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Effects of Diet and Time on Feed on Fatty Acid Composition in Muscle of Charolais Steers (사료급원과 급여기간이 Charolais 거세우 근내 지방산 조성에 미치는 영향)

  • 최낙진;강수원;권응기;조원모;전병수;박병기
    • Journal of Animal Science and Technology
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    • v.48 no.6
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    • pp.847-860
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    • 2006
  • This study investigated the effects of feeding Charolais steers on diets rich in either n-6 or n-3 polyunsaturated fatty acids (PUFA) and time on feed (TOF) on muscle fatty acid composition and content. Twenty eight steers were fed on ad libitum forage and one of two concentrates varying in the source of fat; soya (high in C18:2 n-6) or whole linseed (high in C18:3 n-3) for either 60 or 90 days in IGER (Institute of Grassland and Environmental Research, UK). The concentrates were fed at approximately 0.73 of total DM intake. TOF influenced carcass weight, conformation and fatness scores, which were higher at 90 v. 60 days (P<0.05). Diet did not affect total fatty acid content of neutral lipid in m. longissimus thoracis but feeding linseed increased total phospholipid fatty acid by approx- imately 15%(P<0.05). Linseed increased the amount and proportion of C18:3 n-3 (P<0.001) and the proportion of CLA (cis-9, trans-11 conjugated linoleic acid), while soya increased the content (P<0.05) and proportion (P<0.001) of C18:2 n-6 in muscle neutral lipid. In muscle phospholipid, linseed significantly increased the amount of CLA, C18:3 n-3 and its longer chain derivatives as well as C14:0, C16:0, C18:0. C18:1 trans and C18:2 n-6. The amount and proportion of C18:2 n-6 and its longer chain C20 derivatives were higher on feeding soya. TOF (90 v. 60 day) increased the content of C14:0, C16:0, C16:1, CLA, C18:1 n-9, C18:2 n-6 and C18:3 n-3 in muscle neutral lipid. The P:S was not affected by diet or TOF. The ratio of C18:2 n-6 : C18:3 n-3 and sum of n-6 : n-3 fatty acids were higher in muscle from animals fed on linseed v. soya (P<0.001). The study indicates that the PUFA composition of beef muscle may be significantly modified by feeding contrasting dietary lipids, soya vs. linseed. Feeding linseed produced a better balance of muscle fatty acids, more in line with current nutritional recommendations with a lower C18:2 n-6:C18:3 n-3 ratio associated with higher muscle content of C18:3 n-3 and C20:5 n-3 and CLA and lower C20:4 n-6.

Refinement of the Structure of p-Dimethylaminobenzaldehyde 4-(p-Ethoxyphenyl) Thiosemicarbazone (p-Dimethylaminobenzaldehyde 4-(p-Ethoxyphenyl) Thiosemicarbazone구조의 정밀화)

  • Seo, Il-Hwan;Seo, Chu-Myeong;Park, Yeong-Ja
    • Korean Journal of Crystallography
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    • v.2 no.1
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    • pp.12-16
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    • 1991
  • C18H22N4OS, Mr=342.47, monoclinic, P2₁/c,a=11.802(2), b=31.962(2), c=9.829(2)A, β=100.12(1)˚, V=3694.8A3,F(000)=1472, Z=8, Dx=1.246 Mg m-3, Dm=1.17Mg m-3,λ=0.71073 A, μ=0.15mm-1, T=294 K. final R=0.0856 for 3718 observed reflection (Fo>3σ(Fo)) There are two molecules in an asymmetric unit and a major difference between these molecules is in the C(9)-N(1)-C(6)-C(7) torsion angles [58.8(8)˚and 1(1)˚]. Both molecules have intramolecular N(1)-H(10)'N(3) hydrogen bonds [ 2.613(7) and 2.566(7) A] and assume V-shaped conformation with N(2) atoms at the verices. The two independent molecules are linked by the two N(2)-H(11)'S' hydrogen bonds[3.367(5) A and 3.421(4)A] and the dimergen are held together by van der Waals forces.

