• Title/Summary/Keyword: CL Data

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ATM Connection Admission Control Using Traffic Parameters Compression (트래픽 파라메타 압축을 이용한 ATM 연결수락제어)

  • Lee, Jin-Lee
    • The KIPS Transactions:PartC
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    • v.8C no.3
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    • pp.311-318
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    • 2001
  • 본 논문에서는 연결수락 제어시 사용자가 전송하는 트래픽 파라메타(샐 개수의 분산값과 평균값)를 압축하여 망에 신고하는 방법을 제안하고, 압축방법에 의한 연결수락제어의 성능을 분석 비교한다. 트래픽 파라메타 압축방법은 K-means, CL(Competitive Learning), Fuzzy ISODATA,FNC(Fuzzy Neural Clustering)를 사용한다. 제안한 트래픽 파라메타의 압축에 의한 연결수락제어는 퍼지 매핑함수(Fuzzy Mapping Funciton)fp 의해 신고한 트래픽 패턴을 추정하고, 전방향 구조의 신경망을 사용하여 연결의 수락/거절을 결정한다. ON-OFF 트래픽 모델 환경에서 컴퓨터 실험을 통하여 여러 가지 압축방법들을 사용한 연결수락제어의 성능을 Fuzziness 값에 따라 비교하였고, 그 결과 FNC 방법이 우수함을 알 수 있었다. EH한 연결수락제어의 성능을 높히기 위해서 관측 프레임의 셀 분산값이 크면 Fuzziness 값을 작게 선정하고, 작으면 상대적으로 크게 선정해야 함을 알 수 있었다.

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A Study on the Electrochemical Impedance Spectroscopy and the Electrical Circuit Model for the Electrode/Electrolyte Interface (전극/전해질 계면의 전기화학적 임피던스 측정 및 전기회로 모델 연구)

  • Chang, Jong-Hyeon;Hong, Jang-Won;Pak, Jung-Ho
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.274-275
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    • 2007
  • The investigation of the equivalent circuit models for the electrode/electrolyte interface has been pursued for a long time by several researchers. Previous circuit models fit the experimental results in limited conditions such as frequency range, type of electrode, or electrolyte. This paper describes a new electrical circuit model and its capability of fitting the experimental results. Electrochemical impedance spectroscopy was used to characterize the interface for Au, Pt, and stainless steel electrode in 0.9% NaCl solution. Both the proposed model and the previous model were applied to fit the measured impedance results for comparison. The proposed model fits the experimental data more accurately than other models especially at the low frequency range, and it enables us to predict the impedance at very low frequency range, including DC, using the proposed model.

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MOLTEN SALT VAPORIZATION DURING ELECTROLYTIC REDUCTION

  • Hur, Jin-Mok;Jeong, Sang-Moon;Lee, Han-Soo
    • Nuclear Engineering and Technology
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    • v.42 no.1
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    • pp.73-78
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    • 2010
  • The suppression of molten salt vaporization is one of the key technical issues in the electrolytic reduction process developed for recycling spent nuclear fuel from light-water reactors Since the Hertz-Langmuir relation previously applied to molten salt vaporization is valid only for vaporization into a vacuum, a diffusion model was derived to quantitatively assess the vaporization of LiCl, $Li_2O$ and Li from an electrolytic reducer operating under atmospheric pressure. Vaporization rates as a function of operation variables were calculated and shown to be in reasonable agreement with the experimental data obtained from thermogravimetry.

Chemical Constituents from the Apical Bud of Gardenia sootepensis and Their Bioactivity (Gardenia sootepensis의 끝눈으로부터 생리활성 성분)

  • Youn, Ui Joung;Chang, Leng Chee
    • Korean Journal of Pharmacognosy
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    • v.48 no.2
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    • pp.113-118
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    • 2017
  • Bioassay guided fractionation and isolation of the $CH_2Cl_2$ extract from the apical bud of Gardenia sootepensis (Rubiaceae) led to the isolation of five known flavonoids (1-5). The structures of the compounds were determined by 1D and 2D NMR, and MS experiments, as well as by comparison of their data with published values. Compounds 1-5 were isolated for the first time from this plant source. The isolated compounds were evaluated for their cancer chemopreventive potential based on their ability to inhibit nitric oxide (NO) production. Among the isolates, compound 4 exhibited considerable NO inhibitory activity with an $IC_{50}$ value of $13.8{\mu}M$.

