• Korean Chemical Engineering Research
• /
• v.55 no.3
• /
• pp.379-384
• /
• 2017

An electrochemical reduction of a mixture of NiO and rare earth oxides has been conducted to increase the reduction degree of rare earth oxides. Cyclic voltammetry (CV) measurement was carried out to determine the electrochemical reduction behavior of the mixed oxide in molten LiCl medium. Constant voltage electrolysis was performed with various supplied charges to understand the mechanism of electrochemical reduction of the mixed oxide as a working electrode. After completion of the electrochemical reduction, crystal structure of the reaction intermediates was characterized by using an X-ray diffraction method. The results clearly demonstrate that the rare earth oxide was converted to RE-Ni intermetallics via co-reduction with NiO.

• Plant Journal
• /
• v.11 no.3
• /
• pp.46-52
• /
• 2015

200MWe 순환유동층보일러인 A화력발전소는 정부정책에 의해 국내 무연탄만을 연료로 배정받아 운영되었다. 하지만 무연탄에 대한 민간수요 증가에 따른 정부의 정책변경에 따라 유 무연탄 혼탄을 2000년대 후반부터 시행하고 있다. 하지만 기동시 석탄 투입온도는 여전히 무연탄 전소시의 기준온도인 $600^{\circ}C$에 석탄을 투입하고 있는 실정이라 기동시간 지연의 한 원인으로 작용하고 있고 기동 중 소요되는 경유의 과다소비라는 고질적인 문제점을 안고 있다. 이에 본 연구에서는 A화력에서 사용되는 석탄에 대한 공업분석과 원소분석을 통하여 비교적 휘발분이 많고 반응성이 좋은 러시아산 유연탄(Suek) 연소에 따른 경유에서 석탄으로의 연료교체시 경제적인 시점을 예측하였다. 실험결과 러시아산 유연탄 (Suek) 연소시 투입가능온도는 연소전환율이 90%이상이 되는 연소최대온도($426^{\circ}C$)가 기술적, 경제적으로 가장 적합한 것으로 예상하였다.

• Korean Journal of Microbiology
• /
• v.41 no.3
• /
• pp.225-231
• /
• 2005

The characteristics of cell growth and medium-chain-length polyhydroxyalkanoate (MCL-PHA) biosynthesis of Pseudomonas chlororaphis HS21 were investigated using plant oils as the carbon substrate. The organism was efficiently capable of utilizing plant oils, such as palm oil, corn oil, and sunflower oil, as the sole carbon source for growth and MCL-PHA production. When palm oil (5 g/L) was used as the carbon source, the cell growth and MCL-PHA accumulation of this organism occurred simultaneously, and a high dry cell weight (2.4 g/L) and MCL-PHA ($40.2\;mol{\%}$ of dry cell weight) was achieved after 30 hr of batch-fermentation. The repeating unit in the MCL-PHA produced from palm oil composed of 3-hydroxyhexanoate ($7.0\;mol{\%}$), 3-hydroxyoctanoate ($45.3\;mol{\%}$), 3-hydroxydecanoate ($39.0\;mol{\%}$), 3-hydroxydodecanoate ($6.8\;mol{\%}$), and 3-hydroxytetradecanoate ($1.9\;mol{\%}$), as determined by GC/MS. Even though glucose was a carbon substrate that support cell growth but not PHA production, the conversion rate of palm oil to PHA was significantly increased when glucose was fed as a cosubstrate, suggesting that bioconversion of some functionalized carbon substrates to related polymers in P chlororaphis HS21 could be enhanced by the co-feed of good carbon substrates for cell growth. In addition, the change of compositions of repeating units in MCL-PHAs synthesized from the plant oils was markedly affected by the supplementation of acrylic acid, an inhibitor of fatty acid ${\beta}-oxidation$. The addition of acrylic acid resulted in the increase of longer chain-length repeating units, such as 3-hydroxydodecanoate and 3-hydroxytetradecanoate, in the MCL-PHAs produced. Particularly, MCI-PHAs containing high amounts of unsaturated repeating units could be produced when sunflower oil and corn oil were used as the carbon substrate. These results suggested that the alteration of PHA synthesis pathway by acrylic acid addition can offer the opportunity to design new functional MCL-PHAs and other unusual polyesters that have unique physico-chemical properties.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.28 no.1
• /
• pp.65-72
• /
• 2020