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품종에 따른 돈육의 지방 함량, 지방산 조성 및 전자코에 의한 향기 패턴의 차이 분석

  • Gang, Seon-Mun;Gang, Chang-Gi;Lee, Seong-Gi
    • Proceedings of the Korean Society for Food Science of Animal Resources Conference
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    • 2006.05a
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    • pp.107-111
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    • 2006
  • 본 연구는 돼지 품종에 따른 지방 함량, 지방산 조성 및 전자코에 의한 향기 패턴의 차이를 분석하고자 실시하였으며, 평균 생시체중이 111 kg인 멧돼지 5두, 64 kg인 재래흑돼지 5두 및 114 kg인 개량종 돼지($Landrace{\times}Yorkshire$) 5두의 등심(M. longissimus) 부위를 본 실험에 이용하였다. 근내 지방함량은 재래흑돼지가 멧돼지, 개량종 돼지보다 유의적으로 높았다(p<0.05). 지방산 조성에서 C14:0, C18:3n3, MUFA/SFA 비율은 재래흑돼지가 가장 유의적으로 높았으며(p<0.05), C18:1n9는 개량종 돼지가 멧돼지보다 높았다(p<0.05). C16:1n7, C18:1n7, UFA/SFA 비율은 멧돼지가 가장 높았으며(p<0.05), C18:0, C20:1n9는 멧돼지가 가장 낮았다(p<0.05). C20:4 n6은 멧돼지가 개량종 돼지보다 높았고(p<0.05), C22:4n6은 재래흑돼지가 가장 높았으며(p<0.05), C22:5n3은 멧돼지가 재래흑돼지보다 높았다(p<0.05). PUFA n6/n3 비율은 개량종 돼지가 가장 낮았으며(p<0.05), 멧돼지가 재래흑돼지보다 낮았다(p<0.05). 전자코의 PCA에 의한 향기패턴은 신선육에서 품종에 따른 차이가 명확히 나타났으며, 가열육에서는 멧돼지 및 재래흑돼지, 개량종 돼지간에 차이가 나타났다. 따라서 재래흑돼지가 가장 높은 근내 지방 함량 및 가장 낮은 MUFA/SFA 비율을 가졌고, 멧돼지가 가장 높은 UFA/SFA 비율을 가졌으며, 개량종 돼지가 가장 낮은 PUFA n6/n3 비율을 가졌다. 또한 전자코에 의해 돼지 품종에 따른 돈육의 향기 패턴 차이를 효과적으로 분별할 수 있었다.

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A New Analysis Method of the Consolidation Test Data for an Undisturbed Clay (불교란 점토 압밀시험 결과의 새로운 해석법)

  • 박종화;고우모또타쯔야
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.44 no.6
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    • pp.106-114
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    • 2002
  • In this study, the results of a series of consolidation test for undisturbed Ariake clay in Japan were analyzed by three methods, e-log p (e: void ratio, p: consolidation pressure), log e-log p and n-log p (n: porosity). Moreover, the characteristics of each analysis method were studied. For undisturbed Ariake clay, the log o-Log p and the n-log p relationships can be found as two groups of straight lines of different gradients, but both the elastic consolidation and plastic consolidation regions of e-log p relationship are expressed as a curve. In this paper, the porosity of consolidation yield n$\_$y/, consolidation yield stress p$\_$y/, and the gradient of the plastic consolidation region C$\_$p/ were represented by the log e-log p method, and n$\_$c/, P$\_$cn/ and C$\_$cn/ were represented by the n-log p method. The meaning and the relationships of each value were studied, and the interrelationships among compression indices i.e. C$\_$cn/, C$\_$p/ and C$\_$c/ are obtained from each analysis method as a function of initial porosity n$\_$0/.

