• 제목/요약/키워드: CONDENSER

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Preparation of Silicon Tetrachloride by Chlorination of Silicon (실리콘의 염소화반응에 의한 사염화규소 제조)

  • Park, Kyun Young;Lee, Mi Sun;Kim, Min Cheol;Lee, Chan Hee;Park, Hoey Kyung;Kang, Tae Won;Jeong, Hae Seong;Han, Kyoung Ah;Huh, Weon Hoe;You, Ji Cheol
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.407-410
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    • 2013
  • The chlorination of a metallurgical-grade silicon was carried out in a fluidized bed reactor, 25 mm in diameter. The flow rate of the chlorine admitted into the reactor was 0.2 L/min and that of the carrier nitrogen was 0.8~1.0 L/min. The reactor temperature was maintained at $450^{\circ}C$ and the temperature of the coolant at the $SiCl_4$ condenser was at $-5^{\circ}C$. The $SiCl_4$ yield increased with increasing the mole fraction of chlorine in the feed gas, exhibiting 28% at the mole fraction of 0.2. Further increase of the chlorine mole fraction was not attempted in a worry that the reactor might be failed due to the high exothermicity of the reaction. The production of $SiCl_4$ from silicon by fluidized bed chlorination was demonstrated on a laboratory scale, which is a stepping stone for future studies under more severe conditions toward industrial application.

Study on Condition of Fabrication Processing for R. F. High-power Unit Capacitor and Electrical Characteristics According to Addition of ZrO2 (고주파용 대용량 단위 유전체 제조공정과 ZrO2 첨가에 따른 전기적 특성 연구)

  • Ahn, Young-Soo;Kim, Joon-Soo;Park, Joo-Seok;Kim, Hong-Soo;Han, Moon-Hee;No, Kwang-Soo
    • Journal of the Korean Ceramic Society
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    • v.39 no.9
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    • pp.822-828
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    • 2002
  • Fabrication and electrical characterization of R. F. High-power unit capacitors were investigated to study on condition of fabrication processing for R. F. High-power unit capacitor and electrical characteristics according to addition of $ZrO_2$. The unit capacitors were fabricated using tape casting. The optimum mixture ratio of dielectrics and mixing binder for the slurry fabrication was 57.5∼60.0: 42.5∼40.0 wt%. The slurry viscosity was 4000∼5000 cps and casting state of green tape fabricated using these slurry was excellent. Optimum stacking was made by 200 kg/$cm^2$ pressure with 80$^{\circ}C$ heating. $ZrO_2$ was added to improve the electrical characteristics of unit capacitor, especially breakdown characteristics. The dielectric constant and loss factor of the unit condenser having different $ZrO_2$ amounts was not changed in the addition range of 1 to 5 wt%. Also, dielectric constant was not changed in the frequency range of 10 to 500 kHz. It was found that characteristics of resistance voltage was improved through the formation of $CaZrO_3$ and the reduction of particle size as about 3wt% $ZrO_2$ was added.

The Development of X-ray Unit of Remote Emergency medical System (원격응급시스템에 적합한 X-ray 장치 개발)

  • Cho, Dong-Heon;Koo, Kyung-Wan;Yang, Hae-Sool;Han, Man-Seok;Han, Sang-Ok
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.6
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    • pp.49-54
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    • 2006
  • The X-ray unit developed by this study is to diagnose emergency cases which is too far from a hospital and to classify the patients. We have to use the X-ray in a ambulance or the scene of an accident where we cannot use the AC220 outlet because of the distance from a hospital as well. The X-ray unit developed has a characteristics as follows. First of all, as the unit has a condenser in itself where there is no electric supply, we can use the X-ray inspector in a mountain area or a island. Second, we can detect by digital detector the information taken by X-ray from DC 12[V] electricity and store as a form of file. A control circuit can secure the reliability of the X-ray unit by using the Pic16F84A X-ray and provide various functions. The X-ray unit which suits remote emergency system can be efficiently used for the emergent cases who is too far from a doctor and a hospital or in the situation where it is difficult to diagnose, transcribe and treat simultaneously.

Recovery of Silver and Nitric Acid in the Liquid Waste Resulted from the Mediated Electrochemical Oxidation Process (전기화학적 매개산화공정 폐액에서 은 및 질산의 회수)