The aims of this study were to compare the biomethanation of CO₂ through specific methanogenic activity (SMA) test which was inoculated with four different types of mixed microbial culture obtained from full-scale anaerobic digestion (AD) plants. The experimental results showed that CH₄ conversion was the highest in the samples inoculated by seed sludge taken from ADs of food waste and brewery; under this condition, the produced biomethane contains 89.3-91.9% of CH₄. Meanwhile, the lowest level was obtained in the sample from sewage sludge. The measured ratio of CH₄ production rate to CO₂ consumption rate in all reactors was higher than the theoretical value (1) in the middle of the period and soon dropped to 0.7-0.8. It might be due to changed metabolic pathways in the reactor by the degradation of residual organic matter and the increased activity of homoacetogenic bacteria.

• Resources Recycling
• /
• v.26 no.3
• /
• pp.53-60
• /
• 2017

Black dross contains metallic aluminium, alumina, silica, MgO, soluble salts together with minor ingredients. Control of silica in black dross is important in transforming the black dross into usable materials. First, most of the soluble salts (KCl and NaCl) in black dross were dissolved in water at reaction temperature of $50^{\circ}C$. Leaching behavior of silica, alumina, MgO and $TiO_2$ from the residue after water treatment was investigated by varying NaOH concentration and reaction temperature. Reaction temperature ($25{\sim}95^{\circ}C$) was favorable to the leaching of alumina but an optimum temperature existed for silica. MgO was not dissolved at all in the NaOH concentration range from 2 to 6 M. At the leaching condition of 5 M NaOH and reaction temperature of $95^{\circ}C$, approximately 80% of alumina and 68% of silica was dissolved.

• Journal of Embryo Transfer
• /
• v.16 no.3
• /
• pp.213-221
• /
• 2001

This study was conducted to examine in vitro developmental ability of porcine embryos after somatic cell nuclear transfer. The porcine ear fell was cultured in vitro for confluency in serum-starvation condition(TCM-199 + 0.5% FBS) far 3~6 days of cell confluency. The zona pellucida of IVM oocytes were partially drilled using laser system. Single somatic cell was individually transferred into enucleated oocytes. And the reconstructed embryos were electrically fused(single DC 1.9kv/cm, 30$\mu$ sec) with 0.3M mannitol. After electrofusion, embryos were activated(single AC 5v/mm, 5sec) and cultured in HCSU-23 medium containing 10% FBS at 39$^{\circ}C$, 5% $CO_2$ in air for 6 to 8 days. The fusion rate of donor cells was 45.6, 36.8 and 46.1% in 3~4, 5~6 days of serum starvation and non serum starvation(N-S), and were 52.7. 53.0 and 51.7% in 1~2. 5~6 and 13~14 passages of donor cell culture, respectively. No significant difference was found in the fusion rate of donor cells by the duration of serum starvation treatment or the number of donor cell passages. By the size of donor cells, however, the fusion rate was significantly higher(P<0.05) for reconstructed embryos derived from 25r $\mu$m $\geq$ site of donor cells (65.3%) than that of 25~30$\mu$ m(42.5%) or 30$\mu$ m(45.5%)$\leq$ cells. The cleavage rate was significantly (P<0.05) higher in 3~4 darts of serum starvation treatment(67.1%) than that in N-S (50.7%) or 5~6 days of starvation(57.1%). The activation rate by the size of donor cells in fused oocytes was 56.5, 68.8 and 58.5%, respectively, and was not significant.

