ray crystallography. The complexes crystallizes in the monoclinic space groups, $C2 _1$/a in I and $P2 _1$/n in II. Analysis of the crystal structure of complex I reveals that central chromium(III) ion has a distorted octahedral coordination environment and two hydrogensalicylato ligands are unidentate to the chromium(III) ion via the carboxyl groups in the cis-position. For monomeric complex I the hydrogensalicylato coordination geometry is as follows: Cr-O(average) = 1.984(3) $\AA$;Cr-N range = 2.105(3)-2.141(4) $\AA$;C(24)-O(4) = 1.286(5) $\AA$;N(2)-Cr-N(4) (equatorial position) = 96.97(15)${^{\circ}}$; N(1)-Cr-N(3) (axial position) = 168.27(15)${^{\circ}}$; O(1)-Cr-O(4) = 85.70(13)${^{\circ}}$. The crystal structure of II has indicated that chromium(III) ion is six-coordinated by four secondary amines of the macrocycle, hydroxide anion and nitrophenolate anion.

• Nuclear Engineering and Technology
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• v.26 no.4
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• pp.548-554
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• 1994

The full-energy peak efficiency for a collimated geometry of a Si (Li) detector has been experimentally determined using the electro-deposition sources. The radioactive sources of $^{51}$ Cr, $^{54}$ Mn, $^{57}$ Co and $^{65}$ Zn nuclides are prepared by the electro-deposition method. The measured efficiency values are corrected for the escape losses due to the K X-rays of silicon and the absorptions in materials related to source-to-detector geometry. The corrected efficiency values have turned out to be nearly constant regardless of photon energy.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.6
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• pp.1107-1113
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• 2002

This study presents the hydrogen emblittlement in the metal, which decreases the ductility and then induces the brittle fracture. The contribution deals with the effect of strain rate and notch geometry on hydrogen emblittlement of 1.25Cr-0.5Mo and 2.25Cr-1Mo steels, which are in use at high pressure vessel. Smooth and notched specimens were examined to obtain the elongation and tensile strength. For charging the hydrogen in the metal, the cathodic electrolytic method was used. In this process, current density is maintained constant. The amount of hydrogen penetrated in the specimen was detected by the hydrogen determenator(LECO RH404) with the various charging time. The distribution of hydrogen concentration penetrated in the specimen was obtained by finite element analysis. The amount of hydrogen is high in smooth specimen and tends to concentrate in the vicinity of surface. The elongation and tensile strength decreased with the passage of charging time in 1.25Cr-0.5Mo and 2.25Cr-1Mo steels. The elongation increased and tensile strength decreased as strain rate increased. As a result of this study, it is supposed that 1.25Cr-0.5Mo steel is more sensitive than 2.25Cr-lMo steel in hydrogen embrittlement. Hydrogen embrittlement susceptibility of notched specimen after hydrogen charging is more remarkable than that of smooth specimen.

• Bulletin of the Korean Chemical Society
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• v.29 no.7
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• pp.1374-1378
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• 2008

Using DFT B3LYP/6-31+G(d,p)//B3LYP/6-31G(d,p) calculation method, stable molecular structures were optimized for the p-tert-butylcalix[4]arene functionalized at lower rim by cage-annulated crown ether (1) in two different conformers and their potassium-ion complexes. Cone conformer of free host 1 was slightly more stable than partial-cone conformer. For two different kinds of complexation mode, the potassium ion in benzene-rings (bz) pocket showed comparable complexation efficiency with the cation in cage-annulated crown-ether (cr) for the cone and partial-cone conformers of 1. The complex (1${\bullet}K^+$) in the cr-binding mode for the partial-cone conformer was more stable than the cone conformer for B3LYP/6-31G(d,p) geometry optimization. However, $1_{(cone)}{\bullet}K^+$(cr) showed lower single-point energy than the $1_{(pc)}{\bullet}K^+$(cr) for B3LYP/6- 31+G(d,p) calculation method.

• Journal of The Korean Astronomical Society
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• v.36 no.1
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• pp.1-12
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• 2003

Nonthermal particles can be produced due to incomplete thermalization at collisionless shocks and further accelerated to very high energies via diffusive shock acceleration. In a previous study we explored the cosmic ray (CR) acceleration at cosmic shocks through numerical simulations of CR modified, quasi-parallel shocks in 1D plane-parallel geometry with the physical parameters relevant for the shocks emerging in the large scale structure formation of the universe (Kang & Jones 2002). Specifically we considered pancake shocks driven by accretion flows with $U_o = 1500 km\;s^{-l}$ and the preshock gas temperature of $T_o = 10^4 - 10^8K$. In order to consider the CR acceleration at shocks with a broader range of physical properties, in this contribution we present additional simulations with accretion flows with $U_o = 75 - 1500 km\;s^{-l}$ and $T_o = 10^4K$. We also compare the new simulation results with those reported in the previous study. For a given Mach number, shocks with higher speeds accelerate CRs faster with a greater number of particles, since the acceleration time scale is $t_{acc}\;{\propto}\;U_o^{-2}$. However, two shocks with a same Mach number but with different shock speeds evolve qualitatively similarly when the results are presented in terms of diffusion length and time scales. Therefore, the time asymptotic value for the fraction of shock kinetic energy transferred to CRs is mainly controlled by shock Mach number rather than shock speed. Although the CR acceleration efficiency depends weakly on a well-constrained injection parameter, $\epsilon$, and on shock speed for low shock Mach numbers, the dependence disappears for high shock Mach numbers. We present the 'CR energy ratio', ${\phi}(M_s)$, for a wide range of shock parameters and for $\epsilon$ = 0.2 - 0.3 at terminal time of our simulations. We suggest that these values can be considered as time-asymptotic values for the CR acceleration efficiency, since the time-dependent evolution of CR modified shocks has become approximately self-similar before the terminal time.