  • 최왕규;김영민;이근우;박상윤;오원진
    • Resources Recycling
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    • v.7 no.3
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    • pp.17-26
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    • 1998
  • A study on the recovery of silver and nitric acid in the liquid waste resulted from the mediated electrochemical oxidation(MEO) process was conducted. The removal of silver in the concentrated nitric acid solutions was carried out by the electrodeposition. The removal efficiency more than 98% could be obtained in nitric acid concentrations less than 3 M with the current efficiency of nearly 100%. The experimonts on the evaporation for the recovery of nitric acid were performed as well. At the evaporation factor of 25., the degree of nitric acid recovery in 3.5 M nitric acid solution containing 0.5 to 1.0 mol% NaNO, was 80~90% resulting in 2.8~3.1 M nitric acid. The design factors and operating conditions of the distillation tower were analyzed by using MEH model derived by Maphtali-Sandholm with the throughput of 4 kg/hr for the enrichment of dilute nitric acid solution recovered by evaporation to reuse in the MEO process. The distillation column composed of eleven theoretical stages having the overall tray efficiency of 70% are needed to obtain 1.03 kg/h of 12M nitric acid and 2.97 kg/h of water with feed being introduced to the column at tray 6 from the bottom at the reflux ratio of 0.25, the reboiler with the heat load of 2.7 kW, and the condenser with the cooling load of 0.5 kW.

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Area Effect on Galvanic Corrosion of Condenser Materials with Titanium Tubes in Nuclear Power Plants (Titanium 전열관을 사용하는 원전 복수기 재료의 Galvanic Corrosion에 미치는 면적의 영향)

  • Hwang, Seong-Sik;Kim, Joung-Soo;Kim, Uh-Chul
    • Nuclear Engineering and Technology
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    • v.25 no.4
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    • pp.507-514
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    • 1993
  • Titanium tubes have recently been used in condensers of nuclear power plants since titanium has very good corrosion resistance to seawater. However, when it is connected to Cu alloys as tube sheet materials and these Cu alloys are connected to carbon steels as water box materials, it makes significant galvanic corrosion on connected materials. It is expected from electrochemical tests that the corrosion rate of carbon steel will increase when it is galvanically coupled with Ti or Cu in sea water and the corrosion rate of Cu will increase when it is coupled with Ti, if this couple is exposed to sea water for a long time. It is also expected that the surface area ratios, R$_1$(surface area of carbon steel/surface area of Ti) and R$_2$(surface area of carbon steel/surface area of Cu) are very important for the galvanic corrosion of carbon steel and that these should not be kept to low values in order to minimize the galvanic corrosion on the carbon steel of the water box. Immersed galvanic corrosion tests show that the corrosion rate of carbon steel is 4.4 mpy when the ratio of surface area of Fe/ surface area of Al Brass is 1 while it is 570 mpy when this ratio is 10$^{-2}$ . The galvanic corrosion rate of this carbon steel is increased from 4.4 mpy to 13 mpy at this area ratio, 1, when this connected galvanic specimen is galvanically coupled with a Ti tube. This can be rationalized by the combined effects of R$_1$ and R$_2$ on the polarization curve.

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Development of High Efficiency Dehumidifiers in low temperature (저온에서 고효율 제습기 개발)

  • Kim, Jong-Ryeol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.206-211
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    • 2016
  • Various applications require dry air at low temperature, such automation equipment, semiconductor manufacturing, chemical production lines, and coating processes for the shipbuilding industry. Four evaporators for low temperature (below $0^{\circ}C$) were installed for a dehumidification system. Moist air is cooled sequentially over three evaporators. The first evaporator has an evaporation temperature of $13^{\circ}C$, that of the second evaporator is $5^{\circ}C$, and that of the third evaporator is maintained at $-1.3^{\circ}C$. In the fourth evaporator implantation thereby the moisture contained in the moisture air. A pressure regulator (CPCE 12) is used at this point and is defrosted when the vapor pressure is below a set value. The non-implantation moisture of the air is a heating system that uses the waste heat of a condenser with high temperature. It develops the cooling type's dehumidifier, which is important equipment that prevents the destruction of protein and measures the temperature and humidity at each interval by changing the front air velocity from 1.0 m/s to 4.0 m/s. The cooling capacity was also calculated. The greatest cooling capacity was 1.77 kcal/h for a front air velocity of 2.0 m/s

Air-side Heat Transfer and Pressure Drop of a Fin-and-Tube Heat Exchanger Under Low Temperature Condition (저온 조건에서 핀-관 열교환기의 공기측 열전달 및 압력손실)

  • Kim, Nae-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.4
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    • pp.15-20
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    • 2017
  • Currently, residential air conditioners operate as a heat pump during winter. In this case, the outdoor heat exchanger acts as an evaporator obtaining heat from cold air. On the other hand, it acts as a condenser during summer transferring heat to hot air. The outdoor temperature changes significantly from high to low. Generally, the air-side j and f factors are obtained at a standard outdoor temperature. Therefore, the applicability of the j and f factors under different outdoor conditions needs to be checked. In this study, tests were conducted for a two-row louver finned heat exchanger changing the outdoor temperature to subzero. The effects of the tube-side brine flow rate were also checked. The results showed that air-side j and f factors were essentially constant and independent of the outdoor temperature, suggesting that an extension of j and f factors obtained under standard conditions to a low outdoor temperature is acceptable. All j and f factors agreed within 9% and 3%, respectively. Tests were also conducted by changing the coolant flow rate. Both the j and f factors did not change according to the flow rate, suggesting that the tube-side heat transfer correlation is acceptable.