$C^*$-ALGEBRAS ASSOCIATED WITH LENS SPACES

  • Boo, Deok-Hoon;Oh, Sei-Qwon;Park, Chun-Gil
    • Communications of the Korean Mathematical Society
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    • v.13 no.4
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    • pp.759-764
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    • 1998
  • We define the rational lens algebra (equation omitted)(n) as the crossed product by an action of Z on C( $S^{2n+l}$). Assume the fibres are $M_{ k}$/(C). We prove that (equation omitted)(n) $M_{p}$ (C) is not isomorphic to C(Prim((equation omitted)(n))) $M_{kp}$ /(C) if k > 1, and that (equation omitted)(n) $M_{p{\infty}}$ is isomorphic to C(Prim((equation omitted)(n))) $M_{k}$ /(C) $M_{p{\infty}}$ if and only if the set of prime factors of k is a subset of the set of prime factors of p. It is moreover shown that if k > 1 then (equation omitted)(n) is not stably isomorphic to C(Prim(equation omitted)(n))) $M_{k}$ (c).

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Swelling Characteristics of a Hydrogel poly(N-isopropylacrylamide-co-N N'-dimethylaminopropyl methacrylamide) Sensitive to Both pH and Temperature (pH 및 온도에 동시에 민감한 하이드로젤의 팽윤 특성)

  • 손창규;정인식;박창호
    • KSBB Journal
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    • v.14 no.1
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    • pp.58-65
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    • 1999
  • A hydrogel, poly(N-isopropylacrylamide-co-N,N'-dimethylaminopropyl methacrylamide), sensitive to both pH and temperature was synthesized and characterized for its welling behavior, lower critical solution temperature (LCST), and its appearance. The hydrogel with 5 mol% of N,N'-diemthylaminopropyl methacrylamide (DMAPMAAm) increased its volume phenomenonally in a lower pH range (ph 1~8) even at temperature ($37^{\circ}C$ and $40^{\circ}C$) higher than LCST. This behavior was unique compared to the temperature -sensitive hydrogel which did not exhibit any swelling in the same pH range. The hydrogel with 20 mol% of DMAPMAAm was swollen significantly at a higher pH of 12. With pH decrease from 12 to 2 water content in the gel increased from 38.8 wt% and 60.6 wt%, and 90.8 wt% for 5 mol% and 20 mol% gel, respectively. The transition pH that pH effect overwhelmed temperature effect occurred at a lower pH for a higher temperature ($40^{\circ}C$) and a lower mol% (5 mol%) of DMAPMAAm. Transparency and LCST of the gel increased with higher DMAPMAAm mol%.

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The Effect of Nutritional Balance between Carbon and other Nutrient Sources on the Growth of Sporobolomyces holsaticus (탄소원과 다른 영양원간의 영양균형이 Sporobolomyces holsaticus의 균체생육도에 미치는 영향)

  • Park, Wan-Soo;Koo, Young-Jo;Shin, Dong-Hwa;Min, Byung-Yong
    • Korean Journal of Food Science and Technology
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    • v.15 no.1
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    • pp.56-61
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    • 1983
  • Direct production of biomass from starch using amylolytic yeast, Sporobolomyces holsaticus FRI Y-5 was studied with varying the ratios between carbon and other nutrient sources in the medium. It was investigated under condition of constant C/P and C/S ratio to influence the initial concentration of starch $(S_o)$ and C/N ratio on its growth which is described as the specific growth rate $({\mu})$, cell yield (Y), the maximum concentration of cell $(X_m)$, and productivity (P). They were very dependent on both $S_o$ and C/N ratio. The form of the relationship between and ${\mu}$ and $S_o$ was observed to be similar to saturation kinetics at C/N = 100 but presented substrate inhibition at other C/N ratios. As $S_o$ was changed from 22.5 to 90 g/l, Y was observed to vary with C/N ratios but seemed to decrease as a wholes. $X_m$ was linearly related to $S_o$ at more than C/N = 50 but at less than C/N = 10 substrate inhibition was presented. P increased suddenly to $S_o$ = 45 g/l and then changed decreasingly at less than C/N = 50, but at more than C/N = 100 it changed increasingly. The effect of C/P ratio and C/S ratio on the yeast growth was also investigated at constant $S_o$ and C/N ratio. ${\mu}$ was dependent on C/P and C/S ratios, but Y, independent on them. But $X_m$ was reliant upon C/P ratio but not upon C/S ratio.