• Kyungpook Mathematical Journal
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• v.58 no.1
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• pp.149-165
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• 2018

A. Bejancu [2] was the first who instigated the new concept in differential geometry, i.e., CR-submanifolds. On the other hand, CR-submanifolds were generalized by B. Y. Chen [7] as slant submanifolds. Further, he gave the notion of a Kaehlerian slant submanifold as a proper slant submanifold. This article has two objectives. For the first objective, we derive Simons' type formula for a minimal Kaehlerian slant submanifold in a complex space form. Then, by applying this formula, we give a complete classification of a minimal Kaehlerian slant submanifold in a complex space form and also obtain its some immediate consequences. The second objective is to prove some results about semi-parallel submanifolds.

• Bulletin of the Korean Chemical Society
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• v.20 no.4
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• pp.436-440
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• 1999

The highly resolved absorption spectra of mer-[Cr(dpt)(Gly-Gly)]ClO4·H2O [dpt = di(3-aminopropyl)amine, H2Gly-Gly = glycylglycine] have been measured between 13000 cm-1 and 50000 cm-1 temperatures down to 2 K. The vibrational intervals were extracted by recording emission and far-infrared spectra. The characteristic infrared bands in meridional isomer were discussed. The four-teen electronic origins due to spin-allowed and spin-forbidden transitions were assigned. With the use of this electronic transitions, a ligand field optimization based on the exact known ligand geometry have been performed to determine more detailed bonding properties of Gly-Gly and dpt ligands. It is confirmed that the peptide nitrogen of the Gly-Gly has a weak π-donor property toward chrornium(Ⅲ) ion.

• Journal of Communications and Networks
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• v.18 no.3
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• pp.340-350
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• 2016

The performance of large-scale cognitive radio (CR) networks with secondary users sustained by opportunistically harvesting radio-frequency (RF) energy from nearby primary transmissions is investigated. Using an advanced RF energy harvester, a secondary user is assumed to be able to collect ambient primary RF energy as long as it lies inside the harvesting zone of an active primary transmitter (PT). A variable power (VP) transmission mode is proposed, and an energy-based opportunistic spectrum access (OSA) strategy is considered, under which a secondary transmitter (ST) is allowed to transmit only if its harvested energy is larger than a predefined transmission threshold and it is outside the guard zones of all active PTs. The transmission probability of the STs is derived. The outage probabilities and the throughputs of the primary and the secondary networks, respectively, are characterized. Compared with prior work, the throughput can be increased by as much as 29%. The energy-based OSA strategy can be generally applied to a non-CR setup, where distributed power beacons (PBs) are deployed to power coexisting wireless signal transmitters (WSTs) in a wireless powered sensor network.

• Korean Journal of Metals and Materials
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• v.48 no.10
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• pp.914-921
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• 2010

Studies were carried out to assess the microstructural and mechanical properties of ferriticmartensitic steel under a flowing sodium environment. HT9 (12Cr-MoVW) and Gr.92 (9Cr-MoVNbW) steel were exposed to liquid sodium at $650^{\circ}C$ containing dissolved oxygen of 20 ppm for 2333 hours and evaluations of the microstructure as well as the mechanical properties of the microhardness and nanoindentation were carried out. The result showed that both HT9 and Gr.92 exhibited macroscopic weight loss caused by general corrosion as well as localized types such as intergranular corrosion and pitting. Decarburization at the steel surface took place as the test proceeded. As the Cr content increased, dissolution and decarburization were suppressed. Assessment of the actual cladding geometry revealed that an aging process rather than decarburization governed the mechanical properties, which resulted in a decrease of the microhardness and yield stress.

• Journal of the Korean Society of Radiology
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• v.5 no.6
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• pp.421-426
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• 2011

This research was accomplished to assess dose effects on image quality at computed radiography (CR). The ultimate target of the research was finding optimized exposure that provides necessary image quality for the clinical chest diagnosis. Modulation transfer function (MTF), normalized noise power spectrum (NNPS), and Noise equivalent quanta (NEQ) corresponding to the different doses were measured for the assessment of image quality. The preparation of "edge test device" used in MTF measurement and experimental geometry setup were followed by the recommendations of International Electrotechnical Commission (IEC). The experimental results show the necessary image quality can be achieved even at a half of the automatic exposure control (AEC) setting dose for chest diagnosis. It means that the patient exposure can be reduced dramatically by using optimized dose.