• Journal of Korean Society on Water Environment
• /
• v.28 no.2
• /
• pp.202-212
• /
• 2012

Due to the deterioration of water supply network and the deficiency of raw water, the water utility of local governments have performed various projects to improve their revenue water ratio. However, it is very difficult to estimate the cost for maintaining the revenue water ratio at higher level after completing the project, because local governments have different conditions affecting the operating and maintenance cost of water supply network. The purpose of this study is to present a procedure to estimate the operating and maintenance cost required to maintain the target revenue water ratio of the water supply network. For this purpose, we estimated the cost used only for operation and maintenance of water supply network of 164 local governments with the aid of K-Mean Clustering Analysis and the data from 40 representative local governments. Then, the regression analysis was performed to find relationship between revenue water ratio and the operating and maintenance cost with two different data sets generated by two classification methods; the first method classifies the local governments by means of k-means clustering, and the other classifies the local governments according to the index standardized by the operating and maintenance cost per unit length of water mains per revenue water ratio. The results shows that the method based on the index standardized by the cost and revenue water ratio of each government produces more reliable results for finding regression equations between revenue water ratio and the operating and maintenance cost only for water supply network. The estimated regression equations for each group can be used to estimate the cost required to keep the target revenue water ratio of the local government.

• Journal of Energy Engineering
• /
• v.25 no.4
• /
• pp.214-225
• /
• 2016

Gasification is one of the important contribution to resource recycling by conversion of biomass to a variety of energy sources such as alcohol, SNG etc., and to global warming prevention by reduction of green house gases such as $CO_2$. The aim of this study is to draw the optimal operation condition of dual fluidized-bed gasifier with biomass fuel, to verify SNG production efficiency and to establish the basis for the domestic commercialization of dual fluidized bed gasification. As a result, dual fluidized-bed gasifier has the optimal conditions at $826^{\circ}C$ with steam input 1,334 g/hr, air input 5.56 L/min. The carbon conversion is 81% and SNG production efficiency was $CH_4$ 92%.

• The Journal of The Korea Institute of Intelligent Transport Systems
• /
• v.20 no.6
• /
• pp.162-176
• /
• 2021

Recently, Autonomous Vehicle(AV) has been expected to solve various transportation problems. s the problem of environmental pollution become serious, research to reduce pollution is needed. However, empirical research on AV related pollution is insufficient. Based on this background, this study analyzed network performance changes and CO₂ emissions introduc AVs and Electric Vehicles(EV) in eight intersections. The results show that when AVs with internal combustion engines were, the effect of carbon reduction over the network was insignificant. On the other hand, it was that the total amount of CO₂ generated in the network decreased significantly when EVs and autonomous electric vehicles were emissions in the transportation sector.

• Journal of the Society of Disaster Information
• /
• v.18 no.1
• /
• pp.116-128
• /
• 2022

Purpose: The paper aims to: 1) identify the reasons for the low usage of recycled paper in domestic workplaces and the premature state of recycled paper industry; 2) assess the environmental effects of replacing domestically consumed copy papers with recycled papers; and 3) suggest ways in which the recycled paper industry can expand in South Korea. Method: Questionnaire survey with cluster sampling is used to identify the attitudes and behavior with respect to recycled copy paper, the results of which are analyzed using SPSS. The environmental effect of replacing copy papers with recycled paper is assessed through the Life Cycle Assessment approach and Paper Calculator V4.0. Result: While the respondent's experience in using recycled copy paper was relatively low, they tend to acknowledge the need for its use and show relatively high satisfaction with the quality of the recycled paper. The environmental benefits of replacing ordinary copy paper with 40%+ recycled paper under the 10% market share increase scenario amounts to 60,000 tons of CO₂ emissions reductions. Conclusion: The results from the attitude survey and market research, five approaches to improving the recycled copy paper market are suggested.