Activity Measurement in Liquid Zn-(In, Sn) Alloy Using E.M.F Method (기전력법에 의한 용융 ZR-(In, Sn) 합금의 활동도 측정)

  • Jung Woo-Gwang
    • Korean Journal of Materials Research
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    • v.15 no.1
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    • pp.47-53
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    • 2005
  • The E.M.F. of the galvanic cell with fused salt was measured to determine the activities of zinc at 720-860 K over the entire composition range of liquid Zn-In and Zn-Sn alloys. The cell used was as follows: $$(-)W{\mid}Zn(pure){\mid}Zn^{2+}(KCl-LiCl){\mid}Zn(in\;Zn-In\;or\;Zn-Sn\;alloy){\mid}W(+)$$ The activities of zinc in the alloys showed positive deviation from Raoult's law over the entire composition range. The activity of cadmium and some thermodynamic functions such as Gibbs free energy, enthalpy and entropy were derived from the results by the thermodynamic relationship. The comparison of the results and the literature data was made. The liquid Zn-In and Zn-Sn alloys are found to be close tn the regular solution. The concentration fluctuations in long wavelength limit, $S_{cc}(o)$, in the liquid alloy were calculated from the experimental results.

Micro-PIV Measurements of interfacial electrokinetic effects in a microchannel (마이크로 PTV 기법을 이용한 미세채널 내부 계면의 electrokinetic 효과 해석)

  • Kim Guk-bae;Lee Sang-Joon
    • 한국가시화정보학회:학술대회논문집
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    • 2002.11a
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    • pp.49-50
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    • 2002
  • In micro-channels, the electro-viscous effect is caused by the electrical double layer on pressure-driven liquid flow. Velocity fields of flow inside micro-channels were measured using micro-PIV system for investigating the electro-viscous effect. De-ionized water and aqueous NaCl solutions with four different concentrations were used as working fluid in a PDMS micro-channel of $100{\mu}m$ width and $66{\mu}m$ height. The pressure gradient, dP/dx, was determined from the pre-determined input flow rate Q of syringe pump. The mean velocity $u_m$ used for calculating Reynolds number was obtained from the PIV velocity field data. These are used to plot the pressure gradient as a function of Reynolds numbers. The pressure gradient far lower concentration solution $(10^{-5}\;M)$ was higher than that for the higher concentration solution. The increase of flow resistance was about $30\%\;and\;37.5\%$ at Re=0.02 and 0.06, respectively.

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Circadian Changes of Cyclosporine Pharmacokinetics in Rabbits (생체리듬에 따른 싸이클로스포린의 약물동태)

  • Choi, Jon Shik;Park, Bok Soon;Lee, Jin Hwan
    • Korean Journal of Clinical Pharmacy
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    • v.9 no.1
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    • pp.66-70
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    • 1999
  • The effect of circadian rhythm on cyclosporine pharmacokinetics was studied in rabbits after oral administration of 10 mg/kg dose of cyclosporine at 10:00 a.m. and 10:00 p.m. The blood concentration data were subjected to simultaneous computer nonlinear least squares regression analysis using a 1-compartment pharmacokinetic model. The blood concentrations of cyclosporine at 10:00 a. m. were increased significantly during 2-6 hr compared to those at 10:00 p.m. The area under the blood concentration-time curve (AUC) and peak concentration $(C_{max})$ of cyclosporine at 10:00 a.m. were increased significantly compared to those at 10:00 p.m. The mean total body clearance (CL) of cyclosporine at 10:00 a.m. were decreased significantly compared to those at 10:00 p.m. It is reasonable to consider individual circadian rhythm for effective dosage regimen of cyclosporine in therapeutics.