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COMPOSITION OPERATORS ON THE PRIVALOV SPACES OF THE UNIT BALL OF ℂn

  • UEKI SEI-ICHIRO
    • Journal of the Korean Mathematical Society
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    • v.42 no.1
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    • pp.111-127
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    • 2005
  • Let B and S be the unit ball and the unit sphere in $\mathbb{C}^n$, respectively. Let ${\sigma}$ be the normalized Lebesgue measure on S. Define the Privalov spaces $N^P(B)\;(1\;<\;p\;<\;{\infty})$ by $$N^P(B)\;=\;\{\;f\;{\in}\;H(B) : \sup_{0 where H(B) is the space of all holomorphic functions in B. Let ${\varphi}$ be a holomorphic self-map of B. Let ${\mu}$ denote the pull-back measure ${\sigma}o({\varphi}^{\ast})^{-1}$. In this paper, we prove that the composition operator $C_{\varphi}$ is metrically bounded on $N^P$(B) if and only if ${\mu}(S(\zeta,\delta)){\le}C{\delta}^n$ for some constant C and $C_{\varphi}$ is metrically compact on $N^P(B)$ if and only if ${\mu}(S(\zeta,\delta))=o({\delta}^n)$ as ${\delta}\;{\downarrow}\;0$ uniformly in ${\zeta}\;\in\;S. Our results are an analogous results for Mac Cluer's Carleson-measure criterion for the boundedness or compactness of $C_{\varphi}$ on the Hardy spaces $H^P(B)$.

Hydrolysis Mechanism of N-(benzenesulfonyl)-C-(N-methylanilino)imidoyl Chloride Derivatives (N-(benzenesulfonyl)-C-(N-methylanilino)imidoyl Chloride 유도체의 가수분해 반응 메카니즘)

  • Kwon, Ki-Sung;Song, Yun-Yi
    • Journal of the Korean Chemical Society
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    • v.39 no.8
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    • pp.650-656
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    • 1995
  • Rate Constants of hydrolysis of N-(benzenesulfonyl)-C-(N-methylanilino)imidoyl chlorides were determined by UV spectrophotometry in 50% (v/v) aqueous methanol at 25$^{\circ}C.$ On the basis of rate equation, substituent effect, solvent effect, salt effect, thermodynamic parameters and hydrolysis product analysis, it may be concluded that the hydrolysis of N-(benzenesulfonyl)-C-(N-methylanilino)imidoyl chlorides proceed through $S_N1$ mechanism via azocarbonium ion intermediate below pH 9.0, while aebove pH 10.0 the hydrolysis proceeds through nucleophilic addition-elimination ($Ad_{N-E}$) mechanism.

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Carbon and Nitrogen Responses of Litterfall Components by NPK and PK Fertilizers in a Red Pine (Pinus densiflora S. et Z.) Stand

  • Park, Seong-Wan;Baek, Gyeongwon;Kim, Seongjun;Yang, A-Ram;Kim, Choonsig
    • Journal of Korean Society of Forest Science
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    • v.108 no.1
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    • pp.21-28
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    • 2019
  • This study was conducted to determine the carbon (C) and nitrogen (N) response of litterfall components as affected by N addition in compound fertilizer in a Korean red pine (Pinus densiflora S. et Z.) stand in southern Korea. Litterfall in a mature red pine stand was collected for two years following compound fertilizer application ($N_3P_4K_1$; $P_4K_1$) and no fertilization (control). The C concentration of litterfall components was not significantly (P > 0.05) different between the $N_3P_4K_1$ and the control plots, whereas the N concentration of the litterfall components was significantly higher in the $N_3P_4K_1$ plot than in the control plot. The $N_3P_4K_1$ and $P_4K_1$ additions induced a lower C/N ratio of litterfall components compared with the control plot. Annual C and N fluxes via litterfall components were not affected by the $N_3P_4K_1$ addition over the study period, except for reproduction litter. Annual N fluxes via reproduction litter were significantly higher in the $N_3P_4K_1$ plot than in the control plot. Thus, the $N_3P_4K_1$ and $P_4K_1$ additions could modify differently nutrient distribution of the forest floor and mineral soils in a red pine stand. These results indicate that N concentration and C/N ratio in litterfall components are more susceptible to fertilizer application than the C response in litterfall components.