A Study on the Application of a Turbidity Reduction System for the Utilization of Thermal Wastewater in High Turbidity Zones (고탁도 해역의 온배수 활용을 위한 탁도저감시스템 적용에 대한 연구)

  • Ha, Shin-Young;Oh, Cheol;Gug, Seung-Gi
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.7
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    • pp.916-922
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    • 2018
  • Recently, power plant effluent condensers received a Renewable Energy Certificate as components of hydrothermal energy (weighted 1.5 times) as one target item of the Renewable Portfolio Standard (RPS) policy. Accordingly, more attention is being paid to the value of thermal wastewater as a heat source. However, for utilization of thermal wastewater from power plants in high-turbidity areas like the West Sea of Korea, a turbidity reducing system is required to reduce system contamination. In this study, an experimental test was performed over a month on thermal wastewater from power plants located in the West Sea of Korea. It was found that water turbidity was reduced by more than 80 % and that the concentration of organic materials and nutrient salts was partially reduced due to the reduction of floating/drifting materials. To conduct a comparative analysis of the level of contamination of the heat exchanger when thermal wastewater flows in through a turbidity reducing system versus when the condenser effluent flows in directly without passing through the turbidity system, we disassembled and analyzed heat exchangers operated for 30 days. As a result, it was found that the heat exchanger without a turbidity reducing system had a higher level of contamination. Main contaminants (scale) that flowed in to the heat exchanger included minerals such as $SiO_2$, $Na(Si_3Al)O_8$, $CaCO_3$ and NaCl. It was estimated that marine sediment soil flowed in to the heat exchanger because of the high level of turbidity in the water-intake areas.

Greenhouse Gas Mitigation Effect Analysis by Establishing Additional Heat Storage System for Combined Heat and Power Plant (열병합발전소에서의 축열조 증설에 의한 온실가스 감축 효과 분석)

  • Kim, Shang Mork;Yoon, Joong Hwan;Lim, Kyoung Mi
    • Journal of Climate Change Research
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    • v.2 no.3
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    • pp.175-189
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    • 2011
  • In this research, we describe the methodology and the quantification about GHG reduction effects, expected by optimization of operation mode according to establishing additional heat storage system of Bundang Combined Cycle Power Plant. As an intermediate form of General Combined Cycle Power Plant and Heat supply only district heating plant, Bundang Combined Cycle Power Plant(and Ilsan, Anyang, Bucheon) is possible to satisfy demand for the electrical load and thermal load capacity at the same time through changes to the operation mode itself. Therefore, through the operating transition of high-efficiency mode that the condenser cooling water is recovered and supplied to district heat and cooling, establishing additional heat storage system have flexible supply ability at the power and heat market. In this research, We calculated using the operating performance for the last three years(2008~2010) and efficiency of each mode-specific values. As a result, GHG reduction effects were calculated as $97.95kg_{-}CO_2/Gcal$ per heat energy 1 Gcal supplied at the heat storage system and we expected emmision reduction effect about $13,500Ton_{-}CO_2/yr$.

Numerical Study of the Heat Removal Performance for a Passive Containment Cooling System using MARS-KS with a New Empirical Correlation of Steam Condensation (새로운 응축열전달계수 상관식이 적용된 MARS-KS를 활용한 원자로건물 피동냉각계통 열제거 성능의 수치적 연구)

  • Jang, Yeong-Jun;Lee, Yeon-Gun;Kim, Sin;Lim, Sang-Gyu
    • Journal of Energy Engineering
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    • v.27 no.4
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    • pp.27-35
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    • 2018
  • The passive containment cooling system (PCCS) has been designed to remove the released decay heat during the accident by means of the condensation heat transfer phenomenon to guarantee the safety of the nuclear power plant. The heat removal performance of the PCCS is mainly governed by the condensation heat transfer of the steam-air mixture. In this study, the heat removal performance of the PCCS was evaluated by using the MARS-KS code with a new empirical correlation for steam condensation in the presence of a noncondensable gas. A new empirical correlation implemented into the MARS-KS code was developed as a function of parameters that affect the condensation heat transfer coefficient, such as the pressure, the wall subcooling, the noncondensable gas mass fraction and the aspect ratio of the condenser tube. The empirical correlation was applied to the MARS-KS code to replace the default Colburn-Hougen model. The various thermal-hydraulic parameters during the operation of the PCCS follonwing a large-break loss-of-coolant-accident were analyzed. The transient pressure behavior inside the containment from the MARS-KS with the empirical correlation was compared with calculated with the Colburn-Hougen model.