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The Crystal Structure of Metoclopramide

  • Shin, Whan-chul;Chang, Tai-Sik;Koo, Chung-Hoe
    • Bulletin of the Korean Chemical Society
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    • v.4 no.3
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    • pp.123-127
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    • 1983
  • The crystal structure of metoclopramide, $C_14H_22ClN_3O_2$, has been determined by X-ray diffraction techniques using diffractometer data obtained by the ${\omega}-2{\theta}$ scan technique with Mo $K\alpha$ radiation from a crystal with space group symmetry $P{\overline{1}}$ and unit cell parameters a = 7.500(1), b = 8.707(2), c = 13.292(2) ${\AA}$; ${\alpha}$ = 101.70(2), ${\beta}$ = 81.20(2), and ${\gamma}$ = $114.90(l)^{\circ}$. The sructure was solved by direct methods and refined by full-matrix least-squares to a final R = 0.055 for the 1524 observed reflections. The bent overall-conformation of the molecule seems to be determined mainly by the bifurcated intramolecular hydrogen bond from the amide nitrogen atom to the methoxy oxygen and the amine nitrogen atoms. The crystal packing consists of the hydrogen bonds, ${\pi}-{\pi}$ interaction and hydrophobic interaction.

Dissociation Kinetics of Linear polyaminopolycarboxylate Complexes of Lanthanides(III)

  • Ki-Young Choi;Ki Sung Kim;Choon Pyo Hong
    • Bulletin of the Korean Chemical Society
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    • v.15 no.9
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    • pp.782-785
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    • 1994
  • The dissociation kinetics of linear polyaminopolycarboxylate complexes of lanthanide ions (L$n^{3+}: Ce^{3+},\;Eu^{3+}\;and\;Yb^{3+}$) has been studied in an aqueous solution of 0.10 M (NaCl$O_4$) at 25.0${\pm}0.1^{\circ}C$ using Cu(II) ions as a scavenger. The dissociation rates of acid-catalyzed pathway decrease in the order Ln(EPDTA$)^- > Ln(DPOT)^- > In(TMDTA)^- > Ln(MPDTA)^- > Ln(EDTA)^- > Ln(PDTA)^- > Ln(DCTA)^-$ according to the present and literature data. An increase in the N-Ln-N chelate ring from 5 to 6 and substitution of two methyl groups, one ethyl and hydroxyl group on a chelate ring carbon of these ligands leads to a decrease in kinetic stabilities of the complexes. The substitution of one methyl group and cyclohexyl ring on a ring carbon, however, results in a significant increase in the kinetic stability of the resulting $Ln^{3+}$ complexes. Individual reaction steps taking place for each system, with different copper, acetate buffer concentration and pH dependence, are also discussed.

Molecular Orbital Study of Bonding and Stability on Rh(Ⅰ)-Alkyne Isomers

  • 강성권;송진수;문정현;윤석성
    • Bulletin of the Korean Chemical Society
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    • v.17 no.12
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    • pp.1149-1153
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    • 1996
  • Ab initio and extended Huckel calculations were carried out on the isomers of trans-RhCl(η2-C2H2)(PH3)2 (1). Due to π-back donation in 1 complex, the rotational energy barrier of alkyne ligand is computed to be in the range of 18.6-25.2 kcal/mol at MP4 levels. The optimized hydrido-alkynyl complex (2) at ab initio level has the distorted trigonal bipyramidal structure. Vinylidene complex (3) is computed to be more stable than 1 complex by 17.1 kcal/mol at MP4//MP2 level. The stabilities of isomers show similar trend at the various level calculations, that is, EHT, MP4//HF, and MP4//MP2 levels. The optimized geometries at ab initio level are in reasonable agreement with experimental data. A detailed account of the bonding in each isomers (1-3) have been carried out in terms of orbital analyses.